This invention relates to metal organic framework (MOF) compositions, methods of preparing them and methods of using them. The MOF compositions are characterized in that at least a portion of the linker molecule is an amino containing organic linker. The MOF also has a crystal size of greater than 1 μm and has been treated with an acid wash to provide a MOF in which at least 55% of the amino groups are activated amino groups of the form —NH.sub.2. The MOF compositions are useful in adsorbing various contaminants from various gas stream. One specific example is adsorbing NO.sub.2 from an air stream.

This invention relates to modified MOF materials, methods of preparing them and processes using them. A modified MOF of the invention is modified by impregnating a MOF with an inorganic metal salt. The starting MOF contains at least one linker or ligand which contains an aryl amino group as part of its structure. These modified MOFs are able to adsorb either basic or acidic toxic industrial compounds (TIC). The modified MOFs can be used to remove TICs from various gaseous streams such as air.

Described are gas storage medium and methods of storing source gases in the gas storage medium, particularly relating to using hydroxylated metal oxides or hydroxylated metalloid oxides as a storage medium for storing diborane.

The disclosure provides a device for purification, sterilization and deodorization of air. The device includes a housing, a sterilization and disinfection device, a fan, a deodorization device, and a photocatalyst reactor. The housing is in a barrel shape and includes a side wall including a plurality of air inlets. The fan is disposed on one end of the housing. The deodorization device, the photocatalyst reactor and the sterilization and disinfection device are disposed in the housing.

An apparatus and method are provided for purifying air for breathing. The apparatus includes an armrest having a receiver and an air purification module releasably received in the receiver. The air purification module is portable and displaceable between a first operating position held in the receiver and a second operating position remote from the armrest and the vehicle.

A system for mitigating naturally occurring radioactive materials (NORM) in an oxidative dehydrogenation process includes a feed stream, an oxidative dehydrogenation (ODH) reactor, an effluent stream, a processing unit, and a NORM reduction unit. The feed stream includes oxygen, a hydrocarbon, and NORM. The ODH reactor is configured to receive the feed stream and react the hydrocarbon with the oxygen to form a dehydrogenated hydrocarbon and water. The effluent stream includes the dehydrogenated hydrocarbon, water, unreacted hydrocarbon, and NORM. The processing unit is configured to process the effluent stream to form product stream and a recycle stream. The product stream includes the dehydrogenated hydrocarbon. The recycle stream includes unreacted hydrocarbon and NORM. The NORM reduction unit is configured to reduce an amount of the NORM in the recycle stream to produce a NORM-reduced recycle stream. The ODH reactor is configured to receive the NORM-reduced recycle stream.

A plasma abatement process for abating effluent containing compounds from a processing chamber is described. A plasma abatement process takes gaseous foreline effluent from a processing chamber, such as a deposition chamber, and reacts the effluent within a plasma chamber placed in the foreline path. The plasma dissociates the compounds within the effluent, converting the effluent into more benign compounds. Abating reagents may assist in the abating of the compounds. The abatement process may be a volatizing or a condensing abatement process. Representative volatilizing abating reagents include, for example, CH.sub.4, H.sub.2O, H.sub.2, NF.sub.3, SF.sub.6, F.sub.2, HCl, HF, Cl.sub.2, and HBr. Representative condensing abating reagents include, for example, H.sub.2, H.sub.2O, O.sub.2, N.sub.2, O.sub.3, CO, CO.sub.2, NH.sub.3, N.sub.2O, CH.sub.4, and combinations thereof.

An air purifier and conditioner (and concomitant method of simultaneously purifying and conditioning air) comprising a housing receiving source air and an aqueous solution, a drop charger receiving the source air and providing a spray of electrically charged drops of the aqueous solution to produce treated air, a mist eliminator eliminating liquid in the treated air and producing conditioned air, a heat exchanger receiving the conditioned air and producing supply air, and a fan moving the supply air to a facility employing the supply air.

The embodiments herein provide a filter for cigarette comprising graphene nano-composite based material enclosed in a casing. The filter is reusable and is plugged to any cigarette, or tobacco smoking products. The filter is a stand-alone product or manufactured integrally with each individual cigarette. The filter provides a safe smoking option to tobacco smokers without changing their smoking habits by reducing the tar content and other toxic chemicals in the inhaled smoke. The graphene based nanocomposite filter adsorbs the toxic agents from the smoke of cigarette, beedi, hookah. The filter is fabricated by treating ceramic particles and coating them with carbon particles. The carbon particles are carbonized. The ceramic particles coated with carbon are segregated based on shape and size and treated chemically to convert carbon into graphene under inert conditions. The graphene coated particles are chemically functionalized for improved filtration.

A gas sensor includes a sensor element that has an atmospheric-air introduction path into which atmospheric air is introduced. The sensor element includes a solid electrolyte body, an insulating body, an exhaust electrode, and an atmosphere electrode. The solid electrolyte body has ion conductivity. The insulating body is laminated onto the solid electrolyte body. The exhaust electrode is provided in the solid electrolyte body and exposed to an exhaust gas. The atmosphere electrode is provided in a position that opposes the exhaust electrode in the solid electrolyte body. The atmosphere electrode is used so as to be paired with the exhaust electrode, and is exposed to atmospheric air. The atmospheric-air introduction path is formed to house the atmosphere electrode in a section of the insulating body that opposes the solid electrolyte body. The atmospheric-air introduction path is provided with a trap layer for capturing toxic substances in the sensor element.