Patent classifications
B01D71/06
Asymmetric modified carbon molecular sieve hollow fiber membranes having improved permeance
The present invention provides an asymmetric modified CMS hollow fiber membrane having improved gas separation performance properties and a process for preparing an asymmetric modified CMS hollow fiber membrane having improved gas separation performance properties. The process comprises treating a polymeric precursor fiber with a solution containing a modifying agent prior to pyrolysis. The concentration of the modifying agent in the solution may be selected in order to obtain an asymmetric modified CMS hollow fiber membrane having a desired combination of gas permeance and selectivity properties. The treated precursor fiber is then pyrolyzed to form an asymmetric modified CMS hollow fiber membrane having improved gas permeance.
POROUS MEMBRANE
The object of the present invention is to provide a porous membrane by which a useful component can be recovered while suppressing the clogging during filtration of a protein solution and from which only a small amount of an eluate is eluted even when an aqueous solution is filtered.
The present invention provides a porous membrane containing a hydrophobic polymer and a water-insoluble hydrophilic polymer, the porous membrane having a dense layer in the downstream portion of filtration in the membrane, having a gradient asymmetric structure in which the average pore diameter of fine pores increases from the downstream portion of filtration toward the upstream portion of filtration, and having a gradient index of the average pore diameter from the dense layer to the coarse layer of 0.5 to 12.0.
METHODS AND SYSTEMS FOR TREATING MICROBIAL DISEASE
The present disclosure provides methods and systems for treating a biological fluid of a subject suffering from a microbial infection (e.g., a drug-resistant microbial infection). In some embodiments, these methods and systems involve a complement receptor immobilized on, or otherwise associated with a polymer substrate, for example, high surface area particles, membranes, hollow fibers, and/or other porous or non-porous media. In other embodiments, the methods and systems involve a complement receptor present in a dialysate used in a dialyzer for extracting pathogens out of a biological fluid, for example, the blood of a patient.
METHODS AND SYSTEMS FOR TREATING MICROBIAL DISEASE
The present disclosure provides methods and systems for treating a biological fluid of a subject suffering from a microbial infection (e.g., a drug-resistant microbial infection). In some embodiments, these methods and systems involve a complement receptor immobilized on, or otherwise associated with a polymer substrate, for example, high surface area particles, membranes, hollow fibers, and/or other porous or non-porous media. In other embodiments, the methods and systems involve a complement receptor present in a dialysate used in a dialyzer for extracting pathogens out of a biological fluid, for example, the blood of a patient.
Alkaline anion exchange membranes derived from diphenylethylene and co-monomer feedstock
The anion exchange membranes exhibit enhanced chemical stability and ion conductivity when compared with traditional styrene-based alkaline anion exchange membranes. A copolymer backbone is polymerized from a reaction medium that includes a diphenylalkylene and an alkadiene. The copolymer includes a plurality of pendant phenyl groups. The diphenyl groups on the polymer backbone are functionalized with one or more haloalkylated precursor substrates. The terminal halide from the precursor substrate can then be substituted with a desired ionic group. The diphenylethylene-based alkaline anion exchange membranes lack the α-hydrogens sharing tertiary carbons with phenyl groups from polystyrene or styrene-based precursor polymers, resulting in higher chemical stability. The ionic groups are also apart from each other by about 3 to 6 carbons in the polymer backbone, enhancing ion conductivity. These membrane are advantageous for use in fuel cells, electrolyzers employing hydrogen, ion separations, etc.
Alkaline anion exchange membranes derived from diphenylethylene and co-monomer feedstock
The anion exchange membranes exhibit enhanced chemical stability and ion conductivity when compared with traditional styrene-based alkaline anion exchange membranes. A copolymer backbone is polymerized from a reaction medium that includes a diphenylalkylene and an alkadiene. The copolymer includes a plurality of pendant phenyl groups. The diphenyl groups on the polymer backbone are functionalized with one or more haloalkylated precursor substrates. The terminal halide from the precursor substrate can then be substituted with a desired ionic group. The diphenylethylene-based alkaline anion exchange membranes lack the α-hydrogens sharing tertiary carbons with phenyl groups from polystyrene or styrene-based precursor polymers, resulting in higher chemical stability. The ionic groups are also apart from each other by about 3 to 6 carbons in the polymer backbone, enhancing ion conductivity. These membrane are advantageous for use in fuel cells, electrolyzers employing hydrogen, ion separations, etc.
METHOD FOR PRODUCING PERMSELECTIVE MEMBRANE
A method for producing permselective membrane includes preparing a support membrane having selective permeability and a lipid membrane containing a channel substance, the lipid membrane being formed on a surface of the support membrane. Excess lipids are removed with an acid or an alkali, and the support membrane has a permeation flux of 20 L/(m.sup.2.Math.h) or more and a desalination capacity of 1% to 20% at a pressure of 0.1 MPa.
Method for treating domestic sewage
A method for treating domestic sewage includes: preliminarily treating the domestic sewage through a grating and a grit chamber, so as to remove large-particle solids in the domestic sewage; and subjecting the domestic sewage after the preliminary treatment to circulating anaerobic-oxic treatment in a membrane bioreactor (MBR). In the oxic treatment process, microorganisms oxidize nitrogen in the sewage into nitrite or nitrate. Under anaerobic conditions, denitrifying bacteria in the microorganisms reduce the nitrate, releasing molecular nitrogen or nitrous oxide. In the present invention, the MBR is filled with a quinone-based hollow fiber membrane. During the microbial denitrification, the quinone acts as an electron transfer carrier to participate in the denitrification to promote the reduction of the nitrate (nitrite), increasing the denitrification rate under anaerobic conditions, and achieving the purpose of efficient denitrification.
Method for treating domestic sewage
A method for treating domestic sewage includes: preliminarily treating the domestic sewage through a grating and a grit chamber, so as to remove large-particle solids in the domestic sewage; and subjecting the domestic sewage after the preliminary treatment to circulating anaerobic-oxic treatment in a membrane bioreactor (MBR). In the oxic treatment process, microorganisms oxidize nitrogen in the sewage into nitrite or nitrate. Under anaerobic conditions, denitrifying bacteria in the microorganisms reduce the nitrate, releasing molecular nitrogen or nitrous oxide. In the present invention, the MBR is filled with a quinone-based hollow fiber membrane. During the microbial denitrification, the quinone acts as an electron transfer carrier to participate in the denitrification to promote the reduction of the nitrate (nitrite), increasing the denitrification rate under anaerobic conditions, and achieving the purpose of efficient denitrification.
Nanocomposite membranes and methods of forming the same
A nanocomposite including a mesoporous, macroporous, or a combination thereof oxide and a zeolitic imidazolate framework (ZIF) that is filling the pores of the oxide to form a ZIF phase embedded and at least substantially confined mostly within the oxide. Methods of making nanocomposites including the steps of depositing an oxide in the pores of a mesoporous oxide; and further treating the resulting material with vapor, liquid, or supercritical CO.sub.2 comprising an azole-based compound, a carboxylate based compound, or a combination thereof. Use of disclosed articles to separate propylene and propane in a mixture thereof.