Provided is a composition for use in fabricating a carbon molecular sieve membrane, including a fluorine-containing polymer matrix and polysilsesquioxane. The composition shows high selectivity to the gas to be separated and high separation quality by controlling the mixing ratio of the fluorine-containing polymer matrix with polysilsesquioxane as well as the type of fluorine-containing polymer matrix and polysilsesquioxane. Ancillary selective pore formation is enhanced by a so-called autogenous fluorinated gas induced siloxane etching (A-FISE) mechanism of fluorine-containing polymer/polysilsesquioxane blend precursors during carbonization. Therefore, it is possible to effectively separate gases having a small difference in particle size, which, otherwise, are difficult to be separated with the conventional polymer membranes.

Composite membranes comprising a layer having first and second microporous surfaces and a bulk between the surfaces, the bulk comprising a first set of pores having outer rims, and a second set of pores connecting the rims, and a polymer matrix supporting the first set of pores; and, a second layer having first and second porous surfaces and a second bulk between the porous surfaces, wherein the second bulk comprises a fibrous matrix; or, first and second microporous surfaces and a second bulk between the microporous surfaces, the second bulk comprising: a third set of pores having outer rims and a fourth set of pores connecting the rims, and a polymer matrix supporting the third set of pores; a third set of pores prepared by phase inversion; or, a fibrous matrix; or, a third set of pores prepared by stretching, track etching or e-beam, are disclosed.

Disclosed is a charged hollow fiber membrane having hexagonal voids for use in high throughput applications. The membrane includes: (i) an inner surface; (ii) an outer surface; (iii) a porous bulk disposed therebetween, wherein the porous bulk comprises at least a first region including: a) a first set of pores having a controlled pore size and having outer rims; b) a second set of pores connecting the outer rims of the first set of pores, wherein the pore size of the first set of pores is greater than the pore size of the second set of pores; and c) a polymer matrix supporting the first set of pores; and (iv) at least one charged zone disposed on the inner surface, on the outer surface, and/or in the porous bulk hollow fiber membrane. Also disclosed is a method for preparing such hollow fiber membranes, which involves coating a filament with a coating composition that includes a membrane-forming polymer, a charged polymer, and dissolvable nanoparticles, followed by phase invention, dissolving of the nanoparticles, and removal of the filament.

A method for making a filter membrane includes: forming a polymer layer; applying a plurality of nanoparticles on the polymer layer, the nanoparticles being self-assembled to form a closed pack arrangement on the polymer layer; heating the nanoparticles such that a portion of the polymer layer contacting the nanoparticles is softened so that the nanoparticles are sunk into the polymer layer; and removing the nanoparticles from the polymer layer so that the polymer layer is formed with a plurality of pores penetrating the polymer layer and being arranged in a honeycomb pattern.

A method for preparing a ceramic fiber filter tube with high air permeability, including: using mullite short fibers as aggregates, adding glass fibers and silica sol as sintering aids, obtaining a ceramic fiber filter tube green body by using a filterer-pressing forming process, and obtaining the ceramic fiber filter tube with high air permeability by freeze-drying and heat treatment in turn. The combination of two sintering aids with different properties can effectively improve the performance of ceramic fiber filter tube prepared by a wet forming technology. At the same time, the freeze-drying treatment can block the migration path of nanoparticles in the silica sol to the surface of the ceramic fiber filter tube due to the capillary force, so that the properties of the prepared ceramic fiber filter tube are more uniform, providing a reference for the preparation of a ceramic fiber membrane with high flux.

A zeolite membrane complex includes a porous support, and a zeolite membrane formed on the support and composed of an 8-membered ring zeolite. The zeolite membrane is selectively permeable to hydrogen sulfide rather than nitrogen for a gas containing nitrogen and hydrogen sulfide.

The present disclosure provides a porous hollow fiber membrane that exhibits blocking performance and water permeability performance suitable for filtration applications, as well as having excellent chemical resistance. In order to provide a solution to the above issue, the porous hollow fiber membrane of the present disclosure is made of a thermoplastic resin, wherein the crystallization onset temperature is 140 C. or lower, and the enthalpy of crystal fusion at and below the crystallization onset temperature is 10 J/g or less.

A method for preparing a ceramic fiber filter tube with high air permeability, including: using mullite short fibers as aggregates, adding glass fibers and silica sol as sintering aids, obtaining a ceramic fiber filter tube green body by using a filterer-pressing forming process, and obtaining the ceramic fiber filter tube with high air permeability by freeze-drying and heat treatment in turn. The combination of two sintering aids with different properties can effectively improve the performance of ceramic fiber filter tube prepared by a wet forming technology. At the same time, the freeze-drying treatment can block the migration path of nanoparticles in the silica sol to the surface of the ceramic fiber filter tube due to the capillary force, so that the properties of the prepared ceramic fiber filter tube are more uniform, providing a reference for the preparation of a ceramic fiber membrane with high flux.

According to an aspect of the present inventive concept there is provided a method for manufacturing a membrane with through-going pores, the method comprising: controlling starting points for the through-going pores by forming indents on a surface of a semiconductor substrate using a dry-etch process; forming the pores, at locations of the starting points, through the semiconductor substrate using electrochemical etching, wherein the electrochemical etching through the semiconductor substrate selectively starts at the starting points.

Provided is a method for making a porous graphene layer of a thickness of less than 100 nm, including the following steps: providing a catalytically active substrate, said catalytically active substrate on its surface being provided with a plurality of catalytically inactive domains having a size essentially corresponding to the size of the pores in the resultant porous graphene layer; and chemical vapour deposition and formation of the porous graphene layer on the surface of the catalytically active substrate. The catalytically active substrate is a copper-nickel alloy substrate with a copper content in the range of 98 to less than 99.96% by weight and a nickel content in the range of more than 0.04-2% by weight, the copper and nickel contents complementing to 100% by weight of the catalytically active substrate.