A process is presented to treat a process stream containing a hydrocarbon (oil and/or gas) and hydrogen sulfide with a liquid treatment solution containing a sulfur dye catalyst. The process stream can be within a pipeline, wellbore, subsea pipeline or a wellhead that contains hydrogen sulfide where the liquid treatment solution is injected at a predetermined point to define a scavenger zone such that the sulfur dye catalyst in the liquid treatment solution causes the sulfide from the hydrogen sulfide to react with the catalyst. The hydrocarbon component is separated substantially free of the hydrogen sulfide from a spent treatment solution containing spent sulfur dye catalyst which can then be fed to an oxidation vessel where it is contacted with an oxygen containing gas causing the sulfide to oxidize to thiosulfate and converting the spent sulfur dye catalyst to regenerated sulfur dye catalyst. The thiosulfate can be recovered, and the regenerated sulfur dye catalyst can be recycled as part of the liquid treatment solution.

The invention discloses a phosphorus-doped tubular carbon nitride micro-nano material and application thereof in waste gas treatment. Melamine is partially hydrolyzed into cyanuric acid through a phosphorous acid-assisted hydrothermal method to form a melamine-cyanuric acid super molecular precursor; the center of the precursor starts to be pyrolyzed under heating calcination, and thus phosphorus-doped tubular carbon nitride is obtained; the phosphorus-doped tubular carbon nitride and sodium borohydride are mixed and subjected to low-temperature calcination in an inert gas atmosphere, and defect-modified phosphorus-doped tubular carbon nitride is obtained. The defect-modified phosphorus-doped tubular carbon nitride micro-nano material has a good photocatalytic effect on catalytic degradation of waste gas; besides, the production raw materials are abundant and easy to obtain, and the phosphorus-doped tubular carbon nitride micro-nano material is good in stability and recyclable and has application prospects in waste gas treatment.

A process is presented where a feed stream containing a hydrogen sulfide and another feed component is introduced into an absorber that the feed stream flows upward from the bottom of the absorber and contacts a liquid treatment solution, where the liquid treatment solution contains a sulfur dye catalyst. The hydrogen sulfide is absorbed into the liquid treatment solution and converted into sulfide ions. The other feed component is removed from the absorber vessel substantially free of the hydrogen sulfide and a spent treatment solution is also removed from the absorber vessel and fed to an oxidation vessel where it is contacted with an oxygen containing gas causing the sulfide ions to oxidize to thiosulfate and converting the spent sulfur dye catalyst to regenerated sulfur dye catalyst. The thiosulfate is recovered, and the regenerated sulfur dye catalyst can be recycled as part of the liquid treatment solution.

A multifunctional microwave plasma and ultraviolet light deodorization treatment unit, which includes: a rapid decomposition device (1), a high frequency plasma electric field (2), a microwave plasma electric field (3), a high intensity ultraviolet radiation field (4), a low temperature plasma electric field (5), a high intensity ozone gas reaction chamber (6), a reaction termination chamber (7) and a clean gas organization chamber (8) sequentially installed inside a horizontal rectangular box which has an elongated body defining a horizontal axis and has a channel cavity therein. The deodorization treatment unit further includes an exhaust gas odor collecting pipe and an odor gas storage cabinet (9) connected to an air pump (10), the air pump (10) is connected to an odor gas inlet of the rapid decomposition device (1), the clean gas organization chamber (8) has one end connected to a clean gas exhaust pipe.

A process is presented where a feed stream containing a hydrogen sulfide and another feed component is introduced into an absorber that the feed stream flows upward from the bottom of the absorber and contacts a liquid treatment solution, where the liquid treatment solution contains a sulfur dye catalyst. The hydrogen sulfide is absorbed into the liquid treatment solution and converted into sulfide ions. The other feed component is removed from the absorber vessel substantially free of the hydrogen sulfide and a spent treatment solution is also removed from the absorber vessel and fed to an oxidation vessel where it is contacted with an oxygen containing gas causing the sulfide ions to oxidize to thiosulfate and converting the spent sulfur dye catalyst to regenerated sulfur dye catalyst. The thiosulfate is recovered, and the regenerated sulfur dye catalyst can be recycled as part of the liquid treatment solution.

A process is presented to treat a process stream containing a hydrocarbon (oil and/or gas) and hydrogen sulfide with a liquid treatment solution containing a sulfur dye catalyst. The process stream can be within a pipeline, wellbore, subsea pipeline or a wellhead that contains hydrogen sulfide where the liquid treatment solution is injected at a predetermined point to define a scavenger zone such that the sulfur dye catalyst in the liquid treatment solution causes the sulfide from the hydrogen sulfide to react with the catalyst. The hydrocarbon component is separated substantially free of the hydrogen sulfide from a spent treatment solution containing spent sulfur dye catalyst which can then be fed to an oxidation vessel where it is contacted with an oxygen containing gas causing the sulfide to oxidize to thiosulfate and converting the spent sulfur dye catalyst to regenerated sulfur dye catalyst. The thiosulfate can be recovered, and the regenerated sulfur dye catalyst can be recycled as part of the liquid treatment solution.

Cluster-supporting catalyst having an improved heat resistivity, and method for producing the same are provided. The cluster-supporting catalyst includes boron-substitute zeolite particles, and catalyst metal clusters supported within the pores of the boron-substitute zeolite particles. The method for producing a cluster-supporting catalyst, includes the following steps: providing a dispersion liquid containing a dispersion medium and boron-substitute zeolite particles dispersed in the dispersion medium; and in the dispersion liquid, forming catalyst metal clusters having a positive charge, and supporting the catalyst metal clusters on the acid sites within the pores of the boron-substitute zeolite particles through an electrostatic interaction.

There is provided a zeolite having a CHA structure. When a total integrated intensity of a (211) plane, a (104) plane, and a (220) plane in an X-ray diffraction spectrum obtained by an X-ray powder diffraction method is defined as X.sub.0 and the total integrated intensity after heat endurance test for five hours at 900 C. under an air atmosphere is defined as X.sub.1, a ratio of X.sub.1 (X.sub.1/X.sub.0) to X.sub.0 is within a range from 0.2-0.7; and as measured by a .sup.27Al-NMR method after the heat endurance test for five hours at 900 C. under the air atmosphere, when a peak intensity of tetra-coordinated Al atoms is defined as P.sub.4 and a peak intensity of hexa-coordinated Al atoms is defined as P.sub.6, a ratio of P.sub.6 (P.sub.6/P.sub.4) to P.sub.4 is 0.1 or less.

According to an example aspect of the present invention, there is provided a method of selectively catalytically reducing dinitrogen oxide present in a gaseous sample, comprising: providing a catalyst capable of reducing dinitrogen oxide; bringing the gaseous sample into contact with the catalyst to reduce dinitrogen oxide in the gaseous sample in the presence of the catalyst; wherein as a result of the reduction step, the gaseous sample is adapted for determination of the amount of an isotopic form of CO.sub.2 in the gaseous sample.

The present invention discloses an air filter cartridge for use in an air-purifying device for removing formaldehyde (methane, HCHO) and other aldehyde-like VOCs (Volatile Organic Compounds), and in certain embodiments amine-like VOCs, from indoor air. The air filter cartridge is made up of a casing containing a plurality of filament-like elements as a support and a mixture of one or more natural polyphenols and a catalyst integrated in said support as a powder, forming a sponge-like mesh. The air filter acts as an absorption filter, the sponge-like mesh reacting irreversibly with the aldehyde-like VOCs present in the air, generating a polymer in the form of a polyphenol-aldehyde resin inside the air filter. Due to this irreversible reaction, the air filter is capable of capturing formaldehyde, as well as other aldehyde-like VOCs that are less reactive than formaldehyde, amine-like VOCs and ammonia.