An electrochemical gas conversion device is provided, that includes a flexible membrane formed in a sack-shape, where the membrane includes a gas permeable and liquid-impermeable membrane, where at least a portion of the flexible membrane is surrounded by a liquid electrolyte held by a housing, where the flexible membrane includes a gas interior, an electrically conductive catalyst coating on an exterior surface of the flexible membrane, where the flexible membrane and the electrically conductive catalyst coating are configured as a anode or a cathode, and an inlet/outlet tube configured to flow the gas to the interior, from the interior, or to and from the interior of the flexible membrane.

A device for decomplexation and enhanced removal of copper based on self-induced Fenton-like reaction constructed by electrochemistry coupled with membrane separation is disclosed. The device includes a reactor, two electrocatalytic anodes capable of generating hydroxyl radicals, an electrocatalytic cathode membrane assembly, a direct current power supply, an aeration system, an inlet pipe and an outlet pipe. The device of the present invention has a simple construction. Using this device to treat industrial wastewater containing copper complexes under specific conditions allows the decomplexation and the removal of the industrial wastewater containing the copper complexes to be simultaneously realized at a low consumption and a high efficiency. The coupling of electrochemistry with membrane separation can be achieved to protect the cathode from being contaminated by pollutants in the sewage and prolong the service life of the electrode.

Described herein is an ion pump system implementing an electronic ratchet mechanism produced by modulating a spatially varying electric potential distribution that can result in a net ionic current and voltage. The ion pumping membrane system includes an ion-permeable layer that can also be integrated with ion-selective membranes. The electric potential distribution within the ion-permeable layer is modulated through external stimuli. When immersed in solution, ions within the ion-permeable layer experience a time varying, spatially asymmetric electric field distribution resulting in ratchet-driven direct ion pumping, which can be used in applications such as desalination.

The present technology provides micro fabricated filtration devices, methods of making such devices, and uses for microfabricated filtration devices. The devices may allow diffusion to occur between two fluids with improved transport resistance characteristics as compared to conventional filtration devices. The devices may include a compound structure that includes a porous membrane overlying a support structure. The support structure may define a cavity and a plurality of recesses formed in a way that can allow modified convective flow of a first fluid to provide improved diffusive transport between the first fluid and a second fluid through the membrane.

A layered electroosmotic structure for transporting fluid by electroosmotic transport includes a porous layer; a first electrode located on a first side of the porous layer; and a second electrode located on a second side of the porous layer. The first electrode may include a first surface that faces the porous layer, wherein the first surface of the first electrode includes a region that is electrically insulating. The first electrode and/or the second electrode may not be in electrical contact with an edge region of the porous layer. Methods of manufacturing the layered electroosmotic structures are also provided.

Chemically inert, mechanically tough, cationic metallo-polyelectrolytes designed as durable anion-exchange membranes (AEMs) via ring-opening metathesis polymerization (ROMP) of cobaltocenium-containing cyclooctene with triazole as the only linker group, followed by backbone hydrogenation to provide a new class of AEMs with a polyethylene-like framework and alkaline-stable cobaltocenium cation for ion transport, which exhibit excellent thermal, chemical and mechanical stability, as well as high ion conductivity.

A molecular sieve that has high selectivity and enables high-speed molecular permeation is provided. The molecular sieve has a nanowindow formed lacking a portion of carbon atoms in graphene, and one or more heteroatoms substituting for one or more carbon atoms that constitute a rim of this nanowindow, in which an electrostatic field is induced within the nanowindow by the heteroatoms, the rim of the nanowindow is relaxed in cooperation with a permeating molecule having a van der Waals' radius larger than the nanowindow, and the molecular sieve becomes permeable to the permeating molecule.

In a first aspect, the present disclosure relates to a method for forming a diamond membrane, comprising: providing a substrate having an amorphous dielectric layer thereon, the amorphous dielectric layer comprising an exposed surface, the exposed surface having an isoelectric point of less than 7, preferably at most 6; seeding diamond nanoparticles onto the exposed surface; growing a diamond layer from the seeded diamond nanoparticles; and removing a portion of the substrate from underneath the diamond layer, the removed portion extending at least up to the amorphous dielectric layer, thereby forming the diamond membrane over the removed portion.

Chemically inert, mechanically tough, cationic metallo-polyelectrolytes designed as durable anion-exchange membranes (AEMs) via ring-opening metathesis polymerization (ROMP) of cobaltocenium-containing cyclooctene with triazole as the only linker group, followed by backbone hydrogenation to provide a new class of AEMs with a polyethylene-like framework and alkaline-stable cobaltocenium cation for ion transport, which exhibit excellent thermal, chemical and mechanical stability, as well as high ion conductivity.

The present disclosure is directed to the preparation of highly metallic, hydrophilic, polymer-free carbon nanotube (CNT) thin sheets with high tensile strength. The densified CNT sheet has reduced pore sizes, increased tensile strength, and improved electrical conductivity. The disclosed CNT materials can be used as filtration membranes with little or no propensity toward surface fouling. Such densified CNT sheets are also useful as superior electromagnetic interference (EMI) shielding materials.