The invention provides a clog-free condensation system for a pyrolysis apparatus used in the thermal degradation of waste plastics that contain polyethylene terephthalate (PET). A conduit carries vapor from a pyrolysis reactor to a condenser having an inlet for an oil-immiscible solvent stream; a liquid outlet for removal of the oil-immiscible solvent, benzoic acid, and other condensed pyrolysates; and a vapor outlet to pass uncondensed vapors. A liquid-liquid phase separator connected to the liquid outlet continuously separates the two immiscible phases. Benzoic acid is precipitated and removed from the oil-immiscible phase, and the oil-immiscible solvent is returned to the condenser as a solvent stream. The invention provides a method for condensing PET pyrolysis vapors without formation of clogs in the condensation apparatus, and provides a method for the continuous recovery of benzoic acid and other condensable pyrolysates from a PET-containing waste plastic stream.

A system and method for processing unconditioned syngas first removes solids and semi-volatile organic compounds (SVOC), then removes volatile organic compounds (VOC), and then removes at least one sulfur containing compound from the syngas. Additional processing may be performed depending on such factors as the source of syngas being processed, the products, byproducts and intermediate products desired to be formed, captured or recycled and environmental considerations.

A cooling system utilizes an organic ionic salt composition for dehumidification of an airflow. The organic ionic salt composition absorbs moisture from an inlet airflow to produce an outlet airflow with a reduce moisture from that of the inlet airflow. The organic ionic salt composition may be regenerated, wherein the absorbed moisture is expelled by heating with a heating device. The heating device may be an electrochemical heating device, such as a fuel cell, an electrochemical metal hydride heating device, an electrochemical heat pump or compressor, or a condenser of a refrigerant cycle, which may utilize an electrochemical pump or compressor. The efficiency of the cooling system may be increased by utilization of the waste heat the cooling system. The organic ionic salt composition may circulate back and forth or in a loop between a conditioner, where it absorbs moisture, to a regenerator, where moisture is desorbed by heating.

Provided is a process for separating an organic isocyanate prepared by reacting an organic amine with a stoichiometric excess of phosgene in the gas phase from the gaseous crude product obtained in the reaction, the process comprising the steps of (i) at least partially condensing the crude product stream containing at least the isocyanate, hydrogen chloride and unconverted phosgene by contacting with at least one liquid stream containing at least one quench liquid in a first separation apparatus to obtain a liquid stream containing at least some of the quench liquid and some of the isocyanate and a gas stream containing at least hydrogen chloride, evaporated quench liquid and phosgene, (ii) discharging the liquid stream obtained in step (i) via a first liquid outlet and of the gas stream obtained in (i) via a first gas conduit and (iii) at least partially condensing and/or absorbing the gas stream discharged in step (ii) through the first gas conduit, wherein that the at least partial condensation and/or absorption is effected in step (iii) by direct introduction of at least one cooling fluid, wherein the cooling fluid is introduced directly into the first gas conduit via at least one addition unit assigned to the first gas conduit.

A method for removing solvent from a solvent containing sweep gas stream obtained from a fertilizer coating process is disclosed. The method can include directly contacting the solvent containing sweep gas stream with an aqueous composition comprising 50% wt/wt to 100% wt/wt of water, condensing at least a portion of the solvent out of the solvent containing sweep gas stream into the aqueous composition to produce a solvent-enriched aqueous composition and a recovered sweep gas stream, and removing the recovered sweep gas stream from the solvent-enriched aqueous composition.

The disclosure pertains to a urea production process comprising concentrating a first urea solution in a first vacuum evaporator in an evaporation section to give a urea melt and first vapor, and condensing said first vapor in a first condensation section, wherein the first condensation section is a chilled condensation section.

This disclosure describes single and multi-layer woven meshes designed to enable sucking flow condensation and capillary-driven liquid film boiling, respectively, for instance, in use in heat spreaders. The single-layer woven meshes can include a nanostructure coating and a hydrophobic coating, while the multi-layer meshes can include a microcavity coating and optionally a hydrophilic coating.

A method may include: heating a hydrocarbon contaminated waste in a first heating unit, vaporizing at least a portion of water and hydrocarbons in the hydrocarbon contaminated waste and generating: a first vaporized stream and a first bottoms stream, heating the first bottoms stream in a second heating unit; vaporizing at least a portion of hydrocarbons in the first bottoms stream and generating: a second vaporized stream and a second bottoms stream, condensing the first vaporized stream to form a first condensed stream; and condensing the second vaporized stream to form a second condensed stream.

Apparatuses for removal of solids from water comprising a heater for heating an immiscible liquid (IL), a humidifier having porous sheets allowing direct contact between the IL and water, thereby separating the solids by evaporating the water into cool dry air flowing past the porous sheets, and a dehumidifier comprising porous sheets that allow direct contact between the cool IL and hot moist air flowing past the porous sheets, thereby condensing fresh water from the moist air. Also disclosed are methods for removal of solids from water by heating an IL, distributing the IL to porous sheets in a humidifier, distributing water with dissolved solids to the porous sheets, separating the solids from the water by evaporating the water into dry air flowing past the porous sheets, and condensing fresh water by flowing the moist air past porous sheets in a dehumidifier having cool IL distributed to the porous sheets.

A system and method for processing unconditioned syngas first removes solids and semi-volatile organic compounds (SVOC), then removes volatile organic compounds (VOC), and then removes at least one sulfur containing compound from the syngas. Additional processing may be performed depending on such factors as the source of syngas being processed, the products, byproducts and intermediate products desired to be formed, captured or recycled and environmental considerations.