A metal organic framework glass membrane and a preparation method thereof are provided. The preparation method includes a step of heating a crystalline metal organic framework material to the melting temperature at a rate of 1-15° C./min and then naturally cooling the crystalline metal organic framework material. The crystalline metal organic framework material contains a metal node and a ligand A. The metal node is a zinc ion and/or a cobalt ion and the ligand A is imidazole or phosphoric acid. The metal organic framework glass membrane has a wide range of membrane-forming conditions, and the material thereof can be melted without being decomposed within a control range to form a continuous glass layer with good repeatability.

An aminated siliceous adsorbent, which is the reaction product of dried acidified rice husk ash having disordered mesopores and an amino silane, wherein amine functional groups are present on an external surface and within the mesopores of the dried acidified rice husk ash, and wherein the aminated siliceous adsorbent has a carbon content of 24 to 30 wt. %, based on a total weight of the aminated siliceous adsorbent. A method of making the aminated siliceous adsorbent and a method of capturing CO.sub.2 from a gas mixture with the aminated siliceous adsorbent.

A filter assembly has a housing defining an inlet and an outlet. A plurality of chemical filter elements are disposed in the housing and are arranged in a series with respect to fluid flow. A spacing region is between adjacent filter elements in the series. Also disclosed is an assembly having a housing and a first and second chemical filter element. The second chemical filter element is downstream of the first chemical filter element. Each chemical filter element has a sheet of chemical filter material having a first edge and a second edge. A first flow path is defined parallel to a surface of the first sheet extending from its first edge to its second edge. A second flow path is defined parallel to a surface of the second sheet extending from its first edge to its second edge.

A system and method for cooling, purifying and liquifying a feed gas stream uses liquid nitrogen for cooling the system. After cooling the system, the warmed nitrogen is vented as a vapor. The system and method include a water condenser, a first and second cooler and a liquifier and production of at least first and second contaminant streams. Optionally, the system includes a compressor or blower and/or a separator.

In one embodiment, a system includes a purification stage configured to purify an input gas stream prior to delivering the input gas stream to a reaction stage; and a collection stage configured to collect at least some ammonia from the reaction stage. The reaction stage is configured to reduce nitrogen into nitride; and convert at least some of the nitride into ammonia. In another embodiment, a separation membrane includes: an anode; a cathode electrically coupled to the anode; and a porous support material positioned between the anode and the cathode. The separation membrane is configured to reduce nitrogen into nitride; and facilitate hydrogenation of the nitride to form ammonia. In another embodiment, a method includes delivering an input gas stream comprising nitrogen to a separation membrane; reducing at least some of the nitrogen into nitride; and reacting at least some of the nitride with hydrogen-containing compound(s).

The present invention generally relates to a pressure swing adsorption process for separating an adsorbate impurity from a feed stream comprising product gas, said process comprising feeding the feed stream to an adsorbent bed at a pressure of from about 60 psig to 2000 psig, wherein said adsorbent bed comprises adsorbent having: An isosteric heat of adsorption of from about 5 kJ/mol to about 30 kJ/mol, as determined by the LRC method, for the adsorbate, and an equivalent 65 kJ/mol or less isosteric heat of adsorption for the product,
wherein the adsorbent has a rate of adsorption for the adsorbate impurity that is at least 10 times greater than the rate of adsorption for the product gas as determined by the TGA method and recovering said product gas with a reduced a level of said adsorbate impurity. The invention also related to an adsorbent useful in PSA separations, particularly separating N.sub.2 from methane, CO.sub.2 from methane O.sub.2 from N.sub.2 and the like.

The present invention provides a composite body having, on a porous substrate and in the interstices of the substrate that includes fibers, preferably of an electrically nonconductive material, a porous layer (1) composed of oxide particles bonded to one another and partly to the substrate that include at least one oxide selected from oxides of the elements Al, Zr, Ti and Si, preferably selected from Al.sub.2O.sub.3, ZrO.sub.2, TiO.sub.2 and SiO.sub.2, and having, at least on one side, a further porous layer (2) including oxide particles bonded to one another and partly to layer (1) that include at least one oxide selected from oxides of the elements Al, Zr, Ti and Si, preferably selected from Al.sub.2O.sub.3, ZrO.sub.2, TiO.sub.2 and SiO.sub.2, where the oxide particles present in layer (1) have a greater median particle size than the oxide particles present in layer (2), which is characterized in that the median particle size (d.sub.50) of the oxide particles in layer (1) is from 0.5 to 4 μm and the median particle size (d.sub.50) of the oxide particles in layer (2) is from 0.015 to 0.15 μm, preferably 0.04 to 0.06 μm, a process for producing corresponding composite bodies and for the use thereof, especially in gas separation.

A hybrid nitrogen gas generation system includes a membrane nitrogen gas generator and a pressure swing absorption nitrogen generator. A gas comprising nitrogen is purified to a first nitrogen purity using one of the membrane nitrogen gas generator and the pressure swing absorption nitrogen generator. The gas is either bypassed around the other of the membrane nitrogen gas generator and the pressure swing absorption nitrogen generator to provide the gas having the first nitrogen purity or the gas is purified to a second nitrogen purity using the other of the membrane nitrogen gas generator and the pressure swing absorption nitrogen generator.

The present disclosure provides a gas separation membrane module that has high, long-term utility. The present disclosure provides a gas separation membrane module that has: a housing; a gas separation membrane that is arranged inside the housing; and an adhesive part that fixes the gas separation membrane to the housing.

An improved system for separating gas from a process stream by providing a stripping unit at the overhead stream of a fractionation column to selectively and effectively remove the gas using a stripping fluid without providing a dedicated light-ends separations unit. The stripper unit may be connected to the reflux drum at the overhead stream. The system for separating gas further achieves greater thermodynamic efficiency by means of a split column design using mechanical vapor recompression with the reboiler and condenser integrated in a falling-film evaporator- or thermosiphon-type vapo-condenser.