Provided is a method of efficiently treating a fluid to be treated containing a compound that destroys a zeolite membrane to prevent the fluid from destroying the zeolite membrane. A fluid to be treated 10 formed of a liquid mixture or a gas mixture and containing a compound that destroys a zeolite membrane 2 is brought into contact with particles (3, 5) made of the same type of zeolites as the zeolite membrane 2 and filling a pretreatment device 4 installed upstream of a membrane module 1 including the zeolite membrane 2 or a portion upstream of the zeolite membrane 2 in the membrane module 1 to destroy the zeolite forming the particles (3, 5) and the fluid to be treated 10 is made to contain a component generated by the destruction.

A novel membrane is provided in which the permeate flow rate is not prone to decrease even when the membrane is used to process seawater with high salt concentration and high heavy metal ion concentration. This composite semipermeable membrane comprises a porous support layer, a separation function layer arranged on the porous support layer, and a coating layer coating the separation function layer, wherein the separation function layer contains a crosslinked polymer amide which is a condensate of polyfunctional aromatic amine and polyfunctional aromatic acid chloride, and the coating layer contains an aliphatic polymer including a polyether moiety and a carbonic acid polymer moiety.

Provided is a method of efficiently treating a fluid to be treated containing a compound that destroys a zeolite membrane to prevent the fluid from destroying the zeolite membrane. A fluid to be treated 10 formed of a liquid mixture or a gas mixture and containing a compound that destroys a zeolite membrane 2 is brought into contact with particles (3, 5) made of the same type of zeolites as the zeolite membrane 2 and filling a pretreatment device 4 installed upstream of a membrane module 1 including the zeolite membrane 2 or a portion upstream of the zeolite membrane 2 in the membrane module 1 to destroy the zeolite forming the particles (3, 5) and the fluid to be treated 10 is made to contain a component generated by the destruction.

A system and method to increase surface friction across a hydrophobic, anti-fouling, and oleophobic coated substrate. The substrate has a hydrophobic surface defined by a surface friction. The system works to increases the surface friction, or roughness, across the hydrophobic surface. The increase in surface friction is accomplished by generating power through an ion source to create an ion cloud. The ion cloud is generated in proximity to the substrate. The ions interact with the hydrophobic surface to create a roughing effect thereon. A gas carrier device introduces an inert carrier gas through the ion cloud to increase density of the ions, which in turn increases surface friction. The system is variable, selectively increasing and decreasing surface friction by: varying the duration that the hydrophobic surface is exposed to the ion cloud; varying power applied to ion source; and varying distance between the ion cloud and the hydrophobic surface.

A method is disclosed for forming a microporous membrane that incorporates an additive having low water solubility at the membrane's active surface from a precipitation fluid. The incorporated additive at the membrane's active surface can improve one or more of the membrane's hydrophilicity, wettability, anti-fouling behavior, blood compatibility, and stability over long periods of use or repetitive use. The microporous membrane with this modified active surface can be a hollow fiber, flat sheet, or other self-supporting shape. The microporous membranes can be used for membrane filtering or a solute and/or solvent exchange process, which involve contacting aqueous-based fluid or blood with the microporous membrane, such processes for dialysis, blood oxygenation, or blood separation filtering, or other processes.

In at least one embodiment, a microporous membrane having a moderate to high water vapor permeability and high liquid water penetration resistance is disclosed. The microporous membrane may be used in building applications, including as or as part of a building wrap, a rain screen, a roofing underlayment, a flashing, a sound proofing material, or an insulation material. The microporous membrane may include at least one thermoplastic polymer, at least one filler, and at least one processing oil. The microporous membrane may be flat or may have ribs. The microporous membrane may include at least one scrim component. A method for forming the microporous membrane is also disclosed.

The invention is an improved method of making an improved carbon molecular sieve (CMS) membrane in which a precursor polymer (e.g., polyimide) is pyrolyzed at a pyrolysis temperature to form a CMS membrane that is cooled to ambient temperature (about 40° C. or 30° C. to about 20° C.). The CMS membrane is then reheated to a reheating temperature of at least 250° C. to 400° C. to form the improved CMS membrane. The CMS have a novel microstructure as determined by Raman spectroscopy. The improved CMS membranes have shown an improved combination of selectivity and permeance as well as stability for separating light hydrocarbon gas molecules such as C.sub.1 to C.sub.6 hydrocarbon gases (e.g., methane, ethane, propane, ethylene, propylene, butane, butylene).

Co-polyimide membranes for separating components of sour natural gas including at least three distinct moieties polymerized together, the moieties including a 2,2′-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride (6FDA) based moiety; a 4,4′-(hexafluoroisopropylidene)dianiline (6FpDA) based moiety; and at least one component selected from the group consisting of: a 9,9-bis(4-aminophenyl) fluorene (CARDO) based moiety; a 2,3,5,6-tetramethyl-1,4-phenylenediamine (durene diamine) based moiety; a 2,2′-bis(trifluoromethyl)benzidine (ABL-21) based moiety; a 3,3′-dihydroxybenzidine based moiety; and a 3,3′-(hexafluoroisopropylidene)dianiline based moiety.

Co-polyimide membranes for separating components of sour natural gas including at least three distinct moieties polymerized together, the moieties including a 2,2′-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride (6FDA) based moiety; a 2,4,6-trimethyl-m-phenylenediamine (DAM) based moiety; and at least one component selected from the group consisting of: a 4,4′-(hexafluoroisopropylidene)dianiline (6FpDA) based moiety; a 9,9-bis(4-aminophenyl) fluorene (CARDO) based moiety; a 2,3,5,6-tetramethyl-1,4-phenylenediamine (durene diamine) based moiety; a 2,2′-bis(trifluoromethyl)benzidine (ABL-21) based moiety; a 3,3′-dihydroxybenzidine based moiety; and a 3,3′-(hexafluoroisopropylidene)dianiline based moiety.

A porous membrane has a thickness of 150 m or greater. The pore diameters of a first surface are smaller than the pore diameters of a second surface. The average value of the pore diameters of the first surface is 60 nm or less, and the coefficient of variation of the pore diameters is 10% or greater and 50% or less.