Disclosed herein are polycationic microfibers comprising a high-aspect-ratio polymeric core, the polymeric core comprising a blend of a first core polymer and a second core polymer, and a polycationic polymer immobilized on the surface of the polymeric core. The polycationic microfibers are capable of sequestering or clearing nucleic acids, proteins, biomolecular complexes, exosomes, or microparticles from solutions and samples and may be formed into filters or integrated into filtration apparatuses. Also disclosed are methods for sequestering or clearing solutes from solutions and fluids, methods for the treatment of diseases or conditions, and methods for the prevention of diseases or conditions.

In at least one embodiment, a microporous membrane having a moderate to high water vapor permeability and high liquid water penetration resistance is disclosed. The microporous membrane may be used in building applications, including as or as part of a building wrap, a rain screen, a roofing underlayment, a flashing, a sound proofing material, or an insulation material. The microporous membrane may include at least one thermoplastic polymer, at least one filler, and at least one processing oil. The microporous membrane may be flat or may have ribs. The microporous membrane may include at least one scrim component. A method for forming the microporous membrane is also disclosed.

The disclosure discloses an anti-haze anti-harmful gas air filter membrane as well as a preparation method and application thereof. The air filter membrane comprises a nano fiber membrane made of nano fibers and having a two-dimensional or three-dimensional network structure. The nano fiber membrane can be a high-molecular polymer nano fiber membrane prepared by utilizing an electrostatic spinning process, and can also be doped with an organic or inorganic additive capable of adsorbing and absorbing harmful gases, such as VOCs, NO.sub.x, SO.sub.x and NH.sub.3, in the air and/or a photocatalyst capable of degrading these harmful gases in a photocatalysis manner, or the like. The anti-haze anti-harmful gas air filter membrane disclosed by the disclosure can efficiently filter PM2.5 and PM10 particulate pollutants and the like in the air and simultaneously can efficiently identify and clear multiple harmful gases in the air. The anti-haze anti-harmful gas air filter membrane has a wide application prospect in the field of air purification, for example, can be applied to air purification devices, such as screen windows, gauze masks and filter screens.

Membranes, methods of making the membranes, and methods of using the membranes are described herein. The membranes can comprise a support layer, and a selective polymer layer disposed on the support layer. The selective polymer layer can comprise an oxidatively stable carrier and a borate additive dispersed within a hydrophilic polymer matrix. The oxidatively stable carrier can comprise a quaternaryammonium hydroxide carrier (e.g., a mobile carrier such as a small molecule quaternaryammonium hydroxide, or a fixed carrier such as a quaternaryammonium hydroxide-containing polymer), a quaternaryammonium fluoride carrier (e.g., a mobile carrier such as a small molecule quaternaryammonium fluoride, or a fixed carrier such as a quaternaryammonium fluoride-containing polymer), or a combination thereof. The borate additive can comprise a borate salt, a boric acid, or a combination thereof. The membranes can exhibit selective permeability to gases. As such, the membranes can be for the selective removal of carbon dioxide and/or hydrogen sulfide from hydrogen and/or nitrogen.

A polymerizable composition for forming an ion-exchange resin precursor, the polymerizable composition containing a monomer component and polyethylene particles in an amount of 50 to 120 parts by mass per 100 parts by mass of the monomer component, wherein the monomer component contains an aromatic monomer for introducing ion-exchange groups and a nitrogen-containing aliphatic monomer, the nitrogen-containing aliphatic monomer being present in an amount of 10 to 35% by mass in said monomer component. An ion-exchange membrane is produced by applying the polymerizable composition onto a polyolefin type filament base material and polymerizing the polymerizable composition to form an ion-exchange resin precursor and, thereafter, introducing ion-exchange groups into the precursor.

The invention is related to a super-hydrophilic/underwater super-oleophobic attapulgite separation membrane, and a preparation method and use thereof. Monodispersed hydrophilic nanoparticulates are loaded on a surface of nanoparticles, to obtain a super-hydrophilic nanocomposite material with a micro-nanostructure. The nanocomposite material is dispersed in a mixed aqueous solution of polyacrylamide and methyl cellulose, to obtain a membrane-forming slurry after vigorous stirring. A disc-shaped porous support is infiltrated with water and placed on a horizontal surface, and then a certain volume of the membrane-forming slurry is slowly and uniformly drip-coated on a surface of the support, dried and sintered to obtain a super-hydrophilic/underwater super-oleophobic microfiltration membrane layer.

Disclosed herein are multi-layer structures comprising a first composite layer disposed over a second composite layer, wherein the first composite layer contains a first active material dispersed in a first polymer containing an elastomeric polymer and the second composite layer contains a second polymer which may have a second active material dispersed therein, wherein the first active material chemically or physically interacts with at least one toxic chemical and is selected from the group consisting of metal-organic frameworks (MOFs), metal oxides, metal hydroxides, zeolites, and combinations thereof, and wherein the active material and the second active material (if present) are the same as or different from each other, and the first polymer and second polymer are the same as or different from each other, subject to the proviso that the first composite layer and the second composite layer compositionally differ from each other in at least one respect.

A bipolar membrane comprising a cation exchange mat of one or more cation exchange polymers, an anion exchange mat of one or more anion exchange polymers, and an internal 3D bipolar interface, disposed between the cation and anion exchange layers, including a mixture of at least one cation exchange polymer and at least one anion exchange polymer, such that an interface of the at least one cation exchange polymer and the at least one anion exchange polymer is the internal 3D bipolar interface that has a large area, and the at least one cation exchange polymer in the 3D bipolar interface is connected to the one or more cation exchange polymers of the cation exchange layer, and the at least one anion exchange polymer in the 3D bipolar interface is connected to the one or more anion exchange polymers of the anion exchange layer.

Compositions, devices, and methods relating to the use of mixed-matrix membranes containing metal-organic frameworks to separate gases are generally described. In some embodiments, branched nanoparticles made at least in part of metal-organic frameworks are described. In some embodiments, the morphology and size of the branched nanoparticles are controlled by the presence of a chemical modulator during synthesis. In some embodiments, the branched nanoparticles are uniformly distributed in a mixed-matrix membrane. In some embodiments, the mixed-matrix membrane is configured to separate one or more gases from a gas mixture. In some embodiments, the branched nanoparticles contribute at least in part to an increase in permeability, selectivity, and/or resistance to plasticization of the mixed-matrix membrane.

A vesicle in a liquid composition including an amphiphilic diblock copolymer of the PMOXA.sub.a-b-PDMS.sub.c-d type as vesicle membrane forming material, further including as an additive from about 0.05% to about 1% v/v of reactive end group functionalised PDMS.sub.e-f, and a transmembrane protein. The vesicle optionally includes about 1 to about 12% v/v of triblock copolymer of the PMOXA.sub.a-b-PDMS.sub.c-d-PMOXA.sub.a-b type as membrane forming material.