The invention relates to carbon supported crack- and tear-free graphene membranes of large area useful for selective gas separation, method of preparation and uses thereof. In particular, the invention relates to carbon supported crack- and tear-free graphene membranes having good gas separation performance, in particular high H.sub.2 permeance and H.sub.2/CH.sub.4 selectivities.

The invention relates to carbon supported crack- and tear-free graphene membranes of large area useful for selective gas separation, method of preparation and uses thereof. In particular, the invention relates to carbon supported crack- and tear-free graphene membranes having good gas separation performance, in particular high H.sub.2 permeance and H.sub.2/CH.sub.4 selectivities.

An object of the present invention is to provide a filtering device which makes it possible to obtain a chemical liquid having excellent performance and enables filter media to have sufficiently long pot life. Another object of the present invention is to provide a purification device, a chemical liquid manufacturing device, a filtered substance to be purified, a chemical liquid, and an actinic ray-sensitive or radiation-sensitive resin composition. A filtering device according to an embodiment of the present invention has a first filter unit including a first filter, which satisfies at least one condition selected from the group consisting of following conditions 1 to 3, and a housing accommodating the first filter and a second filter unit including a second filter different from the first filter and a housing accommodating the second filter, in which the first filter unit and the second filter unit are independently disposed in a pipe line through which a substance to be purified is supplied. Condition 1: the filter has a filter medium including two or more layers containing materials different from each other. Condition 2: the filter has a filter medium including two or more layers having different pore structures. Condition 3: the filter has a filter medium including one layer in which different materials are mixed together.

An object of the present invention is to provide a filtering device which makes it possible to obtain a chemical liquid having excellent performance and enables filter media to have sufficiently long pot life. Another object of the present invention is to provide a purification device, a chemical liquid manufacturing device, a filtered substance to be purified, a chemical liquid, and an actinic ray-sensitive or radiation-sensitive resin composition. A filtering device according to an embodiment of the present invention has a first filter unit including a first filter, which satisfies at least one condition selected from the group consisting of following conditions 1 to 3, and a housing accommodating the first filter and a second filter unit including a second filter different from the first filter and a housing accommodating the second filter, in which the first filter unit and the second filter unit are independently disposed in a pipe line through which a substance to be purified is supplied. Condition 1: the filter has a filter medium including two or more layers containing materials different from each other. Condition 2: the filter has a filter medium including two or more layers having different pore structures. Condition 3: the filter has a filter medium including one layer in which different materials are mixed together.

A forward osmosis membrane having a low water resistance and an excellent mechanical strength includes a support unit and a selective layer. The support unit includes a plurality of nanostructures, and has opposite first and second surfaces which are defined by the nanostructures. Each of the nanostructures includes a carbon nanotube and a hydrophilic film coated around the carbon nanotube. The hydrophilic film includes a first hydrophilic polymeric material and a second hydrophilic polymeric material. The second hydrophilic polymeric materials of the nanostructures are cross-linked. The selective layer covers and contacts the first surface of the support unit.

A forward osmosis membrane having a low water resistance and an excellent mechanical strength includes a support unit and a selective layer. The support unit includes a plurality of nanostructures, and has opposite first and second surfaces which are defined by the nanostructures. Each of the nanostructures includes a carbon nanotube and a hydrophilic film coated around the carbon nanotube. The hydrophilic film includes a first hydrophilic polymeric material and a second hydrophilic polymeric material. The second hydrophilic polymeric materials of the nanostructures are cross-linked. The selective layer covers and contacts the first surface of the support unit.

The invention, belonging to the field of membrane technology, presents a method for the direct growth of ultrathin porous graphene separation membranes. Etching agent, organic solvent and polymer are coated on metal foil, and then they are calcined at high temperature in absence of oxygen; after removal of metal substrate and reaction products, single-layered or multi-layered porous graphene membranes are obtained. Alternatively, the dispersion or solution of etching agent is coated on metal foil, on which a polymer film is then overlaid. The obtained sample is subsequently calcined at high temperature in absence of oxygen; after removal of metal substrate and reaction products, single-layered or multi-layered porous graphene membranes are obtained. The method involved in this invention is simple and highly efficient, and allows direct growth of ultrathin porous graphene separation membranes, without needing expensive apparatuses, chemicals and graphene raw material. Additionally, the graphene membranes prepared with this method have controlled pore size, ultrahigh water flux and strong resistance to irreversible fouling.

The invention, belonging to the field of membrane technology, presents a method for the direct growth of ultrathin porous graphene separation membranes. Etching agent, organic solvent and polymer are coated on metal foil, and then they are calcined at high temperature in absence of oxygen; after removal of metal substrate and reaction products, single-layered or multi-layered porous graphene membranes are obtained. Alternatively, the dispersion or solution of etching agent is coated on metal foil, on which a polymer film is then overlaid. The obtained sample is subsequently calcined at high temperature in absence of oxygen; after removal of metal substrate and reaction products, single-layered or multi-layered porous graphene membranes are obtained. The method involved in this invention is simple and highly efficient, and allows direct growth of ultrathin porous graphene separation membranes, without needing expensive apparatuses, chemicals and graphene raw material. Additionally, the graphene membranes prepared with this method have controlled pore size, ultrahigh water flux and strong resistance to irreversible fouling.

Disclosed is the preparation of composite membranes formed by a tailored selective chemical modification of an ultra-thin nanoporous surface layer of a semi-crystalline mesoporous poly (aryl ether ketone) membrane with graded density pore structure. The composite separation layer is synthesized in situ on the poly (aryl ether ketone) substrate surface and is covalently linked to the surface of the semi-crystalline mesoporous poly (aryl ether ketone) membrane. Hollow fiber configuration is the preferred embodiment of forming the functionalized the poly (aryl ether ketone) membranes. Composite poly (aryl ether ketone) membranes of the present invention are particularly useful for a broad range of fluid separation applications, including organic solvent ultrafiltration and nanofiltration to separate and recover active pharmaceutical ingredients.

A composite membrane suitable for separating a gas from a gas mixture comprising a selective layer coated on a support, wherein said selective layer comprises: a) a polymeric matrix comprising an amine polymer; b) a graphene oxide nanofiller; and c) a mobile carrier selected from an ionic liquid or an amino acid salt.