Patent classifications
B01D69/14
Reinforced oil-absorptive membrane material, unit and preparation method thereof
A reinforced oil-absorptive membrane material, includes: a tubular support (101) and an oil absorbing layer (102) provided on a surface of the tubular support (101), wherein a plurality of holes are provided on the tubular support (101); and the oil absorbing layer (102) is a piece of nonwoven fabric with a polymer layer provided thereon. The reinforced oil-absorptive membrane material has an excellent oil-absorbing and supportive performance, and is capable of being utilized continuously in a negative pressure suction manner and thus shows high oil absorption efficiency. A method for manufacturing the reinforced oil-absorptive membrane material including pre-treating the nonwoven fabrics by aqueous alkali, covering a membrane casting solution including a solvent, a graphene, polyvinylidene fluoride, pore-forming agent and inorganic particle, and then solidifying and extracting to obtain the oil-absorbing layer.
FILMS DERIVED FROM TWO OR MORE CHEMICALLY DISTINCT BLOCK COPOLYMERS, METHODS OF MAKING SAME, AND USES THEREOF
Methods of making blended, isoporous, asymmetric (graded) films (e.g. ultrafiltration membranes) comprising two or more chemically distinct block copolymers and blended, isoporous, asymmetric (graded) films (e.g. ultrafiltration membranes) comprising two or more chemically distinct block copolymers. The generation of blended membranes by mixing two chemically distinct block copolymers in the casting solution demonstrates a pathway to advanced asymmetric block copolymer derived films, which can be used as ultrafiltration membranes, in which different pore surface chemistries and associated functionalities can be integrated into a single membrane via standard membrane fabrication, i.e. without requiring laborious post-fabrication modification steps. The block copolymers may be diblock, triblock and/or multiblock mixes and some block copolymers in the mix may be functionally modified. Triblock copolymers comprising a reactive group (e.g., sulfhydryl group) terminated block and films comprising the triblock copolymers.
FILMS DERIVED FROM TWO OR MORE CHEMICALLY DISTINCT BLOCK COPOLYMERS, METHODS OF MAKING SAME, AND USES THEREOF
Methods of making blended, isoporous, asymmetric (graded) films (e.g. ultrafiltration membranes) comprising two or more chemically distinct block copolymers and blended, isoporous, asymmetric (graded) films (e.g. ultrafiltration membranes) comprising two or more chemically distinct block copolymers. The generation of blended membranes by mixing two chemically distinct block copolymers in the casting solution demonstrates a pathway to advanced asymmetric block copolymer derived films, which can be used as ultrafiltration membranes, in which different pore surface chemistries and associated functionalities can be integrated into a single membrane via standard membrane fabrication, i.e. without requiring laborious post-fabrication modification steps. The block copolymers may be diblock, triblock and/or multiblock mixes and some block copolymers in the mix may be functionally modified. Triblock copolymers comprising a reactive group (e.g., sulfhydryl group) terminated block and films comprising the triblock copolymers.
ADVANCED FILTRATION MEMBRANES USING CHITOSAN AND GRAPHENE OXIDE
A composition of five parts by mass of chitosan and one part graphene oxide is suspended in water. The composition may be used to form filtration layers of any size or shape and may be reinforced by additional layers. The composition may be used to construct a large filtration apparatus of any size or shape and may be used to form highly resilient, antimicrobial structures and surfaces for a variety of applications.
CHITOSAN-GRAPHENE OXIDE MEMBRANES
This invention relates generally to a chitosan-graphene oxide membrane and process of making the same. The nanocomposite membrane can filter water and remove contaminants without fouling like other commercially-available polymer-based water filters. The membrane can be used as a flat sheet filter or can be engineered in a spiral filtration module. The membrane is scalable and tunable for many water contaminants including pharmaceuticals, pesticides, herbicides, and other organic chemicals. The membrane uses chitosan, which is low-cost, renewable biopolymer typically considered to be a waste product and the second most abundant biopolymer on Earth, thus making the membrane an environmentally-friendly product choice.
LAYERED CDC-POLYAMIDE MEMBRANE AND ITS MAKE AND USE
New carbon nanomaterials, preferably titanium carbide-derived carbon (CDC) nanoparticles, were embedded into a polyamide film to give CDC/polyamide mixed matrix membranes by the interfacial polymerization reaction of an aliphatic diamine, e.g., piperazine, and an activated aromatic dicarboxylate, e.g., isophthaloyl chloride, supported on a sulfone-containing polymer, e.g., polysulfone (PSF), layer, which is preferably previously prepared by dry/wet phase inversion. The inventive membranes can separate CO.sub.2 (or other gases) from mixtures of CO.sub.2 and further gases, esp. CH.sub.4, based upon the generally selective nanocomposite layer(s) of CDC/polyamide.
Zeolitic imidazolate framework materials, their synthesis and use
A novel zeolitic imidazolate framework material comprises a partially saturated benzimidazole or a partially saturated substituted benzimidazole as a linking ligand, optionally together with unsaturated benzimidazole or an unsaturated substituted benzimidazole as a further linking ligand.
COMPOSITE BODY
The present invention provides a composite body having, on a porous substrate and in the interstices of the substrate that includes fibers, preferably of an electrically nonconductive material, a porous layer (1) composed of oxide particles bonded to one another and partly to the substrate that include at least one oxide selected from oxides of the elements Al, Zr, Ti and Si, preferably selected from Al.sub.2O.sub.3, ZrO.sub.2, TiO.sub.2 and SiO.sub.2, and having, at least on one side, a further porous layer (2) including oxide particles bonded to one another and partly to layer (1) that include at least one oxide selected from oxides of the elements Al, Zr, Ti and Si, preferably selected from Al.sub.2O.sub.3, ZrO.sub.2, TiO.sub.2 and SiO.sub.2, where the oxide particles present in layer (1) have a greater median particle size than the oxide particles present in layer (2), which is characterized in that the median particle size (d.sub.50) of the oxide particles in layer (1) is from 0.5 to 4 m and the median particle size (d.sub.50) of the oxide particles in layer (2) is from 0.015 to 0.15 m, preferably 0.04 to 0.06 m, a process for producing corresponding composite bodies and for the use thereof, especially in gas separation.
Method of magnetically aligning and crystallizing membrane proteins
The disclosure describes a method of forming highly ordered membrane protein crystals. The forming process is done in the presence of a magnetic field to exploit the diamagnetic anisotropy of the membrane protein. Further described is a method of magnetic alignment and crystallization of membrane proteins in two-dimensional (2D) sheets for protein structural characterization and applications in functional devices. Block co-copolymers are used in alternative embodiments to assist with the crystallization process.
MIXED MATRIX MEMBRANES WITH EMBEDDED POLYMERIC PARTICLES AND NETWORKS AND RELATED COMPOSITIONS, METHODS, AND SYSTEMS
Described herein are mixed matrix filtration membranes and related, compositions, methods and systems and in particular mixed matrix filtration membranes with an embedded polymer network and/or embedded polymeric micro/nanoparticles functionalized with a functionalization polymer covalently and/or non covalently linked to the micro/nanoparticles and related compositions, methods, and systems.