A catalyst includes LTA zeolite including copper ions, wherein a Si/Al ratio of the LTA zeolite is 2 to 50. The catalyst is coated on a honeycomb carrier or a filter. The catalyst removes NOx from a reaction gas at 100° C. or above. The catalyst has an NOx conversion rate of 80% at 450° C. or above.

Provided are novel synthesis techniques for producing pure phase aluminosilicate zeolite and a catalyst comprising the phase pure zeolite in combination with a metal, and methods of using the same.

A process for removing hydrocarbons from a feed stream containing hydrocarbons includes introducing ozone to the feed stream to produce an ozone doped stream containing ozone and hydrocarbons, and contacting the ozone doped stream with a supported metal catalyst at a temperature of from 100° C. to 300° C. to produce a treated stream, wherein the supported metal catalyst comprises iron supported on a support selected from aluminosilicates, silica-aluminas, silicates and aluminas. A process for removing NOx from a feed stream containing NOx, and an apparatus for removing hydrocarbons and/or NOx from a feed stream containing hydrocarbons and/or NOx are also provided.

The present invention solves the existing problem of using very expensive oxidation reagents, such as H.sub.2O.sub.2 and ozone, in removal of NO.sub.x and SO.sub.x from flue gases, by performing simultaneous oxidation of NO.sub.x and SO.sub.x with atmospheric oxygen in a combined system for catalytic oxidation and wet-scrubbing of both NO.sub.x and SO.sub.x from a flue gas and manufacturing fertilisers. Two major configurations of the oxidation system are disclosed in the present invention. The first configuration operates on oxygen-enriched air to increase efficiency of the oxidation reaction and requires an additional oxygen concentrator unit. The second configuration operates on atmospheric air at ambient conditions and requires an additional catalyst activation unit. In the second configuration, the efficient oxidation process is carried out at low temperatures of about 30-90 C. in the presence of recovered and re-activated catalyst. This temperature is a result of the exothermic character of the reaction, and therefore, no heating is required in the process.

Some embodiments of the present disclosure relate to a method of regenerating at least one filter medium comprising: providing at least one filter medium, wherein the at least one filter medium comprises: at least one catalyst material; and ammonium bisulfate (ABS) deposits, ammonium sulfate (AS) deposits, or any combination thereof; flowing a flue gas stream transverse to a cross-section of a filter medium, such that the flue gas stream passes through the cross section of the at least one filter medium, wherein the flue gas stream comprises: NOx compounds comprising: Nitric Oxide (NO), and Nitrogen Dioxide (NO.sub.2); and increasing an NOx removal efficiency of the at least one filter medium after removal of deposits.

The present invention addresses the problem and purpose of providing a honeycomb structure that has a sufficiently high strength and is excellent in endurance, and a catalyst for cleaning an exhaust gas using the same that is excellent in resistance to sulfur oxide (SOX). The honeycomb structure of the present invention is one consists of a flat inorganic fiber sheet comprising an inorganic fiber sheet having supported thereon an inorganic binder and zeolite, and a corrugated inorganic fiber sheet comprising an inorganic fiber sheet having supported thereon the same inorganic binder and zeolite, which are alternately combined with each other, wherein it is characterized in that the zeolite has a particle diameter (i.e., a median particle diameter, D50) of from 0.5 to 10.0 m.

A catalyst article including a substrate with an inlet side and an outlet side, a first zone and a second zone, where the first zone includes a passive NOx adsorber (PNA), and an ammonia slip catalyst (ASC) comprising a platinum group metal on a support and a first SCR catalyst; where the second zone includes a catalyst selected from the group consisting of a diesel oxidation catalyst (DOC) and a diesel exotherm catalyst (DEC); and where the first zone is located upstream of the second zone. The first zone may include a bottom layer with a blend of: (1) the platinum group metal on a support and (2) the first SCR catalyst; and a top layer with a second SCR catalyst, the top layer located over the bottom layer.

A NO.sub.x and SO.sub.x oxidation with atmospheric oxygen to remove NO.sub.x and SO.sub.x from flue gases. The combined system for catalytic oxidation and wet-scrubbing of NO.sub.x and SO.sub.x from a flue gas and manufacturing fertilizers includes: an air separation unit for separating atmospheric oxygen from air and producing an air stream enriched with atmospheric oxygen, an adsorption and oxidation reactor containing an oxidation catalyst and carrying out the catalytic oxidation of NO.sub.x and SO.sub.x by said oxygen to yield nitric and sulphuric acids, a separator and reactor control unit for separation of products and liquids and controlling the reaction; and a vessel containing ammonia streaming said ammonia into the reactor or into the control unit to react with the nitric and sulphuric acids and to yield the fertilizers.

Some embodiments of the present disclosure relate to a method of regenerating at least one filter medium comprising: providing at least one filter medium, wherein the at least one filter medium comprises: at least one catalyst material; and ammonium bisulfate (ABS) deposits, ammonium sulfate (AS) deposits, or any combination thereof; flowing a flue gas stream transverse to a cross-section of a filter medium, such that the flue gas stream passes through the cross section of the at least one filter medium, wherein the flue gas stream comprises: NO.sub.x compounds comprising: Nitric Oxide (NO), and Nitrogen Dioxide (NO.sub.2); and increasing an NO.sub.x removal efficiency of the at least one filter medium after removal of deposits.

A catalyst article including a substrate with an inlet side and an outlet side, a first zone and a second zone, where the first zone includes a passive NOx adsorber (PNA), and an ammonia slip catalyst (ASC) comprising a platinum group metal on a support and a first SCR catalyst; where the second zone includes a catalyst selected from the group consisting of a diesel oxidation catalyst (DOC) and a diesel exotherm catalyst (DEC); and where the first zone is located upstream of the second zone. The first zone may include a bottom layer with a blend of: (1) the platinum group metal on a support and (2) the first SCR catalyst; and a top layer with a second SCR catalyst, the top layer located over the bottom layer.