In a multi-piece solid golf ball having a core, an envelope layer, an intermediate layer and a cover, the core, an intermediate layer-encased sphere and the ball have surface hardnesses which satisfy a specific relationship, and the envelope layer, the intermediate layer and the cover have thicknesses which satisfy a specific relationship. Also, the core has a hardness profile in which the hardnesses at the core surface, core center, a position 5 mm from the core center, and a position midway between the surface and center of the core satisfy specific relationships. This golf ball, when used by mid- and high-level amateurs, enables the golfer to maintain an adequate distance on shots with a driver and achieve a good distance on iron shots, has a good spin performance on approach shots and has a good feel on impact. In addition, the ball has an excellent scuff resistance when struck with a grooved wedge.

Methods for making multi-piece golf balls comprising at least one component made of ethylene-propylene diene copolymer (EPDM) rubber and the resulting balls are provided. The multi-piece golf ball includes a cover, preferably a dual-cover having inner and outer cover layers. The outer cover is preferably made of a liquid rubber composition based on liquid EPDM rubber. In one version, the ball sub-assembly is dipped in a bath containing liquid EPDM rubber to form the outer cover. In another version, a casting method is used and the liquid EPDM rubber is dispensed into mold cavities to form the outer cover. The inner core of the ball may be made of polybutadiene rubber and the outer core layer may be made of EPDM rubber. The resulting golf ball has high resiliency, a soft feel, and good weatherability.

In a multi-piece solid golf ball having a core formed of a rubber composition, an intermediate layer formed of a polyurethane material and a cover, the ball satisfies the following condition: surface hardness of ball≤surface hardness of intermediate layer-encased sphere. When the ball is struck with a driver at a head speed of 40 m/s, the sum of the time t1 required from contact initiation between the driver and ball for deformation of the ball to reach a maximum value and the time t2 required from the state of maximum ball deformation for the ball and driver clubface to separate is at least 685 microseconds, and the ratio t2/t1 is at least 1.35, and the core has a specific hardness profile. This ball has an excellent flight performance when hit by low or moderate head-speed golfers, is receptive to spin on approach shots and has a good, soft feel at impact.

In a golf ball having a core, envelope layer, intermediate layer and cover, the (core diameter)/(ball diameter) value falls within a particular range, the core has a specific hardness profile, and the Shore C hardness relationships among the core center and surface hardnesses and the surface hardnesses of the envelope layer-encased sphere, intermediate layer-encased sphere and ball satisfy the following conditions:

core surface hardness<surface hardness of envelope layer-encased sphere<surface hardness of intermediate layer-encased sphere>ball surface hardness,  (1)

(surface hardness of envelope layer-encased sphere)−(core center hardness)≥28.  (2)

Also, the envelope layer, intermediate layer and cover have respective thicknesses which satisfy the condition:

cover thickness<intermediate layer thickness  (3)

cover thickness<envelope layer thickness  (4)

envelope layer thickness≥0.8 mm.  (5)

This ball enables mid-level and skilled amateur golfers to achieve superior distances on driver shots and on iron shots, and moreover has a soft yet good feel at impact.

A golf ball comprising an electrical component is disclosed herein. The electrical component comprises an integrated circuit having a gyroscope, a magnetometer, and a BLUETOOTH low energy (BTLE) radio, and at least one battery. A body is composed of an epoxy material, and the body encompasses the electrical component.

In a golf ball having a core, an envelope layer, an intermediate layer and a cover, the difference between the center hardness and the surface hardness of the core is set in a specific range, the intermediate layer is formed of a resin material that includes a high-acid ionomer, the Shore C hardness relationships among the core center and the surfaces of the envelope-encased layer and the intermediate layer-encased sphere satisfy specific conditions; and the ball has a deflection when compressed under a given load which is at least 2.7 mm. This ball achieves a good distance on shots with a driver, utility club or iron, is receptive to spin in the short game, and has a soft feel at impact on all shots, making it useful to amateur golfers.

A golf ball with a cover layer composed of a blend of non- or partially neutralized copolymeric or terpolymeric ionomer(s), hydroxyl-functionalized styrenic block copolymer and silane coupling agent (SCA). The amount of SCA is preferably between 0.01 and 2.0 weight percent based on the total weight of the polymer composition. The cover layer preferably has a Shore A hardness less than 90.

A method for forming a golf ball core with a nanofiller masterbatch is disclosed herein. The method includes mixing the nanofiller masterbatch, a graphene masterbatch material with other materials to form a core mixture, wherein the masterbatch preferably comprises 1-80% by weight of nanofillers and 20-99% by weight of a carrier polymer.

A golf ball with a core comprising polybutadiene and graphene is disclosed herein. The golf ball has a single core comprising polybutadiene and graphene. Alternatively, the golf ball has a dual core with an inner core comprising polybutadiene and graphene. Alternatively, the golf ball has a dual core with an outer core comprising polybutadiene and graphene.

In a golf ball having a core, envelope layer, intermediate layer and cover, the (core diameter)/(ball diameter) value falls within a particular range, the core has a specific hardness profile, and the Shore C hardness relationships among the core center and surface hardnesses and the surface hardnesses of the envelope layer-encased sphere, intermediate layer-encased sphere and ball satisfy the following conditions:

core surface hardness<surface hardness of envelope layer-encased sphere<surface hardness of intermediate layer-encased sphere>ball surface hardness,  (1)

(surface hardness of envelope layer-encased sphere)−(core center hardness)≥28.  (2)

Also, the envelope layer, intermediate layer and cover have respective thicknesses which satisfy the condition:

cover thickness<intermediate layer thickness envelope layer thickness.  (3)

This ball enables mid-level and skilled amateur golfers to achieve superior distances on driver shots and on iron shots, and moreover has a soft yet good feel at impact.