Patent classifications
B01D3/34
Process and device for reducing environmental contaminates in heavy marine fuel oil
A process and device for reducing the environmental contaminants in a ISO 8217 compliant Feedstock Heavy Marine Fuel Oil, the process involving: mixing a quantity of the Feedstock Heavy Marine Fuel Oil with a quantity of Activating Gas mixture to give a feedstock mixture; contacting the feedstock mixture with one or more catalysts to form a Process Mixture from the feedstock mixture; separating the Product Heavy Marine Fuel Oil liquid components of the Process Mixture from the gaseous components and by-product hydrocarbon components of the Process Mixture and, discharging the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil is compliant with ISO 821 7 for residual marine fuel oils and has a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05% wt. to 0.5% wt. The Product Heavy Marine Fuel Oil can be used as or as a blending stock for an ISO 8217 compliant, IMO MARPOL Annex VI (revised) compliant low sulfur or ultralow sulfur heavy marine fuel oil.
Polymerization Inhibitor for Silane
A polymerization inhibitor for a silane enables purification of the silane to a high degree because a polymer is not formed even when heating to distill the silane, even when a cyclic silane monomer is present. A high-purity cyclic silane composition is obtained, in particular high-purity cyclopentasilane, that can be polymerized and applied onto a substrate as a coating-type polysilane composition and fired to produce a good silicon thin film with high conductivity. The polymerization inhibitor includes a secondary or tertiary aromatic amine. The aromatic group is a phenyl group or a naphthyl group. The polymerization inhibitor is present in a proportion of 0.01 to 10 mol % per mole of the silane. In the polymerization inhibitor, a boiling point of the aromatic amine is 196° C. or higher.
Polymerization Inhibitor for Silane
A polymerization inhibitor for a silane enables purification of the silane to a high degree because a polymer is not formed even when heating to distill the silane, even when a cyclic silane monomer is present. A high-purity cyclic silane composition is obtained, in particular high-purity cyclopentasilane, that can be polymerized and applied onto a substrate as a coating-type polysilane composition and fired to produce a good silicon thin film with high conductivity. The polymerization inhibitor includes a secondary or tertiary aromatic amine. The aromatic group is a phenyl group or a naphthyl group. The polymerization inhibitor is present in a proportion of 0.01 to 10 mol % per mole of the silane. In the polymerization inhibitor, a boiling point of the aromatic amine is 196° C. or higher.
DEFOAMING AGENT
There is provided a defoaming agent having excellent defoaming persistence. The defoaming agent includes; hydrophobic silica having a hydrophobicity (M.sub.X) of 50 to 85, and a rate of change (M.sub.Y/M.sub.X) of a hydrophobicity (M.sub.Y) after immersion for 1 hour in a methanol/ion-exchange aqueous solution (volume ratio of 80/20) of sodium hydroxide with a pH of 13 at 25° C. to the hydrophobicity (M.sub.X) of 0.8 to 1.0; and at least one kind of liquid selected from the group consisting of a hydrocarbon oil, a non-reactive silicone oil and a polyoxyalkylene compound.
DEFOAMING AGENT
There is provided a defoaming agent having excellent defoaming persistence. The defoaming agent includes; hydrophobic silica having a hydrophobicity (M.sub.X) of 50 to 85, and a rate of change (M.sub.Y/M.sub.X) of a hydrophobicity (M.sub.Y) after immersion for 1 hour in a methanol/ion-exchange aqueous solution (volume ratio of 80/20) of sodium hydroxide with a pH of 13 at 25° C. to the hydrophobicity (M.sub.X) of 0.8 to 1.0; and at least one kind of liquid selected from the group consisting of a hydrocarbon oil, a non-reactive silicone oil and a polyoxyalkylene compound.
Process for removing light components from an ethylene stream
A process for removing light components from an ethylene stream may include providing a dried ethylene stream containing ethylene, ethane, CO, CO.sub.2, H.sub.2, CH.sub.4, and C.sub.3+ hydrocarbons. The process may include sending the dried ethylene stream to a stripper to produce an overhead stream containing ethylene, CO, H.sub.2 and CH.sub.4, and a bottom stream containing ethylene, ethane, CO.sub.2, and C.sub.3+ hydrocarbons. The gaseous phase on top of the stripper may be condensed in a heat exchanger cooled by a refrigerant stream to get a first gaseous phase and a first liquid phase. The first gaseous phase may be condensed in a heat exchanger cooled by liquid ethane or liquid ethylene to get a second gaseous phase containing ethylene CO, H.sub.2 and CH.sub.4 and a second liquid phase. The first and second liquid phases may be the reflux of the stripper.
Method for refining dicyclopentadiene
A first method for refining dicyclopentadiene of the present invention is characterized in that the method separates and recovers dicyclopentadiene by distilling the crude dicyclopentadiene that contains dicyclopentadiene and is obtained by removing a C5 fraction and a BTX fraction from the reaction product obtained by dimerization reaction of the cracked gasoline by-produced in an ethylene plant that uses as feed stock a C2 fraction, a C3 fraction and a C4 fraction. A second method for refining dicyclopentadiene of the present invention is characterized in that the dicyclopentadiene-containing fraction refined by distillation is brought into contact with an inert gas or a hydrocarbon gas having 1 to 3 carbon atoms.
EVAPORATION SYSTEM, EVAPORATION METHOD, AND SEALING SYSTEM
An evaporating system for separating at least two liquids mixed with one another includes a reactor vessel for receiving the mixture from an inlet, the mixture having a mixture level in the reactor vessel, a blowing-in device for blowing a gaseous aerating agent into the mixture and absorbing the first liquid, a heating device for heating the mixture, an outlet for discharging the aerating agent and the absorbed first liquid, and an inlet for introducing a gaseous fluid above the mixture level to generate a gaseous transport stream to the outlet.
EVAPORATION SYSTEM, EVAPORATION METHOD, AND SEALING SYSTEM
An evaporating system for separating at least two liquids mixed with one another includes a reactor vessel for receiving the mixture from an inlet, the mixture having a mixture level in the reactor vessel, a blowing-in device for blowing a gaseous aerating agent into the mixture and absorbing the first liquid, a heating device for heating the mixture, an outlet for discharging the aerating agent and the absorbed first liquid, and an inlet for introducing a gaseous fluid above the mixture level to generate a gaseous transport stream to the outlet.
Effective novel non-polymeric and non-fouling additive for inhibiting high-temperature naphthenic acid corrosion and method of using the same
The present invention relates to inhibition of high temperature naphthenic acid corrosion occurring in hydrocarbon processing units. The invention provides an effective novel non-polymeric and non-fouling additive for inhibiting high-temperature naphthenic acid corrosion, comprising an effective corrosion-inhibiting amount of a second phosphate ester wherein said second phosphate ester is obtained by reacting a first phosphate ester with an oxirane compound selected from the group consisting of butylene oxide, ethylene oxide, propylene oxide or any other oxirane compound or a combination thereof, preferably with butylene oxide, capably yielding said second phosphate ester, having a structure A or B, ##STR00001##
wherein R.sup.1 and R.sup.2 are each independently selected from the group consisting of moieties having 1 to 20 carbon atoms and R.sup.1 and R.sup.2 may be identical or different, X is H, CH.sub.3 or C.sub.2H.sub.5; and n may vary from 1 to 20,
wherein said first phosphate ester is having a structure I or II, ##STR00002##
wherein R.sup.1 and R.sup.2 are each independently selected from the group consisting of moieties having 1 to 20 carbon atoms and R.sup.1 and R.sup.2 may be identical or different, said first phosphate ester being obtained as a reaction product of reaction of an alcohol with a phosphorous pentaoxide.