Provided is a method for producing acetic acid, which suppresses catalyst precipitation and accumulation in an evaporator, can efficiently recycle catalysts to a reaction vessel, and can contribute to maintenance and improvement in acetic acid productivity and securing of safety operation. In the method, the evaporator has a catalyst precipitation and accumulation prevention structure: (a) structure where inclination angle of inside wall surface of an inverted truncated conical cylindrical connection portion is 5 to 85; and/or (b) structure where a vortex breaker comprising a plate-like vortex breaker main body and a leg is disposed such that the vortex breaker main body covers right above the connection portion of an evaporator bottom part to a residual liquid stream recycle line, and linear velocity r of the residual liquid stream passing through a gap between the vortex breaker main body and the evaporator bottom part is larger than 10 m/h.

The method of obtaining methane clathrates consists in the fact that pure methane or methane in a gas mixture not containing hydrocarbons other than methane in amounts not exceeding 1% is contacted with a mixture of alkanes from C7 to C16 and most preferably light paraffin oil containing alkanes from C10 to C14, at a temperature of 5 to 20 C. and absolute pressure above 1 bar, until the solvent is fully saturated.

A process for removing sulfur dioxide from a feed gas stream, which comprises (i) contacting the feed gas stream with an aqueous lean absorbing medium comprising a chemical solvent comprising a regenerable absorbent, a physical solvent, and one or more heat stable salts. The regenerable absorbent is an amine. The ratio of the wt % of the physical solvent over that of the regenerable absorbent is 0.5 to 2.5. The ratio of the wt % of heat stable salts over that of the regenerable absorbent is 0.29 to 0.37. The pH of the lean absorbing medium is 6 or less. With the process SO2 can be selectively removed. When the absorbing medium is stripped, a reduced amount of energy is required as compared to known processes.

Processes and systems for the production of ethylbenzene using a dilute ethylene feed and subsequent recovery of ethane in the alkylation vent gas.

A process is presented for the removal or aromatics from a hydrocarbon stream. The hydrocarbon stream is generated by a dehydrogenation process that generates aromatics. The process includes a two contact cooler system with the first and second contact coolers using different coolants. The second coolant is a non-aromatic hydrocarbon coolant that will absorb aromatics.

The present invention is directed to a process for removing gas phase nitrogen-based compounds by absorption into a liquid stream. The absorbed nitrogen-based compound is reacted with an acid to produce a nitrogen-based product. The nitrogen-based compound, the acid, and the resulting nitrogen-based product may be organic compounds, i.e. compounds derived from animal matter or plant matter. The nitrogen-based product may be a fertilizer, such as ammonium acetate or ammonium citrate that may be certified as organic. Processes are also described for removing nitrogen-based compounds from a liquid stream to produce a nitrogen-based product, including organic fertilizers. One process includes producing cavitation bubbles into which a liquid phase nitrogen-based compound is stripped, followed by absorption to produce a nitrogen-based product. Another process includes the use of a degassing membrane to remove a liquid phase nitrogen-based compound that is degassed to produce a nitrogen-based product, including organic fertilizers.

A gas conditioning system removes contaminants including carbon dioxide from flue gas, such as flue gas of a marine vessel, and includes a rotating backed bed assembly. The rotating packed bed assembly fluidly connects to an exhaust port of an engine, and receive a flue gas from the exhaust port. The rotating packed bed assembly includes a first rotating packed bed having an absorption agent to absorb a portion of the carbon dioxide from the flue gas, and a second rotating packed bed to receive the absorption agent from the first rotating packed bed and desorb at least some of the portion of the carbon dioxide from the absorption agent.

A gas conditioning system removes contaminants including nitrogen oxides and sulfur oxides from flue gas of a marine vessel, and includes an oxidizer unit and a direct contact cooler. The oxidizer unit receives an exhaust flue gas from a marine engine through a fluid inlet at a temperature between 150 degrees Celsius and 550 degrees Celsius, and converts at least a portion of the nitrogen oxides in the flue gas into nitrogen gas, nitrogen dioxide, or both. The direct contact cooler is fluidly connected to the oxidizer unit, and includes a housing defining a cooling chamber. The direct contact cooler directs the flue gas into contact with seawater residing in the cooling chamber and cools the flue gas to a temperature less than or equal to 60 degrees Celsius. The seawater removes some or all nitrogen dioxide and sulfur dioxide from the flue gas in the cooling chamber.

A gas conditioning system removes contaminants including nitrogen oxides and sulfur oxides from flue gas of a marine vessel, and includes an oxidizer unit and a direct contact cooler. The oxidizer unit receives an exhaust flue gas from a marine engine through a fluid inlet, such as at a temperature between 150 degrees Celsius and 550 degrees Celsius, and converts at least a portion of the nitrogen oxides in the flue gas into nitrogen gas, nitrogen dioxide, or both. The direct contact cooler is fluidly connected to the oxidizer unit, and includes a housing defining a cooling chamber. The direct contact cooler directs the flue gas into contact with seawater residing in the cooling chamber and cools the flue gas to a temperature less than or equal to 60 degrees Celsius. The seawater removes some or all nitrogen dioxide and sulfur dioxide from the flue gas in the cooling chamber.

The technological line for the separation of methane from the mixture of gases discharged in the exhaust shafts from the coal mine has a diffuser (2) installed in the exhaust shaft (1) connected with an installation conduit (3) with a dehydrator (4) and a drying device (5) and a fan (6) and a set of filters (7) coupled with at least one absorber (8) filled with saturated paraffin oil, and the draining installation conduit (9) from the absorber (8) has a paraffin oil dropplet (10) connected to the expansion tank (11) by an installation conduit (11) (12), and the installation conduit (13) connecting the absorber (8) with the expansion tank (12) has a pump (14) coupled with the desorber (15), which is connected to the utility installation with installation conduits (16), the evaporator (15), is also connected with an installation conduit (17) with a pump (18) coupled with a cooler (19), and an eqalizing tank (20), which is connected to the absorber (8) through an installation conduit (21) in a closed system. The line enables the separation of methane from the mixture of gases discharged with the mine ventilation air and its utilization. The invention also relates to a highly efficient process for the removal and utilization of methane as a greenhouse gas from deep hard coal mines, allowing to obtain methane with optimal concentration parameters from the mixture of gases discharged from the underground coal mine through the exhaust shafts.