A process to prevent fouling using a desublimating heat exchanger is disclosed. An outlet stream from the desublimating heat exchanger may be split into a plurality of parallel streams. The parallel streams may be sent through other devices for performing a unit operation, and the devices for performing a unit operation may change the temperature of at least one of the parallel streams. Parallel streams of differing temperature may emerge from the devices for performing a unit operation. The parallel streams of differing temperature may be sent to a mixing chamber. A mixed stream of uniform temperature may emerge from the mixing chamber, and the mixed stream may be recycled back to the desublimating heat exchanger. The mixing chamber may be separate from the desublimating heat exchanger, or the parallel streams of differing temperature may be mixed in the desublimating heat exchanger.

Embodiments of the present disclosure include methods and systems of circulating air in an enclosed environment. In such embodiments, the system may comprise an air handling unit (AHU), the AHU including an indoor air inlet to receive an indoor airflow from the enclosed environment and an indoor air outlet to expel the indoor airflow, a conditioning element arranged between the inlet and the outlet configured to at least heat or cool the indoor airflow as it flows thereover, one or more fan units arranged between the inlet and the outlet configured to provide velocity to the indoor airflow, and an air treatment assembly (ATA) arranged within or proximate the AHU, the ATA including an air inlet configured to receive a portion of the indoor airflow received by the AHU indoor air inlet.

Disclosed is a hydrogen peroxide vapor detoxifying system, which includes a hydrogen peroxide vapor suction unit configured to suck a hydrogen peroxide vapor in a target space; a hydrogen peroxide vapor detoxifying unit configured to decompose the sucked hydrogen peroxide vapor; and a vapor discharging unit configured to discharge a decomposition product generated by decomposing the hydrogen peroxide vapor.

A composition having the structure of formula I:
[RAr(COOH).sub.2].sub.x[Ar(COOH).sub.3].sub.2-xM.sub.3.sup.2+(I)
is provided where M is Mn, Cu, Co, Fe, Zn, Cd, Ni, or Pt; R is a bromine, nitro, a primary amine, C.sub.1-C.sub.4 alkyl secondary amine, C.sub.1-C.sub.4 alkyl oxy, Br(C.sub.1-C.sub.4 alkyl), NO.sub.2(C.sub.1-C.sub.4 alkyl), a mercaptan, and reaction products of any of the aforementioned with acyl chlorides of the formulas: CH.sub.3(CH.sub.2).sub.mC(O)Cl, or CH.sub.3(CH(C.sub.1-C.sub.4 alkyl)CH.sub.2).sub.mC(O)Cl, or CH.sub.3(CH.sub.2).sub.m-Ph-(CH.sub.2).sub.pC(O)Cl, where Ph is a C.sub.6 phenyl or C.sub.6 phenyl with one or more hydrogens replaced with F, C.sub.1-C.sub.4 fluoroalkyl, or C.sub.1-C.sub.4 perfluoroalkyl; m is independently in each occurrence an integer of 0 to 12 inclusive; p is an integer of 0 to 36 inclusive, to form an amide, a thioamide, or an ester; Ar is a 1,3,5-modified phenyl, and 1.4>x>0. A process of synthesis thereof and the use to chemically modify a gaseous reactant are also provided.

A gas accumulation and combustion control device combining a sorption system, a ventilation system, a control system, and sensor system, with the sensor system configured to detect gas contaminants, transmit a gas detection signal to the control system, the control system configured to adjust the ventilation system based on the gas detection signal, the ventilation system configured to draw the contaminated air in from the atmosphere and lead it toward the sorption system, which in turn is configured to adsorb or absorb the gas contaminants.

This invention relates to modified MOF materials, methods of preparing them and processes using them. A modified MOF of the invention is modified by impregnating a MOF with an inorganic metal salt. The starting MOF contains at least one linker or ligand which contains an aryl amino group as part of its structure. These modified MOFs are able to adsorb either basic or acidic toxic industrial compounds (TIC). The modified MOFs can be used to remove TICs from various gaseous streams such as air.

A battery housing, especially for lithium ion batteries, that is designed to prevent and/or contain a battery fire, and/or prevent damage to the battery when the housing is impacted, includes a ceramic base layer and fibrous ballistic layer bonded to the base layer.

A method of using a metal organic framework (MOF) comprising a metal ion and an at least bidendate organic ligand to catalytically detoxify chemical warfare nerve agents including exposing the metal-organic-framework (MOF) to the chemical warfare nerve agent and catalytically decomposing the nerve agent with the MOF.

Embodiments of the present disclosure are directed towards methods for preparing mixed-metal oxide particles by heating adamantane-intercalated layered double-hydroxide (LDH) particles at a reaction temperature of from 400 C. to 800 C. to form mixed-metal oxide particles. The adamantane-intercalated LDH particles have a general formula [M.sub.1-xAl.sub.x(OH).sub.2](A).sub.x.mH.sub.2O, where x is from 0.14 to 0.33, m is from 0.33 to 0.50, M is chosen from Mg, Ca, Co, Ni, Cu, or Zn, and A is adamantane carboxylate, and an aspect ratio greater than 100. The aspect ratio is defined by the width of an adamantane-intercalated LDH particle divided by the thickness of the adamantane-intercalated LDH particle. The mixed-metal oxide particles comprise a mixed-metal oxide phase containing M, Al or Fe, and carbon.

The disclosure provides methods and reagents for removing pesticides or pesticide residues from plant matter such as cannabis plant matter. The method uses Countercurrent Partition Chromatography (CPC).