A method for preparing a high-selectivity lithium-magnesium separation membrane includes: (1) preparing an aqueous phase mixture containing aqueous phase monomer, crown ethers or aza-macrocycles, acid acceptor, surfactant and water; (2) preparing an organic phase mixture containing organic phase monomer, and organic solvent that is incompatible with water; (3) contacting the supporting membrane with the aqueous phase mixture to obtain an aqueous phase monomer-adsorbed supporting membrane; (4) contacting the aqueous phase monomer-adsorbed supporting membrane with an organic phase mixture for an interfacial polymerization reaction; and (5) placing a nascent membrane obtained into a drying oven and heat-treating the membrane to obtain a lithium-magnesium separation membrane. The present method is simple in preparation process, mild in preparation conditions, easy to scale up, and easy to realize industrial production. The prepared high-selectivity lithium-magnesium separation membrane is large in permeation flux, high in lithium-magnesium selectivity and good in long-term operation stability.

The present invention relates to a porous membrane including a polymer including a polyvinylidene fluoride-based resin as a main component, and a branched polyvinylidene fluoride-based resin as the polyvinylidene fluoride-based resin, in which the polymer has a value of a of 0.32 to 0.41 and a value of b of 0.18 to 0.42, each of which is determined by approximation according to the formula 1 below from a radius of gyration <S.sup.2>.sup.1/2 and an absolute molecular weight M.sub.w of the polymer which are measured by GPC-MALS (gel permeation chromatograph equipped with a multi-angle light scattering detector). <S.sup.2>.sup.1/2=bM.sub.w.sup.a (Formula 1)

This disclosure relates to functionalized polyhedral oligomeric silsesquioxanes (POSS) and polymeric membranes containing the functionalized POSS. This disclosure also relates to methods of using the membranes for natural gas liquid recovery, such as removal and recovery of C.sub.3+ hydrocarbons from natural gas.

A porous membrane is made from a poly(phenylene ether) copolymer containing 10 to 40 mole percent repeat units derived from 2-methyl-6-phenylphenol and 60 to 90 mole percent repeat units derived from 2,6-dimethylphenol; and a block copolymer containing backbone or pendant blocks of poly(C.sub.2-4 alkylene oxide). The porous membrane is made by dissolving the poly(phenylene ether) copolymer in a water-miscible polar aprotic solvent to form a membrane-forming composition; and phase-inverting the membrane forming-composition in a first non-solvent composition to form the porous membrane. A method of making a hollow fiber by coextrusion through a spinneret having an annulus and a bore, includes coextruding the membrane-forming composition through the annulus, and a first non-solvent composition through the bore, into a second non-solvent composition to form the hollow fiber.

A separation module that includes a porous membrane, where the porous membrane includes a poly(phenylene ether) copolymer containing 10 to 40 mole percent repeat units derived from 2-methyl-6-phenylphenol and 60 to 90 mole percent repeat units derived from 2,6-dimethylphenol; and a block copolymer containing backbone or pendant blocks of poly(C.sub.2-4 alkylene oxide). The separation module can be used in devices for wastewater treatment, water purification, desalination, separating water-insoluble oil from oil-containing wastewater, membrane distillation, sugar purification, protein concentration, enzyme recovery, dialysis, liver dialysis, or blood oxygenation.

Provided is a method for preparing a gas separation membrane, the method including forming a porous layer by coating a hydrophilic polymer solution on a porous substrate; and forming an active layer by coating a composition for forming an active layer including a polymer of Chemical Formula 1 on the porous layer, ##STR00001## wherein in Chemical Formula 1, n is the number of a repeating unit, and is an integer of 500 to 3,000, and R1 to R5 are the same as or different from each other, and each independently is hydrogen, an alkyl group, or —(C═O)R6, and R6 is an alkyl group, wherein the polymer of Chemical Formula 1 is included in an amount from 1% by weight to 5% by weight based on the composition for forming an active layer, and a gas separation membrane prepared using the same.

A method of preparing a membrane comprising the steps of: a) mixing together a membrane-forming polymer, a water-soluble polyetheramine, and a solvent, said mixture containing no component which will react chemically with the polyetheramine; and b) casting said mixture to form the polymer into a solid membrane.

Provided is a composition for forming a separation membrane active layer, the composition comprising a compound of the following Chemical Formula 1 and a compound of the following Chemical Formula 2, wherein a percentage (a/b) of a weight (a) of the compound of Chemical Formula 1 to a weight (b) of the compound of Chemical Formula 2 is 30% to 60%, and a pH thereof is 11 to 12.7:

##STR00001## wherein in Chemical Formulae 1 and 2: R1 to R16 are each independently —CRR′— or —NR″—. at least two of R1 to R10 are —NR″—; at least two of R11 to R16 are —NR″—; and R, R′, and R″ are each independently hydrogen or a substituted or unsubstituted alkyl group; a method for producing a separation membrane; a separation membrane; and a water treatment module.

Membranes, methods of making the membranes, and methods of using the membranes are described herein. The membrane can comprise a support layer; and a selective polymer layer disposed on the support layer. The selective polymer layer can comprise a selective polymer matrix (e.g., hydrophilic polymer, an amine-containing polymer, a low molecular weight amino compound, a CO.sub.2-philic ether, or a combination thereof), and graphene oxide dispersed within the selective polymer matrix. The membranes can be used to separate carbon dioxide for hydrogen. Also provided are methods of purifying syngas using the membranes described herein.

The invention describes a method for obtaining purified recombinant Adeno-Associated Virus particles (rAAV), comprising performing a depth filtration of a starting material previously obtained from cells producing rAAV particles comprising a cell lysate and/or a culture supernatant, followed by a first step of anion-exchange chromatography, a second step of anion-exchange chromatography and a final step of tangential flow filtration, whereby purified recombinant Adeno-Associated Virus particles (rAAV) are provided.