A method for making a composite polyamide membrane comprising a porous support and a thin film polyamide layer, wherein the method includes the step of applying a polyfunctional amine monomer and polyfunctional acyl halide monomer to a surface of the porous support and interfacially polymerizing the monomers to form a thin film polyamide layer, wherein the step of applying the polyfunctional acyl halide monomer to the porous support includes the step of combining the polyfunctional acyl halide monomer with a non-polar solvent at a concentration of at least 0.18 weight percent to form a coating solution which is applied to the surface of the porous support, and wherein the interfacial polymerization is conducted in the presence of a tri-hydrocarbyl phosphate compound which is provided in a molar ratio of at least 0.5:1 with the polyfunctional acyl halide monomer. Many additional embodiments are described including membranes made from the subject method and applications for such membranes.

A method for making a composite polyamide membrane including a porous support and a thin film polyamide layer, wherein the method includes the step of applying a polyfunctional amine monomer and a tetraacyl acyl halide monomer represented by Formula (I) to a surface of the porous support and interfacially polymerizing the monomers to form a thin film polyamide layer; wherein A is selected from: oxygen (O); carbon (C); silicon (Si); each of which may be unsubstituted or substituted, e.g. with alkyl groups of 1-4 carbon atoms; or a carbonyl group (C(O)), X is the same or different and is selected from a halogen, and Y is selected from halogen and hydroxide. ##STR00001##

A thin film composite polyamide membrane having a porous support and a thin film polyamide layer comprising a reaction product of m-phenylene diamine (mPD) and trimesoyl chloride (TMC), characterized by the thin film polyamide layer having a critical strain value of less than 10%. In another embodiment, the thin film polyamide layer has a modulus of greater than 0.75 (GPa). In yet another embodiment, the thin film polyamide layer has an equilibrium swelling value of at least 45%. In another embodiment, the thin film polyamide layer has a thickness of at least 230 nm.

A thin film composite membrane including a porous support and a thin film polyamide layer characterized by having a dissociated carboxylate content of at least 0.45 moles/kg at pH 9.5 and a method for making a composite polyamide applying a polar solution comprising a polyfunctional amine monomer and a non-polar solution comprising a polyfunctional amine-reactive monomer to a surface of the porous support and interfacially polymerizing the monomers to form a thin film polyamide layer, wherein the method is characterized by the non-polar solution comprising at least 0.025 wt % of an acid compound including at least one carboxylic acid moiety and at least one amine-reactive moiety selected from acyl halide and anhydride.

A composite polymeric membrane includes polylactic acid polymer and an additive component, wherein the additive component includes activated carbon functionalized with polyethylenimine. A method of filtering a liquid includes contacting a liquid with a composite polymeric membrane, wherein the liquid includes one or more metals and the membrane includes an additive component and a polylactic acid polymer, and wherein the additive component includes activated carbon functionalized with polyethylenimine.

The present invention relates to a process for the preparation of a polyarylether copolymer (P), the polyarylether copolymer (P) obtained by the process and a process for the preparation of a membrane comprising the polyarylether copolymer (P) and the membrane itself.

The present invention relates to the development and fabrication of thin-film polymer composite materials containing vertically aligned nanopores. The present invention provides methods of aligning nanopores in a polymeric film. The present invention also provides composite materials and methods of fabricating composite materials containing vertically aligned nanopores.

A metal organic framework glass membrane and a preparation method thereof are provided. The preparation method includes a step of heating a crystalline metal organic framework material to the melting temperature at a rate of 1-15 C./min and then naturally cooling the crystalline metal organic framework material. The crystalline metal organic framework material contains a metal node and a ligand A. The metal node is a zinc ion and/or a cobalt ion and the ligand A is imidazole or phosphoric acid. The metal organic framework glass membrane has a wide range of membrane-forming conditions, and the material thereof can be melted without being decomposed within a control range to form a continuous glass layer with good repeatability.

A method for manufacturing a silica membrane filter includes performing, at least once, a fired membrane forming operation having a membrane forming step of applying, to a porous substrate, a precursor sol which is a sol of a silicon alcoxide including a p-tolyl group to form a precursor sol membrane, a drying step of drying the precursor sol membrane formed in the porous substrate to form a dried membrane, and a firing step of firing the dried membrane formed in the porous substrate to form a fired membrane, thereby preparing the silica membrane filter including the porous substrate and a silica membrane which is the fired membrane formed in the porous substrate, and a ratio of a total mass of the silica membrane to a total mass of the dried membrane is 38 mass % or more and 85 mass % or less.

An asymmetric membrane having a substantially non-porous surface layer is made by a method including: dissolving a poly(phenylene ether) copolymer in a solvent mixture including a first solvent and a second solvent to provide a membrane-forming composition; and phase-inverting the membrane forming composition in a first non-solvent to form the membrane comprising a substantially non-porous surface layer. The first solvent is a water-miscible polar aprotic solvent, and the second solvent is a polar solvent having two to eight carbon atoms.