A catalytic membrane reactor and methods of operating and producing the same are provided that efficiently produces highly pure hydrogen (H.sub.2) from ammonia (NH.sub.3) as well as operates according to other chemical conversion processes. In one embodiment, a tubular ceramic support made from porous yttria-stabilized zirconia has an outer surface that is impregnated with a metal catalyst such as ruthenium and then plated with a hydrogen permeable membrane such as palladium. An inner surface of the ceramic support is impregnated with cesium to promote conversion of ammonia to hydrogen and nitrogen (N.sub.2). The resulting catalytic membrane reactor produces highly pure hydrogen at low temperatures and with less catalytic loading. Therefore, ammonia can be used to effectively transport hydrogen for use in, for example, fuel cells in a vehicle.

A two-reactor catalytic system including a catalytic membrane gasification reactor and a catalytic membrane water gas shift reactor. The catalytic system, for converting biomass to hydrogen gas, features a novel gasification reactor containing both hollow fiber membranes that selectively allow O.sub.2 to permeate therethrough and a catalyst that facilitates tar reformation. Also disclosed is a process of converting biomass to H2. The process includes the steps of, among others, introducing air into a hollow fiber membrane; mixing the O.sub.2 permeating through the hollow fiber membrane and steam to react with biomass to produce syngas and tar; and reforming the tar in the presence of a catalyst to produce more syngas.

Methods of recirculating clean air in an atmosphere of an enclosure comprise directing an input air stream from the atmosphere of the enclosure through a coiled duct at a rate sufficient to stratify the input air stream within the coiled duct according to a molecular weight of components of the input air stream and to form a heavy fraction stream and a light fraction stream, wherein the heavy fraction stream is relatively enriched in carbon dioxide as compared to the light fraction stream; withdrawing the heavy fraction stream from the coiled duct; and returning the light fraction stream from the coiled duct to the atmosphere of the enclosure.

A hardness reduction filter is provided. The hardness reduction filter may include a filter housing having a space formed therein, a filter provided in the space of the filter housing to filter out foreign materials from water flowing into the filter housing, and hardness reduction catalysts provided between the filter housing and the filter and configured to perform at least one of removing a hard water material contained in the water or preventing formation of a scale inducing material in the water flowing into the filter housing.

A molecular separation method can include: passing a deasphalted oil stream through a reactor containing an active substrate, wherein the catalytic active substrate adsorbs heteroatom species from the deasphalted oil stream and produces a pretreated hydrocarbon feed stream essentially free of 4+ ring aromatic molecules (ARC 4+ species), metal species, and heteroatom species; and chromatographically separating with a simulated moving bed apparatus or a true moving bed apparatus (SMB/TMB) the pretreated hydrocarbon feed stream into a saturate fraction and an aromatics fraction.

A drainless reverse osmosis (RO) water purification system provides relatively pure water for on-demand dispensing, while recycling brine to a domestic hot water system. The drainless purification system includes a pre-filter catalyst cartridge for removing chlorine-based contaminants from a tap water supply upstream from an RO membrane. The catalyst is regularly refreshed by a high through-flow of water to a conventional cold water dispense faucet, thereby significantly prolonging the service life of the RO membrane. The RO membrane is incorporated into a multi-cartridge unit adapted for facilitated slide-out removal and replacement as needed. A control valve recycles brine from the RO membrane to the hot water system during pure water production, and recirculates tap water through the RO membrane when a pure water reservoir is substantially filled. The multi-cartridge unit may further include an air filtration system for providing a flow of filtered air.

A catalytic membrane reactor and methods of operating and producing the same are provided that efficiently produces highly pure hydrogen (H.sub.2) from ammonia (NH.sub.3) as well as operates according to other chemical conversion processes. In one embodiment, a tubular ceramic support made from porous yttria-stabilized zirconia has an outer surface that is impregnated with a metal catalyst such as ruthenium and then plated with a hydrogen permeable membrane such as palladium. An inner surface of the ceramic support is impregnated with cesium to promote conversion of ammonia to hydrogen and nitrogen (N.sub.2). The resulting catalytic membrane reactor produces highly pure hydrogen at low temperatures and with less catalytic loading. Therefore, ammonia can be used to effectively transport hydrogen for use in, for example, fuel cells in a vehicle.

A manufacturing method for a separation membrane element is a manufacturing method for a spiral-wound type separation membrane element including a perforated hollow tube and a laminated body that includes a separation membrane and is wound around the hollow tube. The manufacturing method includes pressing a press member against a portion of the laminated body that is wound around the hollow tube. The pressing presses the press member to satisfy respective relations defined by formulas (1) and (2):

0.1Ps1Pe(1), and

0.1Ps2Pe(2).

The disclosure relates to assembled membranes used in water treatment systems, including membranes used in reverse osmosis procedures and methods for making and using the membranes.

Methods of recirculating clean air in an atmosphere of an enclosure comprise directing an input air stream from the atmosphere of the enclosure through a coiled duct at a rate sufficient to stratify the input air stream within the coiled duct according to a molecular weight of components of the input air stream and to form a heavy fraction stream and a light fraction stream, wherein the heavy fraction stream is relatively enriched in carbon dioxide as compared to the light fraction stream; withdrawing the heavy fraction stream from the coiled duct; and returning the light fraction stream from the coiled duct to the atmosphere of the enclosure.