Patent classifications
B01D2323/219
NEW PROCESS FOR THE SEPARATION OF PROPYLENE FROM A GAS MIXTURE (GM) COMPRISING PROPYLENE AND PROPANE
The present invention relates to a process for the separation of propylene from a gas mixture (GM) comprising propylene and propane by means of a membrane (M) comprising a polyarylene ether sulfone polymer (P) prepared by converting a reaction mixture (R.sub.G) comprising at least one aromatic dihalogen sulfone and at least one dihydroxy component comprising trimethylhydroquinone.
MEMBRANE FOR WATER FILTRATION
A process for preparing a semi-permeable membrane includes providing an aqueous phase comprising a polyfunctional amine monomer, covering a surface of a porous support membrane with the aqueous phase, applying an organic phase comprising a polyfunctional acyl halide monomer, a phosphorous containing compound and a co-solvent, and allowing the polyfunctional amine monomer and the polyfunctional acyl halide monomer to perform an interfacial polymerization reaction to form a polyamide thin film composite layer.
The presence of the co-solvent together with the phosphorous compound in the organic phase potentiates the effect of the phosphorous compound so that the water flux is increased without substantially sacrificing the salt rejection.
Polyether block polyamide/polydimethylsiloxane composite membrane for gas separation, and preparation method and use thereof
The present disclosure relates to a polyether block polyamide/polydimethylsiloxane (PDMS) composite membrane for gas separation, and a preparation method and use thereof, and belongs to the technical field of membrane separation. In the present disclosure, an amphoteric copolymer PDMS-polyethylene oxide (PEO) (PDMS-b-PEO) is introduced into an intermediate layer to adjust the interfacial binding performance, thereby promoting preparation of an ultra-thin polyether block polyamide composite membrane. Studies have shown that the surface enrichment of PEO segments not only inhibits a dense SiO.sub.x layer formed due to a plasma treatment of a PDMS intermediate layer, but also provides additional hydrophilic sites and interfacial compatibility for the subsequent selective layer. The use of PDMS-b-PEO in an intermediate layer allows the successful preparation of a selective layer with a thickness of about 50 nm.
Method for manufacturing polyamide-based water-treatment separator having excellent permeation flux characteristics and water-treatment separator manufactured by same
The present invention relates to a method for manufacturing a water treatment separation membrane, the method including: forming an aqueous solution layer including an amine compound on a porous support; and bringing an organic solution including an acyl halide compound into contact with on the aqueous solution layer to form a polyamide active layer, in which the organic solution includes a non-polar solvent and an amphiphilic solvent having a boiling point of 120 C. or more, thereby improving a permeation flux, and a water treatment separation membrane manufactured by the manufacturing method.
POLYETHER BLOCK POLYAMIDE/POLYDIMETHYLSILOXANE COMPOSITE MEMBRANE FOR GAS SEPARATION, AND PREPARATION METHOD AND USE THEREOF
The present disclosure relates to a polyether block polyamide/polydimethylsiloxane (PDMS) composite membrane for gas separation, and a preparation method and use thereof, and belongs to the technical field of membrane separation. In the present disclosure, an amphoteric copolymer PDMS-polyethylene oxide (PEO) (PDMS-b-PEO) is introduced into an intermediate layer to adjust the interfacial binding performance, thereby promoting preparation of an ultra-thin polyether block polyamide composite membrane. Studies have shown that the surface enrichment of PEO segments not only inhibits a dense SiO.sub.x layer formed due to a plasma treatment of a PDMS intermediate layer, but also provides additional hydrophilic sites and interfacial compatibility for the subsequent selective layer. The use of PDMS-b-PEO in an intermediate layer allows the successful preparation of a selective layer with a thickness of about 50 nm.
Polymeric Hollow Fiber Membrane Having A Crosslinked Selective Layer, Carbon Molecular Sieve Hollow Fiber Membrane, And Methods For Preparing The Same
A polymeric hollow fiber membrane is provided having a crosslinked selective layer formed by sequentially performing coating of a polymer precursor on a crosslinked polymeric hollow fiber membrane support and thermal condensation and thermal crosslinking thereof, a carbon molecular sieve hollow fiber membrane, methods for producing the same, and methods of separating gases using the same. The polymeric hollow fiber membrane and the carbon molecular sieve hollow fiber membrane each have a thin crosslinked selective layer and excellent plasticization resistance and separation performance. Accordingly, the polymeric hollow fiber membrane and the carbon molecular sieve hollow fiber membrane, each of which has a thin crosslinked selective layer, can be effectively used in the separation of a mixed gas.
SCALING-RESISTANT AND YELLOWING-RESISTANT REVERSE OSMOSIS COMPOSITE MEMBRANE AND PREPARATION METHOD THEREOF
The present disclosure relates to a scaling-resistant and yellowing-resistant composite reverse osmosis membrane and a preparation method thereof. By modifying the stability and yellowing of a coating of the reverse osmosis membrane, and grafting 2-(methacryloyloxy)ethyl)dimethyl-3-sulphoproyl) ammonium hydroxide (MEDSAH) and ethylene glycol methacrylate (EGMA) as amphoteric monomers and N-(isobutoxymethyl)acrylamide (IBMA) as yellowing-resistant particles on a surface of the reverse osmosis membrane using active polymerization, the present disclosure forms a three-network high-performance PMEDSAH/PEGMA/PIBMA composite coating. By active regulation of a polyamide (PA) layer through the three systems, the reverse osmosis membrane has high compatibility due to PMEDSAH, and stability, high hydrophilicity and anti-protein fouling property due to PEGMA, as well as yellowing-resistant property by coating PIBMA on the surface. The test results show that the reverse osmosis membrane prepared by the present disclosure has excellent stability and yellowing-resistant property. And the flux and salt rejection are also higher than those of the existing reverse osmosis membranes.
MACROPOROUS POLYVINYLIDENE FLUORIDE (PVDF) MEMBRANES
The invention relates to macroporous, hydrophobic and isotropic polyvinylidene fluoride (PVDF) membranes having improved properties and to a new method for preparing the same
METHOD FOR MANUFACTURING HOLLOW FIBER MEMBRANE
A method for manufacturing a hollow fiber membrane wherein a spinning stock solution containing 10 mass % or more and 40 mass % or less of a polysulfone-based resin, 1 mass % or more and 30 mass % or less of polyvinylpyrrolidone, and 1 mass % or more and 80 mass % or less of N,N-dimethylformamide is discharged together with a core liquid from a double-ring nozzle to produce a hollow fiber membrane by dry-wet spinning, and then the hollow fiber membrane is subjected to a dry heat treatment at a temperature of 80? C. or higher and 100? C. or lower for 48 hours or longer and 168 hours or shorter.
FILTRATION MEDIA AND SYSTEMS FOR REDUCTION OF MICROPOLLUTANTS IN LIQUIDS
A washing machine includes a filter that is operably connected to a water circulation system to filter water. The filter may include a mesh filter element and a porous membrane whereby water passes through the mesh element and then through the porous membrane prior to exiting the washing machine. The porous membrane may include a plurality of openings of about 5 microns to about 100 microns to capture microparticles.