An engineered ecosystem, moderating eight primary systemsthermal management, atmospheric optimization, radiation controls, hydrological systems, energy systems, material flows, systems management, and built systemsto provide homeostatic regulation of cascading flows of matter and energy.

Outside air is cooled and dehumidified by a pre-cooler to pass through an adsorption zone of a carbon dioxide adsorbing rotor, producing air having a low carbon dioxide concentration which is cooled by an intercooler. The air that has passed through the intercooler is passed through an adsorption zone of a moisture adsorption rotor and then supplied to a low humidity working chamber. Return air from the low humidity working chamber may be mixed with the air leaving the pre-cooler. A part of the air which passed through the intercooler is branched to pass through a purge zone of the moisture adsorption rotor before being sent to a regeneration zone of the humidity adsorption rotor. Air that passed through the regeneration zone of the humidity adsorption rotor is mixed with outside air and then passed through a regeneration zone of the carbon dioxide adsorption rotor before being exhausted.

A method of operating a carbon dioxide recovering apparatus includes introducing flue gas into an absorbing tower, bringing the flue gas into contact with an absorbing solution, and discharging a first rich solution, which is then divided into second and third rich solutions. The second rich solution is heated using a lean solution from a releasing tower. The third rich solution is heated using steam from the releasing tower. The lean solution and the steam are generated in the releasing tower from the second and third rich solutions. The steam used to heat the third rich solution is separated, in a gas-liquid separator, into carbon dioxide and condensate water. The amount of condensate water formed in the gas-liquid separator is measured, and a flow dividing ratio between the second rich solution and the third rich solution is controlled based on a change in the amount of the condensate water.

Processes for separating CO from CO.sub.2 in flue gas streams from partial oxidation regenerator in FCC processes, as well as reducing the sulfur content of the flue gas stream are described. The processes involve separating the cooled reactor effluent stream into a CO.sub.2 product stream, the CO.sub.2 recycle stream, and a CO product stream. The processes may incorporate either dry sorbent injection (DSI) units or wet gas scrubbing units to remove sulfur compounds. The separation processes can utilize cryogenic fractionation, pressure swing adsorption (PSA) processes including vacuum PSA, and temperature swing adsorption (TSA) processes. The flue gas stream can be used to preheat the CO.sub.2 recycle stream.

The present disclosure relates to systems and methods useful for providing one or more chemical compounds in a substantially pure form. In particular, the systems and methods can be configured for separation of carbon dioxide from a process stream, such as a process stream in a hydrogen production system. As such, the present disclosure can provide systems and method for production of hydrogen and/or carbon dioxide.

In accordance with exemplary inventive practice, a catalytic system and a temperature swing adsorption system are thermally integrated. The temperature range of the adsorption system is lower than the catalyst operating temperature. Benefits of inventive practice include reduction of total energy consumption and of generated waste-heat. Total energy consumption is reduced by transferring some of the waste-heat generated by the catalytic system into the adsorption system during the sorbent heat-up portion of the sorbent regeneration cycle. The heat is transferred using a thermal reservoir, which accumulates heat from the catalytic apparatus and transfers it to the adsorption apparatus at a later time, and which is repeatedly cycled as the sorbent is cycled. The catalytic system and the adsorption system can be inventively integrated in various ways to reduce the total energy consumed, and/or to modify the sorbent regeneration temperature profile, and/or to obtain an optimum power load profile.

A method and an integrated system for reducing CO.sub.2 emissions in industrial processes. The method and integrated system (100) capture carbon dioxide (CO.sub.2) gas from a first gas stream (104) with a chemical absorbent to produce a second gas stream (106) having a higher concentration of carbon monoxide (CO) gas and a lower concentration of CO.sub.2 gas as compared to first gas stream. The CO gas in the second gas stream is used to produce C.sub.5 to C.sub.20 hydrocarbons in an exothermic reaction (108) with hydrogen (H.sub.2) gas (138). At least a portion of the heat generated in the exothermic reaction is used to regenerate the chemical absorbent with the liberation of the CO.sub.2 gas (128) captured from the first gas stream. Heat captured during the exothermic reaction can, optionally, first be used to generate electricity, wherein the heat remaining after generating electricity is used to thermally regenerate the chemical absorbent.

Disclosed herein are methods for treating an exhaust stream comprising NOx, the methods comprising receiving an exhaust stream and combining it with at least one nitrogen-containing reagent to form a combined stream, heating the combined stream to a reaction temperature ranging from about 870 C. to about 1100 C. to react at least a portion of the nitrogen-containing component, cooling the reacted stream in a first cooling step to a first temperature, and optionally further cooling the reacted stream in a second cooling step to a second temperature, wherein the first cooling step comprises heat exchange between at least a portion of the exhaust stream and at least a portion of the reacted stream. Exhaust treatment systems are also disclosed herein.

The present invention relates to a process and contactor vessel in which gas and liquid contact occurs to facilitate mass transfer therebetween. In one embodiment, the process includes a fluidised bed including mobile inert primary objects and secondary particles that facilitate turbulent mixing and enhanced gas/liquid surface area in the contactor.

For purifying waste gas charged with nitrogen oxides in a reactor with heat-accumulator chambers containing heat-accumulator materials, the raw gas to be purified alternately enters one of the heat-accumulator chambers. Mixed with a reducing agent for the reduction of the nitrogen oxides, it is supplied to a catalyst for the reduction of the nitrogen oxides, and the clean gas heats the heat-accumulator material in the heat-accumulator chamber which the clean gas exits. A partial flow is taken therefrom, heated by means of a heat source and, mixed with a reducing agent, supplied again to the heat-accumulator chamber which the raw gas enters. This heated, recirculated gas forms the only heat source for the overall system.