Systems for and methods of treating a fluid containing siloxanes, silanes and/or other silicon compounds. A hot box is configured to receive an initial flow of the fluid, react the flow with water at a temperature and pressure suitable for hydrolysis to generate a first treated flow, in which at least a portion is hydrolyzed to produce silicon dioxide and methane, and discharge the first treated flow. A solid removal mechanism can be configured to receive the first treated flow, separate at least a portion of the silicon dioxide as solid material, and discharge the remaining components as a second treated flow. Techniques of the present disclosure can lead to very low siloxane levels.

An entirely water-based, energy self-sufficient, integrated in-line waste management system is provided for comprehensive conversion of all organic fractions of municipal and wider community waste to fuels suitable for use in transportation, with all solid residues converted to high nutrition compost. The system is based on a combination of pre-treatment, involving alkaline hydrolysis and saponification; three-way separation of the pre-treated waste into different streams that are each directed to suitable further processing including fuel production; which includes biodiesel generation in a continuous-flow catalytic esterification unit, and anaerobic digestion to produce methane or other small molecule biofuel. Remaining solids are converted to compost in a quasi-continuous process.

Primary, secondary (1°,2°) alkylethylenediamine- and alkylpropylenediamine-appended variants of metal-organic framework are provided for CO.sub.2 capture applications. Increasing the size of the alkyl group on the secondary amine enhances the stability to diamine volatilization from the metal sites. Two-step adsorption/desorption profiles are overcome by minimzing steric interactions between adjacent ammonium carbamate chains. For instance, the isoreticularly expanded framework Mg.sub.2(dotpdc) (dotpdc.sup.4−=4,4″-dioxido-[1,1′:4′,1″-terphenyl]-3,3″-dicarboxylate), yields diamine-appended adsorbents displaying a single CO.sub.2 adsorption step. Further, use of the isomeric framework Mg-IRMOF-74-II or Mg.sub.2(pc-dobpdc) (pc-dobpdc.sup.4−=3,3-dioxidobiphenyl-4,4-dicarboxylate, pc=para-carboxylate) also leads to a single CO.sub.2 adsorption step with bulky diamines. By relieving steric interactions between adjacent ammonium carbamate chains, these frameworks enable step-shaped CO.sub.2 adsorption, decreased water co-adsorption, and increased stability to diamine loss. Variants of Mg.sub.2(dotpdc) and Mg.sub.2(pc-dobpdc) functionalized with large diamines such as N-(n-heptyl)ethylenediamine have utility as adsorbents for carbon capture applications.

It is provided a water-saturated carbon molecular sieve membrane obtainable by a) providing a hydrophilic carbon molecular sieve membrane (CMSM) comprising pores of a pore size from 0.25 nm to 0.55 nm for molecular sieving, pores of a pore size from 0.55 nm to 0.90 nm for adsorption diffusion and a negligible amount of pores larger than 0.90 nm such that a plot of N.sub.2 permeance versus pressure of permeation at room temperature and at a pressure from 1 to 4 bar has zero or negative slope; and b) humidifying the membrane until obtaining a water-saturated carbon molecular sieve membrane. It is also provided a process for the separation of a gas from a gas mixture with such a water-saturated membrane, and its use for solvent dehydration, and as a membrane reactor.

Processes, systems, and associated control methodologies are disclosed that control the flow of biogas during the biogas cleanup process to create a more consistent flow of biogas through the digester, while also optimizing the output and efficiency of the overall renewable natural gas facility. In representative embodiments, a biogas buffer storage system may be used during the cleanup process to control the pressure and flow rate of biogas. The biogas buffer storage system may monitor and control the biogas flow rate to either bring down or increase the digester pressure, thereby maintaining a normalized biogas flow rate.

Provided is a carbon dioxide recovery device including an absorption part that produces a compound of carbon dioxide and an amine contained in an absorbing solution, and a regeneration part that includes an anode that desorbs the carbon dioxide from the compound to produce a complex compound of the amine, and a cathode that is electrically connected to the anode and regenerates the amine from the complex compound.

In a process for treating a carbon dioxide-rich gas (1) containing water, the treatment by compression and/or washing and/or drying of the gas produces acidified water (W1, W2, W3, W4, W7) which is sent to a cooling circuit (W8, W10).

The present invention concerns porous carbonaceous particles having pores including micropores and macropores, having a mean diameter, determined by laser diffraction, ranging from 15 to 100 μm and porous carbonaceous monoliths comprising aggregates of said carbonaceous particles.

A high selectivity and high CO.sub.2 plasticization resistant polymer comprises a plurality of repeating units of formula (I) for gas separation applications. The polymer may be synthesized from a superacid catalyzed poly(hydroalkylation) reaction.

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Membranes made from the polymer and gas separation processes using the membranes made from the polymer are also described.

An apparatus and process for separating a gas mixture is disclosed. The apparatus includes a first membrane stage, a second membrane stage, and a third membrane stage. The first membrane stage includes a first gas separation membrane configured to separate the gas mixture into a first retentate stream and a first permeate stream. The second membrane stage includes a second gas separation membrane configured to separate the first permeate stream into a second retentate stream and a second permeate stream. The second retentate stream of the second membrane stage is recycled back to connect with the first retentate stream to form a mixed fluid stream. The third membrane stage includes a third gas separation membrane configured to separate the mixed fluid stream into a third retentate stream and a third permeate stream, and the third retentate stream is configured to be withdrawn as a product or discarded.