A semipermeable arrangement for use in clinical, agricultural, industrial and/or environmental settings. The semipermeable arrangement has a structural arrangement formed from a material such as ePTFE that has an affinity to a lubricating fluid such as perfluorocarbon. The structural arrangement may be infused with a lubricating fluid such that the semipermeable arrangement resists fouling. The semipermeable arrangement is further arranged with barriers to prevent or limit the movement of the lubricating fluid through at least part of the structural arrangement. The semipermeable arrangement further has passageways that are free from the presence of, and/or cannot be infused with, lubricating fluid. The passageways permit the movement of fluids such as air, water and dissolved substances through the structural arrangement. The semipermeable arrangement is thereby both self-cleaning and porous and has a wide range of uses.

Disclosed are selectively-permeable membranes and components configured for selective permeation of a specified gas, such as oxygen, therethrough, methods for making the same and methods for using the same, for example, to implement fuel cells and electrochemical cells.

Systems, devices and methods for molecular separation including a molecular separation device comprising at least a polycrystalline metal-organic framework (MOF) and a nanocrystalline, zeolite MFI, wherein the MOF forms a polycrystalline membrane with zeolite MFI nanoparticles dispersed therein, and the MOF membrane matrix contacting and surrounding the zeolite MFI nanoparticles form a permselective nanoporous structure.

The present invention relates to CO.sub.2 capture from gas mixtures by use of gas separation membranes. In particular, the invention relates to a gas separation membrane comprising: a gas permeable or porous support layer; and at least one CO.sub.2 selective polymer layer comprising carbonic anhydrase (CA) enzymes fixed within the at least one CO.sub.2 selective polymer layer. The present invention also relates to the method of separating CO.sub.2 from a gas and to the use of the gas separation membrane.

The objective of the present invention is to provide a composite separation membrane which is excellent in not only a liquid permeable performance and a separation performance relatively but also a durability and which is particularly useful as a membrane for liquid treatment, and a method for treating a liquid by using the composite separation membrane. The composite separation membrane according to the present invention is characterized in comprising a supporting base material and a complex layer, wherein the complex layer is placed on the supporting base material, the complex layer comprises oxidized metal nanosheets, graphene oxide and an alkanolamine, and at least one of the alkanolamine is present between the oxidized metal nanosheets.

Functionalized membranes are produced via grafting of polymer brushes to the membrane surface for use, e.g., in separation and purification of biomolecules. One or more initiators are attached to the membrane surface. A reactant substrate, such as a copper metal plate, is placed adjacent the membrane. A reaction medium is then provided in fluid contact with the membrane and the reactant substrate, the reaction medium including one or more monomers, one or more ligands, and one or more solvents. The polymer brushes are grown on the membrane via Cu(0)-mediated controlled radical polymerization involving the reactant substrate and the reaction medium. This reaction process uses fewer numbers and amounts of chemicals compared to other controlled radical polymerization reactions such as ATRP. The reaction can take place at room temperature, which is more energy efficient than other CRPs which occur at a much higher temperatures. The reaction process described herein is also sixteen times faster than the standard ATRP method without sacrificing subsequent separation performance.

Provided are catalytic assemblies which include a hollow fiber membrane permeable to a gas; a reactive coating permeable to the gas and a contaminant; and a plurality of catalytic nanoparticles embedded in the reactive coating adapted to catalyze a reaction between the gas and the contaminant. Also provided are preparation methods for the catalytic assemblies, and use thereof for treating contaminated water.

A process is provided of making facilitated transport membrane comprising a relatively hydrophilic, very small pore, nanoporous support membrane, a hydrophilic polymer inside the very small nanopores on the skin layer surface of the support membrane, a thin, nonporous, hydrophilic polymer layer coated on the surface of the support membrane, and metal salts incorporated in the hydrophilic polymer layer coated on the surface of the support membrane and the hydrophilic polymer inside the very small nanopores. In addition, the process provides a new method of making facilitated transport membrane spiral wound elements or hollow fiber modules for olefin/paraffin separations, particularly for C3=/C3 and C2=/C2 separations.

A mixed matrix membrane comprises a support structure. The support structure comprises a glassy polymer matrix, and nanodiamond particles dispersed within the glassy polymer matrix. A gas separation membrane apparatus, a gaseous fluid treatment system, and a method of forming a mixed matrix membrane are also described.

Compositions, devices, and methods for sensing free radicals such as hydroxyl radicals, involving cerium oxide nanoparticles on a carbon-based substrate, are described.