Co-polyimide membranes for separating components of sour natural gas including at least three distinct moieties polymerized together, the moieties including a 2,2′-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride (6FDA) based moiety; a 2,4,6-trimethyl-m-phenylenediamine (DAM) based moiety; and at least one component selected from the group consisting of: a 4,4′-(hexafluoroisopropylidene)dianiline (6FpDA) based moiety; a 9,9-bis(4-aminophenyl) fluorene (CARDO) based moiety; a 2,3,5,6-tetramethyl-1,4-phenylenediamine (durene diamine) based moiety; a 2,2′-bis(trifluoromethyl)benzidine (ABL-21) based moiety; a 3,3′-dihydroxybenzidine based moiety; and a 3,3′-(hexafluoroisopropylidene)dianiline based moiety.

The present invention belongs to the membrane separation area, which provides an MXene material based composite nanofiltration membrane and corresponding method. The mentioned membrane is flat membrane, which has supporting layer and functional separation layer and supporting layer is under the functional separation layer. The functional separation layer is a kind of dense ultra-thin layer, no more than 50 m, prepared with MXene and crosslinking agent. This invention is about a flat composite nanofiltration membrane which has excellent separation performance, thermal resistance and chemical stability because of the novel MXene in the functional separation layer. It can be used in the treatment of the waste water with heavy metal ions, organic solvents or other highly oxidizing solution.

Polymer membranes include a polymer material that is selectively permeable to acidic gases over methane in a gas stream, such as natural gas. The polymer material may be a polymer membrane comprising a fluorinated polytriazole polymer. The fluorinated polytriazole polymer may further comprise a substituted phenyl or a substituted benzenaminyl. The substituted phenyl or substituted benzenaminyl may be substituted with hydrogen, bromo, fluoro, chloro, iodo, hydroxy, methyl, trifluoromethyl, dimethylamino, tert-butyl, or difluoromethoxy groups. The polymer material may have a degree of polymerization of from 100 to 175. The polymer membranes may be incorporated into systems or methods for removing separable gases, such as acidic gases, from gas streams, such as natural gas.

The present disclosure provides a fluorine-based resin porous membrane exhibiting high mechanical strength and low heat shrinkage rate while having a fine pore size, and a method for preparing the same.

Water electrolysis systems that operate at intermediate temperature (i.e., between about 100 C. and about 300 C.) are described. At least some aspects of the present disclosure relate to proton exchange membrane steam electrolysis (PEMSE) systems including a polymer electrolyte comprising at least one phosphorous atom. In at least some examples, the polymer electrolyte my comprise phosphonic acid.

A thermally reflective membrane apparatus comprises a housing structure, and a thermally reflective membrane contained within the housing structure. The thermally reflective membrane comprises a semipermeable structure, and a porous, thermally reflective structure physically contacting the semipermeable structure. The porous, thermally reflective structure comprises discrete thermally reflective particles, and a binder material coupling the discrete thermally reflective particles to one another and the semipermeable structure. A fluid treatment system and method of treating a fluid are also described.

A metal-organic framework material separation membrane and a preparation method for the metal-organic framework material separation membrane are provided. The metal-organic framework material separation membrane has a base membrane and a metal-organic framework material functional layer. The metal-organic framework material functional layer comprises has an inter-embedded polyhedron structure. The preparation metal-organic framework material separation membrane includes the steps of: (1) preparing a solution containing a first organic solvent, an organic ligand, a metal compound, and an auxiliary agent; (2) subjecting a base membrane to a pretreatment, involving introducing, on the surface of the base membrane, metal atoms from the metal compound of step (1); and (3) mixing the pretreated base membrane of step (2) with the solution of step (1) to obtain a first mixture, and then heating the first mixture for reaction, so as to prepare a metal-organic framework material separation membrane.

Embodiments of the present disclosure feature an intrinsically microporous ladder-type Trger's base polymer including a repeat unit based on a combination of W-shaped CANAL-type and V-shaped Trger's base building blocks, methods of making the intrinsically microporous ladder-type Trger's base polymer, and methods of using the intrinsically microporous ladder-type Trger's base polymer to separate a chemical species from a fluid composition including a mixture of chemical species. Embodiments of the present disclosure further include ladder-type diamine monomers for reacting to form a Trger's base in situ, and methods of making the ladder-type diamine monomers using catalytic arene-norbornene annulation.

A method for producing a gas separation membrane, including the following steps: step (a): treating the surfaces of silica nanoparticles dispersed in a first solvent with a reactive functional group-containing compound, while nanoparticles are being dispersed in the solvent, to thereby prepare a first solvent dispersion of reactive functional group-modified silica nanoparticles; step (b): replacing the first solvent dispersion's dispersion medium of reactive functional group-modified silica nanoparticles prepared in step (a) with a second solvent without drying of dispersion medium, and then reacting functional group-modified silica nanoparticles with dendrimer-forming monomer or hyperbranched polymer-forming monomer in the second solvent's presence so that dendrimer or hyperbranched polymer is added to reactive functional group, to thereby prepare dendrimer- or hyperbranched polymer-bound silica nanoparticles; step (c): mixing dendrimer- or hyperbranched polymer-bound silica nanoparticles prepared in step (b) with a matrix resin; and step (d): applying mixture prepared in step (c) to a substrate, and then removing the solvent.

A polyolefin composite porous membrane includes a first layer and a second layer. The first layer contains a polypropylene (A), a first high-density polyethylene (B) having a melting point of 130 C. or higher, and a second high-density polyethylene (C) having a melting point of 120 C. or higher and lower than 130 C. The second layer contains a polyethylene (D). The first layer and the second layer are integrally laminated with each other.