A method for preparing a functional membrane for recovering precious metal ions from oily wastewater is provided. The method includes: obtaining carbon nanotubes functionalized by polyacrylic acid (CNTs-PAA) by grafting acrylic acid onto a surface of carbon nanotubes (CNTs) via graft polymerization; obtaining carbon nanotubes modified by acyl hydrazine functional groups (CNTs-PAH) by reacting adipic dihydrazide (ADH) with carboxyl functional groups of the CNTs-PAA; preparing single-layer MXene nanosheets using Ti.sub.3AlC.sub.2 powder; and preparing a CNTs-PAH/MXene composite membrane by vacuum filtration based on the CNTs-PAH and the single-layer Mxene nanosheets.

Disclosed in the present disclosure is a preparation method for a chelating membrane for purifying wet electronic chemicals, including the following steps: performing hydrophilic treatment on a porous PTFE membrane to obtain a hydrophilic base membrane; sequentially cleaning a chelating resin with a hydrochloric acid solution, a sodium hydroxide solution and deionized water, and then drying; grinding and sieving the cleaned and dried chelating resin to obtain a powder; mixing the powder with polyisobutylene and a polyhexafluoroethylene emulsion, and performing vacuum defoaming to form a membrane coating solution; coating the hydrophilic base membrane with the membrane coating solution to prepare a chelating membrane; and sequentially washing the chelating membrane with a hydrochloric acid solution, a sodium hydroxide solution and pure water until the chelating membrane is neutral, and then drying and storing the chelating membrane.

Disclosed in the present disclosure is a preparation method for a chelating membrane for purifying wet electronic chemicals, including the following steps: performing hydrophilic treatment on a porous PTFE membrane to obtain a hydrophilic base membrane; sequentially cleaning a chelating resin with a hydrochloric acid solution, a sodium hydroxide solution and deionized water, and then drying; grinding and sieving the cleaned and dried chelating resin to obtain a powder; mixing the powder with polyisobutylene and a polyhexafluoroethylene emulsion, and performing vacuum defoaming to form a membrane coating solution; coating the hydrophilic base membrane with the membrane coating solution to prepare a chelating membrane; and sequentially washing the chelating membrane with a hydrochloric acid solution, a sodium hydroxide solution and pure water until the chelating membrane is neutral, and then drying and storing the chelating membrane.

The present disclosure provides a rigid self-supporting MXene separation membrane and a preparation method and use thereof, belonging to the technical field of membranes. In the present disclosure, a MXene material is mixed with an aluminum salt powder to conduct one-step membrane formation by hot-pressing. The pressure forms the powder into a membrane and imparts rigidity, enabling a self-supporting structure; the heating breaks an ionic bond of an inorganic metal salt to reach a molten ionic state, and free metal cations react with active oxygen-containing functional groups on the surface of the MXene to form new chemical bonds (such as an AlO bond); such a chemical bond has higher energy, achieving a desirable anti-swelling effect to improve the membrane stability. The separation membrane further has excellent conductivity and hydrophilicity.

At least one aspect of the present disclosure relates to a two-dimensional mineral membrane including a first phyllosilicate material and a second phyllosilicate material crosslinked with the first phyllosilicate material, where a surface of at least one of the first phyllosilicate material or the second phyllosilicate material includes at least one functional group. Another aspect of the present disclosure relates to a method of producing a two-dimensional mineral membrane. The method includes providing a first phyllosilicate material and a second phyllosilicate material, exfoliating a mixture of the first phyllosilicate material and the second phyllosilicate material into a plurality of flakes, crosslinking the first phyllosilicate material with the second phyllosilicate material, functionalizing a surface of at least one of the first phyllosilicate material or the second phyllosilicate material, and restacking the plurality of flakes to form a membrane.

Disclosed are a solar seawater desalination membrane, a preparation method and a seawater desalination treatment method thereof. The preparation method includes: carrying out hydrophilic treatment on a first carbon cloth to obtain a second carbon cloth with hydrophilicity greater than that of the first carbon cloth; an average pore size of the second carbon cloth is of micron-scale; carrying out a coating treatment on the second carbon cloth based on a preset copper mesh to obtain a first cloth membrane; processing the first cloth membrane to obtain a second cloth membrane; the second cloth membrane includes a graphdiyne structure and the average pore size of the second cloth membrane is of nanometer-scale; processing the second cloth membrane to obtain the solar seawater desalination membrane. The solar seawater desalination membrane contains poly-dopamine particles, and the average pore size of the membrane is smaller than that of the second cloth membrane.

A filtration membrane including a first layer having a triamine-functionalized polysilicate mesoporous material, a second layer including a polysulfone; and a third layer including a polyester terephthalate is described. An orthosilicate group of the triamine-functionalized polysilicate mesoporous material is bonded to a silicon atom of a silicon-containing triamine to form a triamine-functionalized polysilicate backbone, wherein the silicon-containing triamine and one or more tetramines are covalently crosslinked with terephthaloyl chloride to form a polyamide, and wherein the triamine-functionalized polysilicate mesoporous material has a hierarchical structure of MCM-41. The membrane is adapted for use selected from the use group consisting of oil and water separation, water treatment, desalination, and pharmaceutical filtration.

The present disclosure discloses a preparation method of an organosilica/ceramic composite membrane with a gradient pore structure. The preparation method comprises: (1) selecting a porous ceramic material as a membrane support layer; (2) gradually replacing a solvent with water to prepare zirconium colloidal sols with different particle sizes, and successively coating the prepared zirconium colloidal sols onto a ceramic support from large to small so as to form a membrane transition layer with a gradient pore structure; and (3) catalytically synthesizing an organosilica polymeric sol using hydrochloric acid, coating the prepared organosilica sol onto the preheated transition layer through ultrasonic thermal spraying to undergo heat treatment, so as to prepare the organosilica/ceramic composite membrane with the gradient pore structure. According to the present disclosure, the transition layer with the gradient pore structure is prepared by using the zirconium colloidal sols with different particle sizes. An ultrathin defect-free organosilica separation layer is prepared through ultrasonic thermal spraying. As a result, the obtained organosilica/ceramic composite membrane can be applied to the fields of salt-containing dye wastewater treatment and polypeptide bioactive substance separation.