A universal, scalable, solvent-free, one-step method for thermal annealing a stainless steel membrane to create a superhydrophilic surface. The superhydrophilic membrane itself, and methods for using it to separate oil and water in an oil and water mixture or for photocatalytic degradation of methylene blue and other organic contaminants.

A filtering device for obtaining a chemical liquid by purifying a liquid to be purified has an inlet portion, an outlet portion, a filter A, at least one filter B different from the filter A, and a flow path which includes the filter A and the filter B arranged in series between the inlet portion and the outlet portion and extends from the inlet portion to the outlet portion, in which the filter A has a porous base material made of polyfluorocarbon and a coating layer which is disposed to cover the porous base material and contains a first resin having a hydrophilic group.

Provided herein are methods for making a freeze-cast material having a internal structure, the methods comprising steps of: determining the internal structure of the material, the internal structure having a plurality of pores, wherein: each of the plurality of pores has directionality; and the step of determining comprises: selecting a temperature gradient and a freezing front velocity to obtain the determined internal structure based on the selected temperature gradient and the selected freezing front velocity; directionally freezing a liquid formulation to form a frozen solid, the step of directionally freezing comprising: controlling the temperature gradient and the freezing front velocity to match the selected temperature gradient and the selected freezing front velocity during directionally freezing; wherein the liquid formulation comprises at least one solvent and at least one dispersed species; and subliming the at least one solvent out of the frozen solid to form the material.

The invention relates to a method for manufacturing a dialysis filter comprising fluorine-containing hollow fiber membranes, the fluorine-containing hollow fiber membranes being made by a method comprising at least steps (A) to (C): (A) preparing a spinning solution comprising an aprotic solvent, a hydrophobic base polymer, a hydrophilic polymer, and a fluorine-comprising surface modifying macromolecule in a concentration less than 1.12% w/w; (B) extruding said spinning solution from an outer annular orifice through a tube-in-orifice spinneret into an aqueous solution, and (C) isolating the formed hollow fiber membrane,
characterized in that the manufacturing of the dialysis filter comprises a steam sterilization procedure. The invention is further related to dialysis filter comprising a fluorine-containing hollow fiber membrane comprising a hydrophobic base polymer, a hydrophilic polymer and a fluorine-comprising surface modifying macromolecule in a concentration less than 3.6% w/w, based on the total weight of the fluorine-containing hollow fiber membrane.

A surface-modified filter membrane for filtering blood, in particular for separating blood plasma and blood serum, and a method for the production thereof, a filter provided therewith and the use thereof.

A degasification system includes a degasification unit in which a plurality of degasification modules degasifying a liquid are connected, wherein the degasification unit has a connection supply pipe which connects the liquid supply paths of the plurality of degasification modules in series and in which openings through which the liquid passes are formed at positions corresponding to the plurality of degasification modules such that the liquid is supplied to the hollow fiber membrane bundles of the plurality of degasification modules in parallel, and wherein the degasification unit is configured such that a pressure loss of the liquid from a supply port of the connection supply pipe through which the liquid is supplied to the discharge ports of a downstream side degasification module is larger than a pressure loss of the liquid from the supply port to the discharge ports of an upstream side degasification module.

Water-filtration compositions, membranes, devices, and manufacturing processes including graphene oxide with hydrophilic functional groups. Disclosed are a composition comprising graphene oxide with an average particle diameter of no more than about 1 μm and has an oxygen atomic percentage of at least about 30%, a membrane comprising the composition, a water-permeable device comprising the membrane, a method of making the membrane using the composition, and several methods of generating the composition.

[Problem to be Solved]

Provided is a polyvinylidene fluoride resin-made porous membrane having excellent hydrophilicity, permeability, and fouling resistance and having suppressed elution of vinyl ether copolymer by using a small amount of vinyl ether copolymer.

[Means to Solve the Problem]

The porous membrane according to the invention comprises a polyvinylidene fluoride resin as a matrix material and a vinyl ether copolymer, wherein the vinyl ether copolymer is a copolymer of an oxyethylene group-containing vinyl ether monomer and a hydrocarbon group-containing vinyl ether monomer.

A porous membrane includes a modacrylic copolymer. The modacrylic copolymer includes, with respect to 100 parts by mass of all structural units constituting the modacrylic copolymer, 15 to 85 parts by mass of a structural unit derived from acrylonitrile, 15 to 85 parts by mass of a structural unit derived from at least one halogen-containing monomer selected from the group consisting of vinyl halide and vinylidene halide, and 0 to 10 parts by mass of a structural unit derived from a vinyl monomer having an ionic substituent. The porous membrane can be produced by preparing a modacrylic copolymer solution by dissolving the modacrylic copolymer in a solvent, and bringing the modacrylic copolymer solution into contact with a non-solvent for the modacrylic copolymer such that the modacrylic copolymer solution is solidified.

A nanofiber membrane includes a polymer nanofiber; and an amphiphilic triblock copolymer bonded to the surface of the polymer nanofiber, the amphiphilic triblock copolymer includes a hydrophobic portion; hydrophilic portions positioned at both ends of the hydrophobic portion; and a low surface energy portion positioned at one end of each of the hydrophilic portions positioned at both ends of the hydrophobic portion, and the hydrophobic portion of the amphiphilic triblock copolymer is bonded to the surface of the polymer nanofiber and the hydrophilic portion and the low surface energy portion are exposed to the outside of the surface of the polymer nanofiber. The membrane simultaneously exhibits hydrophilicity, underwater oleophobicity, and low oil adhesion force, thus has surface segregation properties, and as a result, has an excellent oil permeate flux, exhibits antifouling properties, and can excellently separate oil in water.