Process for the combined production of a mixture of hydrogen and nitrogen, and of carbon monoxide by cryogenic distillation and cryogenic scrubbing, wherein a methane-rich liquid is introduced at a first intermediate level of a scrubbing column as first scrubbing liquid and at least one nitrogen-rich liquid is introduced at a level higher than the first level of the scrubbing column as second scrubbing liquid and a mixture of hydrogen and nitrogen is drawn off as overhead gas from the scrubbing column.

The present invention relates to a process for oxidative coupling of methane (OCM), comprising the steps of: (a) contacting, in a reactor, oxygen and methane with an OCM catalyst, resulting in a reactor effluent comprising ethylene, ethane, methane, carbon dioxide and water; (b) cooling the reactor effluent to obtain a liquid stream comprising water and a gas stream comprising ethylene, ethane, methane and carbon dioxide; (c) removing carbon dioxide from at least a part of the gas stream comprising ethylene, ethane, methane and carbon dioxide resulting in a gas stream comprising ethylene, ethane and methane; (d) passing at least a part of the gas stream comprising ethylene, ethane and methane as obtained in step (c) through a membrane, preferably a membrane comprising metal cations, more preferably a membrane comprising silver (I) ions (Ag.sup.+ ions) or copper (I) ions (Cu.sup.+ ions), to obtain a stream comprising ethane and a stream comprising ethylene.

The present invention relates generally to the field of emission control equipment for boilers, heaters, kilns, or other flue gas-, or combustion gas-, generating devices (e.g., those located at power plants, processing plants, etc.) and, in particular to a new and useful method and apparatus for reducing and/or eliminating various liquid discharges from one or more emission control equipment devices (e.g., one or more wet flue gas desulfurization (WFGD) units). In another embodiment, the method and apparatus of the present invention is designed to reduce and/or eliminate the amount of liquid waste that is discharged from a WFGD unit by subjecting the WFGD liquid waste to one or more drying processes, one or more spray dryer (or spray dry) absorber processes, and/or one or more spray dryer (or spray dry) evaporation processes.

A process for producing ethanol from lignocellulosic biomass includes adding at least one of sulfur dioxide and sulfurous acid to the lignocellulosic biomass to provide an equivalent sulfur dioxide loading of at least 10 wt % sulfur dioxide to dry lignocellulosic biomass. The acidified lignocellulosic biomass is pretreated at a temperature above about 185° C. and for a pretreatment time less than about 10 minutes, to provide a pretreated biomass composition wherein the biomass is readily hydrolyzed by enzymes. Advantageously, sulfur dioxide from at least one of the flash stream and a stream derived from the flash is recovered and recycled back into the process.

There is provided a process and a system for producing CO and H.sub.2 (syngas) from a CO.sub.2-containing gas. The process includes a step of contacting a CO.sub.2-containing gas with an aqueous absorption solution to produce a bicarbonate loaded stream and a CO.sub.2-depleted gas, followed by a step of subjecting the bicarbonate loaded stream to an electrochemical conversion to generate a gaseous stream including CO and H.sub.2. The system includes an absorption unit wherein the CO.sub.2-containing gas is contacted with the absorption solution to produce the bicarbonate loaded stream and the CO.sub.2-depleted gas and a conversion unit including an electrolytic cell for electrochemically converting bicarbonate ions in the bicarbonate loaded stream into the gaseous stream including CO and H.sub.2 and a bicarbonate depleted stream. In some embodiments, an enzyme such as a carbonic anhydrase can be used to catalyze the conversion of the CO.sub.2-containing gas into the bicarbonate loaded stream.

Various illustrative embodiments of a system and process for recovering high-quality biomethane and carbon dioxide product streams from biogas sources and utilizing or sequestering the product streams are provided. The system and process synergistically yield a biomethane product which meets gas pipeline quality specifications and a carbon dioxide product of a quality and form that allows for its transport and sequestration or utilization and reduction in greenhouse gas emissions. The system and process result in improved access to gas pipelines for products, an improvement in the carbon intensity rating of the methane fuel, and improvements in generation of credits related to reductions in emissions of greenhouse gases.

Various embodiments disclosed relate to extraction of target materials using a CZTS sorbent. A method of extracting a target material from a medium includes contacting a copper zinc tin sulfur (CZTS) sorbent with the target material in the medium including the target material to form a used CZTS sorbent that includes the target material.

Devices, systems and methods for capturing CO.sub.2 in a form that can be stored, processed, and/or converted to usable products is desirable. Systems capture CO.sub.2 using small scale, individual devices at a vast number of locations which, in the aggregate, are capable of significantly decreasing CO.sub.2 concentrations in the atmosphere on a global scale. When such small devices are placed in areas already occupied with a structure, i.e., office buildings, apartments, homes, automobiles and the like, though the amount of CO.sub.2 removal by each individual device may be relatively small, in the aggregate, significant amounts of CO.sub.2 may be removed at a more macro or even global scale.

In various aspects, the present disclosure pertains to high purity chromatographic materials that comprise a chromatographic surface wherein the chromatographic surface comprises a hydrophobic modifier and an ionizable modifier comprising one or more anion exchange moieties that are positively charged when ionized, as well as devices containing such materials. In other aspects, the present disclosure provides methods for mixed mode, anion exchange reversed phase liquid chromatography comprising: (a) loading a sample comprising a plurality of acidic analytes (e.g., acidic glycans) onto a chromatographic separation device comprising such a high purity chromatographic material and (b) eluting adsorbed acidic analytes from the high purity chromatographic material with a mobile phase comprising water, organic solvent, and an organic acid salt, wherein during the course of elution a pH of the mobile phase, an ionic strength of the mobile phase, and a concentration of the organic solvent are altered over time.

Systems and methods are disclosed and include a controller and a water recovery device. The water recovery device includes a desiccant stack including a chamber defining an airflow path therein. The water recovery device includes an evaporator in communication with the desiccant stack and one or more condensers in communication with the desiccant stack. The controller is configured to set the water recovery system to one of an absorption mode and an extraction mode. The water recovery device is configured to receive ambient air in the chamber to remove water vapor using the liquid desiccant and retain the water vapor in the chamber when the water recovery system is in the absorption mode. The water recovery device is configured to remove the water vapor within the chamber when the water recovery system is in the extraction mode.