Disclosed is an external circulating slurry reactive crystallizer, including a riser, a degassing zone and a downcomer. A lower end of the riser is communicated with a gas inlet pipe, a liquid inlet pipe and a solid feeding pipe, while an upper end of the riser is communicated with a lower end of the degassing zone. An upper end of the downcomer is integrally fixed to a sidewall of the degassing zone. At least one hydrocyclone is arranged at a lower end of the downcomer. The hydrocyclone is provided with an overflow port at an upper end thereof and an underflow port and a valve at a lower end thereof. The overflow port is communicated with the riser. The crystallizer can simultaneously realize reaction, crystallization and separation for continuous production with low cost, regulating and controlling the particle size distribution and morphology of crystals.

A hybrid process and system for separating water from an inlet brine solution is disclosed. The hybrid process couples at least two different separation processes/systems. The inlet brine solution is fed into a first separation process, which produces a water distillate and a brine concentrate. The brine concentrate from the first separation process is then fed into the second separation process to further recover additional water. The excess heat from the second separation process is supplied to the first separation process.

An industrial waste salt resourceful treatment method comprises the following steps: the industrial waste salt is sequentially subject to dissolving, chemical pre-purification, deep purification, organic matter concentration reduction, adsorption and oxidation decolorization and multi-effect evaporative crystallization to respectively obtain sodium sulfate, sodium chloride and sodium nitrate crystals; the crystallization temperature of sodium sulfate is in a range of 75° C. to 85° C.; the crystallization temperature of sodium chloride is in a range of 60 to 70° C.; and the crystallization temperature of sodium nitrate is in a range of 45° C. to 55° C. An industrial waste salt resourceful treatment device is further provided.

Methods and systems for forming crystallized products from solutions. Such a method includes depositing an input material in a solvent mixture comprising a solvent and an anti-solvent, increasing the temperature of the solvent mixture with the input material therein to an elevated temperature for a period of time sufficient to fully dissolve the input material in the solvent mixture to form a solution of the material, and performing a series of temperature cycles on the solution to produce a crystallized product from the material in the solution. The solution is alternated between heating cycles and cooling cycles based on the turbidity of the solution, and the solution is filtered to remove and collect the crystallized product therefrom.

A process to treat water includes adding a salt-forming base to the water thereby producing saline water, or thereby forming a salt in the water which is different from a salt that the water started out with, if the water started out as saline. The saline water is treated, at a temperature T1 which is above the saturation temperature of the saline water, in a first membrane separation stage to provide clean water and a first brine, the salinity of the first brine being higher than the salinity of the saline water. The first brine is cooled to a temperature T2 to precipitate some of the salt from the first brine and the precipitated salt is separated from the first brine producing a second brine, the temperature T2 being below the temperature T1 but above the freezing temperature of the first brine. The second brine is treated at a temperature T3 above the saturation temperature of the second brine in a second membrane separation stage to provide clean water and a third brine. The salt-forming base, the temperature T1 and the temperature T2 are selected so that the salt which is formed in the saline water has a solubility in water at the temperature T1 which is at least 1.5 times the solubility of the salt in water at the temperature T2.

A chemical reaction device that supplies a raw material liquid into a solution and causes particles to precipitate in the solution is provided. The chemical reaction device includes an agitation tank configured to accommodate the solution, an impeller configured to agitate the solution, and a plurality of discharge parts configured to discharge the raw material liquid into the solution.

An improved method for making cannabinoids from plant material utilizes the following steps. Plant material is contacted with an aqueous alkaline solution containing a hydroxide base and essentially no organic solvents, thereby extracting cannabinoids including carboxylic acids and salts and producing an alkaline extract. Non-soluble plant material is removed from the alkaline extract to produce a clarified alkaline extract. The extracted cannabinoids are decarboxylated and the decarboxylated cannabinoids are crystallized/precipitated from the clarified alkaline extract at a pH greater than 7.

The present invention relates to the process of purification of boric acid by ion exchange method. Boric acid is dissolved in hot demineralized water. The hot solution is pressure-filtered. The hot saturated solution, which is purified from water-insoluble, is passed through a column containing strong cation exchange resin, followed by a column containing weak anion exchange resin at the same temperature and cooled afterwards. The crystals settling by cooling are separated from the mother liquor, the amount of aqueous solution within them is reduced and then dried. The waste solution formed during crystallization and filtrate formed after separation of crystals from aqueous solution are mixed and used in boric acid dissolving process. The developed method enables the reduction of sodium, sulfate, chloride and iron impurities of technical grade boric acid to less than 1 ppm and is more economic and environmental friendly than current methods.

Provided is a technique for continuously performing poor solvent crystallization or reactive crystallization. A porous membrane in which multiple pores through which a liquid passes are formed internally partitions the treatment container into a first flow space and a second flow space. A raw material liquid supply unit continuously supplies a raw material liquid to the first flow space. A treatment liquid supply unit continuously supplies a treatment liquid to the second flow space at a pressure at which the treatment liquid passes through the porous membrane and enters the first flow space. An extraction unit continuously extracts a mixed liquid of the raw material liquid and the treatment liquid from the first flow space. An aging unit precipitates and grows crystals of a target substance from a mixed liquid.

A device and method for increasing solid holdup in a reaction crystallizer are disclosed. The device includes a discharge pipe, a clear liquid pipe, a clear liquid tank and a gas collecting pipe. A lower end of the discharge pipe is inserted into the crystallizer below the liquid level, while that of the clear liquid pipe is inserted into the clear liquid tank below the liquid level. By using the gas collecting pipe, the reaction crystallizer and the clear liquid tank are communicated all the time. When feeding, a liquid-solid mixture in the crystallizer automatically enters the discharge pipe and flows upward slowly therein, during which solid particles gradually settle down and automatically fall back into the crystallizer while the clear liquid keeps on flowing upward, enters the clear liquid pipe and thereby flows into the clear liquid tank. The clear liquid tank maintains a constant liquid level via overflowing.