An adsorbent device includes adsorbent fibers laid along or wound around a center tube. In a specific example, the adsorbent fibers are porous solid amine adsorbent fibers. A module for purifying a raw fluid includes one or more adsorbent devices that can be installed in a vessel in series or in parallel. The module can be configured for axial or cross flow operation and can be employed to purify a gas containing a contaminant such as an acid gas. In some implementations, the module is provided with one or more heating elements that can be used to release adsorbed contaminant to regenerate the adsorbent fibers.

A system including biogas purification and provides biogas as feedstock to a solid oxide fuel cell. The biogas purification treatment process provides a polished biogas that is substantially free of carbonyl sulfides and hydrogen sulfide. The system uses a biogas treatment apparatus, that includes apparatus such as a packed columns, comprising copper oxide or potassium permanganate packing material, and an activated carbon component configured to treat the biogas by polishing it to remove carbonyl sulfides and deleterious trace residues, such as hydrogen sulfide, that were not removed by any prior bulk H2S removal steps. In addition, an oil removal device is used to remove any entrained fine oil droplets in the biogas. A polished biogas having in the range of 60% methane is charged to the fuel cell. Electricity generated may be fed into a grid or used directly as energy to charge electrical-powered vehicles, for example. Energy credits are tracked in real time and are appropriately assigned.

An adsorption material is disclosed that comprises a metal-organic framework and a plurality of ligands. The metal-organic framework comprising a plurality of metal ions. Each respective ligand in the plurality of ligands is amine appended to a respective metal ion in the plurality of metal ions of the metal-organic framework. Each respective ligand in the plurality of ligands comprises a substituted 1,3-propanediamine. The adsorbent has a CO.sub.2 adsorption capacity of greater than 2.50 mmol/g at 150 mbar CO.sub.2 at 40° C. Moreover, the adsorbent is configured to regenerate at less than 120° C. An example ligand is diamine 2,2-dimethyl-1,3-propanediamine. An example of the metal-organic framework is Mg.sub.2(dobpdc), where dobpdc.sup.4− is 4,4′-dioxidobiphenyl-3,3′-dicarboxylate. Example applications for the adsorption material are removal of carbon dioxide from flue gas and biogasses.

The invention concerns a plant and a method for treating gas by chemical, physical or hybrid absorption of compounds for removal, comprising at least: a) a step of absorption by contacting a gas for treatment with a depleted solvent to give a treated gas and a rich solvent; b) a step of optional separation by medium-pressure flashing c) a step of heat exchange between a fraction of the cold rich solvent and the hot depleted solvent in a first heat exchanger d) a step of heat exchange between the complementary fraction of the cold rich solvent and a hot gaseous effluent in a second exchanger e) a step of optional separation by low-pressure flashing f) a step of regeneration of the rich solvent by heating in a reboiler g) a step of separation by low-pressure flashing h) a cooling of the depleted solvent.

A method for separating carbon dioxide and water from a gas mixture by cyclic adsorption/desorption, using a unit containing an adsorber structure, comprising the following repeating steps: (a) contacting said mixture with sorbent material; (b) at least one of evacuating said unit and heating said sorbent material and extracting the gaseous carbon dioxide and water vapour and separating gaseous carbon dioxide from water vapour; (c) cooling the adsorber structure and re-pressurisation; wherein (i) in step (c) the heat released is stored in a first heat storage device; (ii) during step (b) the sensible and latent heat of gaseous carbon dioxide and water vapour as product gases is stored in second heat storage device; and (iii) during step (b) the heat required for heating said sorbent material is supplied from heat recovered in at least one of step actions (i) and (ii) of previous sequence(s).

Culture systems and methods of using same. The systems include a housing defining an inner space. The inner space includes a headspace and at least a portion of a reservoir. A surface for immobilizing cells is moveable between the headspace and the reservoir. The systems can be used for coculturing methanotrophs and phototrophs for processing biogas and wastewater, particularly from anaerobic digesters.

The present invention provides a device and method for sulphur cycle-based advanced denitrification of wastewater coupling autotrophic denitrification and heterotrophic denitrification, and belongs to the technical field of wastewater treatment. The unit generating hydrogen sulfide during the wastewater treatment process adopts a lye to absorb hydrogen sulfide; the absorbed sulfide is introduced into an anoxic tank that removes nitrate nitrogen through sulfur-based autotrophic denitrification; and the remaining organic matters in the anaerobic methane-producing reaction tank are subjected to heterotrophic denitrification in the anoxic tank, and the anoxic unit combines the sulfur-based autotrophic denitrification with the heterotrophic denitrification of organic matters. The coupling of sulfur-based autotrophic denitrification and heterotrophic denitrification strengthens the removal of nitrate nitrogen. The biogas desulfurization process system only absorbs hydrogen sulfide and uses the absorbed sulfide in an anoxic system to realize the recovery and utilization of sulfur.

Disclosed are a CHA zeolite membrane and a method of preparing the same, and more particularly, a CHA zeolite membrane having high capacity to separate CO.sub.2/N.sub.2 and CO.sub.2/CH.sub.4 even under wet conditions using a membrane produced using a synthetic precursor having a controlled ratio of Si and Al, a method of preparing the same, and a method of capturing and removing carbon dioxide using the membrane.

A method for producing a carbon fiber material is disclosed, the method comprising the steps of a) Preparation of a solution of polyacrylonitrile in a suitable organic solvent b) Electrospinning of the solution obtained in a) and drying of the obtained fiber material c) Crosslinking of the obtained fiber material by heating to 150 to 350° C. in an air or oxygen atmosphere for 1 to 30 h d) Carbonization of the obtained fiber material in an inert gas atmosphere at a temperature in the range of 500 to 2,500° C., characterized in that no silicon, sulfur, metal compounds, intermetallic compounds, silicon compounds and/or sulfur compounds are added to the polyacrylonitrile solution in step a) and that neither stabilization nor surface modification steps are carried out with the fiber material by treatment with chemical reagents and/or exposure to tensile stress.

Also disclosed is a carbon fiber material obtainable by the above process, as well as a carbon fiber material, characterized in that it has a proportion of ultramicropores V.sub.<0.4 nm of 0.01 to 10, more preferably 0.02 to 5, even more preferably 0.025 to 0.1, most preferably 0.03 to 0.06 cm.sup.3/g, determined by CO.sub.2 adsorption tests and evaluation with DFT and GC-MC simulation.

A facility and method for membrane permeation treatment of a feed gas flow containing at least methane and carbon dioxide that includes a compressor, a pressure measurement device, at least one valve, and first, second, third, and fourth membrane separation units for separation of CO.sub.2 from CH.sub.4 to permeates enriched in CO.sub.2 and retentates enriched in CH.sub.4, respectively. The at least one valve adjusts the number of membranes combined and connected to the flow of gas entering into at least one of the membrane separation units as a function of the pressure recorded by the pressure measurement device.