A process can treat a gaseous material mixture obtained by catalytic conversion of synthesis gas that contains at least alkenes, possibly alcohols and possibly alkanes, and also possibly nitrogen as inert gas and unconverted components of the synthesis gas, comprising hydrogen, carbon monoxide and/or carbon dioxide. After catalytic conversion of synthesis gas, separation of the product mixture obtained in this reaction into a gas phase and a liquid phase is performed by at least partial absorption of the alkenes, possibly of the alcohols and possibly of the alkanes, in a high boiling point hydrocarbon or hydrocarbon mixture as an absorption medium, separation as the gas phase of the gases not absorbed into the absorption medium, separating an aqueous phase from the organic phase of the absorption medium, preferably by decanting, and desorption of the alkenes, possibly of the alcohols and possibly of the alkanes, from the absorption medium.

A process can produce alcohols having at least two carbon atoms by catalytic conversion of synthesis gas into a mixture containing alkanes, alkenes, and alcohols. Alkenes are converted into corresponding alcohols in a subsequent step by hydration of the alkanes. Before the hydration and after the catalytic conversion, gas and liquid phases may be separated. Specific catalysts can be employed that have a markedly higher selectivity for alkenes than for alkanes. These catalysts comprise grains of non-graphitic carbon having cobalt nanoparticles dispersed therein. The cobalt nanoparticles have an average diameter d.sub.p from 1 to 20 nm, and an average distance D between nanoparticles is from 2 to 150 nm. The combined total mass fraction of metal ω in the grains ranges from 30% to 70% by weight of the total mass of the grains of non-graphitic carbon, wherein 4.5 dp/ω>D≥0.25 dp/ω.

An apparatus for capturing CO.sub.2 from flue gas includes (a) an absorber, (b) a stripper, (c) a heat exchanger, (d) an amine absorbent circulating through the absorber, the stripper and the heat exchanger, (e) a water washing unit downstream from the flue gas outlet of the absorber, and (f) an electrochemical cell. The electrochemical cell is connected to the water washing unit and is adapted to adsorb and decompose nitrosamine compounds present in liquid separated by the water washing unit.

A process for recovering sulfur from a sour gas is provided. The process includes the steps of: providing the sour gas to a membrane separation unit having a carbon dioxide-selective membrane that comprises a perfluoropolymer, wherein the sour gas comprises carbon dioxide and at least 1 mol % hydrogen sulfide; separating the sour gas using the carbon dioxide-selective membrane in the membrane separation stage to obtain hydrogen sulfide-enriched gas and hydrogen sulfide-stripped gas, wherein the hydrogen sulfide-enriched gas has a hydrogen sulfide concentration of at least 20 mol %, and wherein the hydrogen sulfide-stripped gas comprises carbon dioxide; and processing the hydrogen sulfide-enriched gas in a sulfur recovery unit to obtain sulfur.

Methods and systems of collecting carbon dioxide are disclosed. In one example, a method includes removing water from atmospheric air with a condenser and a desiccant material to produce dry air, adsorbing carbon dioxide to a material from the dry air, releasing the adsorbed carbon dioxide to a vacuum chamber, and transitioning the released carbon dioxide from a gas to a solid in the vacuum chamber.

A process for purifying a feed gas stream containing at least 90% of CO.sub.2, at least 20% RH and at least one impurity chosen from chlorinated, sulfur-bearing, nitrated or fluorinated compounds is provided. The process includes a) subjecting the feed gas stream to catalytic oxidation producing a stream containing at least one of HCl, NOx, SOx or hydrofluoric acid; b) maintaining the temperature of the gas stream above the highest value between the dew points of water and the acid(s) contained in the gas; c) removing at least a part of the acid impurities by bringing the gas stream into contact with a corrosion-resistant heat exchanger to condense the acid compounds while regulating the temperature of the gas stream exiting below the dew point of water; and d) separating the acid condensates with a corrosion-resistant separator in such a way as to produce a CO.sub.2-enriched gas stream.

A process for obtaining carbon dioxide from furnace combustion fumes is provided. The process comprises removing water vapour occurring in combustion fumes through successive gas compression and expansion steps; separating carbon dioxide from oxygen and nitrogen through the use of a filter comprising a gas-separating material, including fullerenes and zeolites, to obtain substantially pure gaseous carbon dioxide; subsequently optionally producing dry ice through further steps of compression and expansion of the substantially pure gaseous carbon dioxide obtained in the preceding steps.

Method and installation for treating a CO.sub.2- and H.sub.2O-containing flue gas generated by an industrial process unit before CCUS, whereby the flue gas evacuated from the unit is subjected to cooling to a temperature T2 between 100 and 600° C., whereby the cooled flue gas is pretreated in one or more particle removal and/or gas cleaning and/or drying stages and the temperature of the cooled flue gas is further reduced to a temperature T3<T2, before a first part of pretreated flue gas is subjected to CCUS, a second part of the pretreated flue gas being recycled at temperature T3 as a cooling agent and mixed with the flue gas during the controlled cooling thereof, partially or fully purified CO.sub.2 from the CCUS may be recycled at temperature T4<T2 may be recycled as a cooling agent and mixed with the flue gas during the controlled cooling.

An apparatus includes a housing that defines a first zone, a second zone, a third zone, and a fourth zone. The apparatus includes an inlet, a first outlet, a second outlet, and a conveyor belt. The inlet is configured to receive a carbon dioxide-containing fluid in the first zone. The first outlet is configured to discharge a carbon dioxide-depleted fluid from the first zone. The second outlet is configured to discharge a carbon dioxide-rich fluid from the third zone. The conveyor belt passes through each of the zones. The conveyor belt includes a carbon dioxide sorbent. Within the first zone, the carbon dioxide sorbent is configured to adsorb carbon dioxide from the carbon dioxide-containing fluid to produce the carbon dioxide-depleted fluid. Within the third zone, the carbon dioxide sorbent is configured to desorb the captured carbon dioxide to produce the carbon dioxide-rich fluid.

A flue gas extraction system provides extraction, collection, cooling, enriching and distributing flue gas from a vent stack of a stationary flue gas generator to carbon dioxide consuming crops, orchards, and other photosynthetic organisms. The collected flue gas is processed through the system to achieve optimal temperature, pressure, flowrate, water content and carbon dioxide concentration for application to plants for increasing plant productivity and sequestering the carbon dioxide. The gas distribution network may have one or more membrane modules which receive a low pressure gas mixture, where the membrane modules are utilized to enrich the CO2 concentration and to separate out a nitrogen rich component from the flue gas. Application of carbon dioxide may be supplemented by providing additional components to the plants which maintain a level of fertilization and irrigation suitable for the increased biomass and water utilization efficiency of the plants resulting from the increased intake of carbon dioxide.