A water harvesting unit may include a chamber and a vessel. The chamber may include a first plenum space and a second plenum space located on either side of a partition member. The vessel may be supported for rotation within the chamber. The vessel may include a base and a plurality of sidewalls. The plurality of sidewalls may extend from the base to a vessel opening. The base may be substantially fluid impermeable and at least a portion of the plurality of sidewalls may be fluid permeable. The base and a majority of the plurality of sidewalls of the vessel may be disposed in the first plenum space. The vessel opening may open to the second plenum space via an opening in the partition member.

There is provided an exhaust system for the treatment of a humid exhaust gas comprising ammonia in an amount of up to 250 ppm, the system comprising: a dehumidifier system comprising a humid air inlet for providing a flow of humid exhaust gas; an exhaust gas inlet for providing a flow of dehumidified exhaust gas; an ammonia storage material arranged to receive the dehumidified exhaust gas from the exhaust gas inlet; an ammonia oxidation catalyst arranged downstream of a selected portion of the ammonia storage material; and a heating device for heating gas before it passes through the selected portion of the ammonia storage material to release ammonia stored therein for treatment on the ammonia oxidation catalyst; wherein the system is configured so that the selected portion of the ammonia storage material changes over time; and wherein the flow of dehumidified exhaust gas provided by the exhaust gas inlet is received from the dehumidifier system.

The present disclosure relates to systems and methods for power production utilizing a recirculating working fluid. In particular, a portion of the recirculating working fluid can be separated from the main stream of recirculating working fluid as a bypass stream that can be compressed for adding heat to the system.

Provided herein are water harvesting systems, as well as methods of making and using such systems, for capturing water from surrounding air using a design that reduces overall energy costs of the systems and improve water harvesting cycle efficiency. The systems and methods use sorbent materials, such as metal-organic frameworks, to adsorb water from the air. The systems and methods desorb this water in the form of water vapor, and the water vapor is condensed into liquid water and collected. The liquid water is suitable for use as drinking water.

Embodiments of the present disclosure describe a metal-organic framework (MOF) composition comprising a plurality of metal clusters, wherein the metal is chromium; and one or more tetratopic ligands; wherein the metal clusters and ligands associate to form a MOF with soc topology. A method of making a MOF comprising contacting a template MOF of formula Fe-soc-MOF and a reactant including chromium in a presence of dimethylformamide sufficient to replace Fe with Cr and form an exchanged MOF of formula Cr-soc-MOF. A method of sorbing water vapor comprising exposing a Cr-soc-MOF to an environment; and sorbing water vapor using the Cr-soc-MOF.

A porous aluminum-based metal-organic framework (MOF) comprises inorganic aluminum chains linked via carboxylate groups of 1H-pyrazole-3,5-dicarboxylate (HPDC) linkers, and of formula: [Al(OH)(C.sub.5H.sub.2O.sub.4N.sub.2)(H.sub.2O)].

A multi-stage process to remove contaminant gases from raw methane streams is provided. The present technology is an innovative solution to recover and purify biogas by use of a process having at least two pressure swing adsorption stages. Taking advantage of the presence of carbon dioxide in the raw biogas streams, nitrogen and oxygen are bulky removed in the first stage, using selective adsorbents, and a nitrogen and oxygen-depleted intermediate stream is yielded to the second stage. The second stage employs an adsorbent or adsorbents to selectively remove carbon dioxide and trace amounts of remaining nitrogen and oxygen, thus producing a purer methane stream that meets pipeline and natural gas specifications.

Method for drying compressed gas by means of a drying device with an inlet for the compressed gas to be dried and an outlet for the dried compressed gas. The drying device includes at least two vessels filled with a regenerable desiccant and an adjustable valve system including a first valve block and a second valve block that connects the inlet, respectively outlet, to the vessels. The adjustable valve system is being regulated as such that at least one vessel will dry compressed gas, while the other vessel will be regenerated and cooled successively, wherein by regulation of the valve system the vessels will each in turn dry compressed gas. The method includes calculating the time period (t.sub.ads) during which a vessel (2) dries compressed gas, calculated on the basis of a (t.sub.ads) formula t.sub.ads=A*B.

The present invention relates to a system for producing synthetic fuels, in particular jet fuel (kerosene), gasoline and/or diesel, comprising: a) an apparatus for separately extracting carbon dioxide and water from ambient air, b) a synthesis gas production apparatus for producing a raw synthesis gas comprising carbon monoxide, hydrogen, carbon dioxide and water, the synthesis gas production apparatus having a supply line for carbon dioxide leading from the apparatus for separately extracting carbon dioxide and water from ambient air, a supply line for air and a supply line for water, c) a separating apparatus for separating carbon dioxide and water from the raw synthesis gas produced in the synthesis gas production apparatus, d) a Fischer-Tropsch apparatus for producing hydrocarbons by means of a Fischer-Tropsch process from the synthesis gas from which carbon dioxide and water were separated in the separating apparatus, e) a refining apparatus for refining the hydrocarbons produced in the Fischer-Tropsch apparatus into synthetic fuels, f) a desalination apparatus for desalinating water, the desalination apparatus having a water supply line from the apparatus for separately extracting carbon dioxide and water from ambient air and a water discharge line to the Fischer-Tropsch apparatus, and g) a water purification apparatus, which comprises a water supply line leading from the Fischer-Tropsch apparatus for purifying water produced therein, the system further comprising a pre-reformer for converting hydrocarbons other than methane into methane, carbon oxides, water and hydrogen and i) a water vapor supply line leading from the water purification apparatus to the pre-reformer, ii) a process gas supply line leading from the refining apparatus to the pre-reformer and/or a return gas line leading from the Fischer-Tropsch apparatus to the pre-reformer and iii) a circulation line leading from the pre-reformer to the supply line for water connected to the synthesis gas production apparatus.

A system for disassociating molecules of a gas based on RF power. Characteristics of the RF power can be tuned to increase disassociation efficiency. The system can include a disassociation chamber configured to enclose a volume of a gas and a radio frequency (RF) power source configured to provide RF power to the disassociation chamber. The RF power source can include a radio-frequency generator configured to generate an electromagnetic (EM) radiation having a frequency between about 20 MHz and about 10 THz, a radio-frequency amplifier configured to amplify the generated EM radiation, and an output channel to direct the amplified EM radiation towards the volume of gas.