Polymer-based membranes and methods for fabricating membranes are described. The methods include forming a casting solution featuring a polyvinylidene fluoride (PVDF)-based solvent and a polyvinylpyrrolidone (PVP)-based modifying agent, dispersing the casting solution to form a first element, generating a plurality of active sites on a surface of the first element, and forming a polymer-based membrane by exposing the surface of the first element to a fluorosilane composition to form a fluorosilane layer on the surface, where the fluorosilane composition includes a silane compound having at least one alkyl substituent that includes between 9 and 21 fluorine atoms.

In this disclosure, a process of recycling acid, base and the salt reagents required in the Li recovery process is introduced. A membrane electrolysis cell which incorporates an oxygen depolarized cathode is implemented to generate the required chemicals onsite. The system can utilize a portion of the salar brine or other lithium-containing brine or solid waste to generate hydrochloric or sulfuric acid, sodium hydroxide and carbonate salts. Simultaneous generation of acid and base allows for taking advantage of both chemicals during the conventional Li recovery from brines and mineral rocks. The desalinated water can also be used for the washing steps on the recovery process or returned into the evaporation ponds. The method also can be used for the direct conversion of lithium salts to the high value LiOH product. The method does not produce any solid effluent which makes it easy-to-adopt for use in existing industrial Li recovery plants.

A process for the efficient transfer of molecules between phases employing mesoporous poly (aryl ether ketone) hollow fiber membranes is provided. The method addresses the controlled transfer of reactants into and removal of reaction products from a reaction media and the removal and separation of target molecules from process streams by membrane-assisted liquid-liquid extraction. A number of possible modes of liquid-liquid extraction are possible according to the invention by utilizing porous poly (aryl ether ketone) hollow fiber membranes of Janus-like structure that exhibit a combination of hydrophilic and hydrophobic surface characteristics. The method of the present invention can address the continuous manufacture of chemicals in membrane reactors and is useful for a broad range of separation applications, including separation and recovery of active pharmaceutical ingredients.

Sometimes, a problem is obvious, everyone sees it, but nothing happens until someone decides to do something useful about it. Methods are herein provided for recovering heavy hydrocarbons from plastic materials and/or geo-formation. In one solution set, PVC waste materials are emulsified by an amine solvent in an aqueous phase, thereby extracting heavier hydrocarbons from the primary structure of PVC into the amine aqueous phase; followed by de-emulsifying the extracted heavier hydrocarbons by separating and recovering the amine solvent, and then separating the de-emulsified heavier hydrocarbons from the aqueous phase by a hydrophobic membrane.

The invention relates to the providing of hydrophobic and hydrophilic polymer-based hollow fiber membranes containing a water-insoluble antioxidant; in particular, the invention relates to the providing of hollow fiber membranes for the extracorporeal treatment of blood, wherein the hollow fiber membranes have improved biocompatibility relative to treatment blood, in particular improved complement activation and lower platelet loss vis-à-vis treatment blood. At the same time, the elution of hydrophilic polymers from the lumen of the hollow fiber membrane is reduced.

The present invention relates, in general terms, to a composite membrane for use in filtration. The present invention also relates to a method of fabricating the composite membrane, and a method of filtrating using the composite membrane as disclosed herein. The method of fabricating a composite membrane comprising contacting a perfluorinated polymer solution with a surface of a polymer layer and drying the perfluorinated polymer solution at a relative humidity of less than 20% to form a perfluorinated polymer layer physisorbed on the surface of the polymer layer.

Systems and methods using: a membrane unit to treat fluids recovered from an oil and gas well are provided. The membrane unit may include a membrane having a porous substrate at. least partially coated with graphene oxide, making the membrane hydrophilic. The membrane separates water from other components within a fluid stream. The membrane unit may include an inlet to receive a fluid stream into the membrane unit. The fluid stream may be pretreated prior to reaching the membrane unit The membrane unit may also include a first outlet in fluid communication with one side of the membrane and a second outlet in fluid communication with the opposite side of the membrane.

Provided is a waterproof gas-permeable membrane (1) having higher levels of both gas permeability and waterproofness than conventional ones. The waterproof gas-permeable membrane (1) includes: a non-porous resin film (2) having through holes (21a to 21g) formed to extend through the thickness of the resin film (2); and a liquid-repellent layer (3) formed on a principal surface of the resin film (2) and having openings (31) positioned in register with the through holes (21a to 21g). The through holes (21a to 21g) extend straight and have a diameter of 15 μm or less. The through holes (21a to 21g) are distributed at a hole density of 1×10.sup.3 holes/cm.sup.2 or more and 1×10.sup.9 holes/cm.sup.2 or less in the resin film (2). The through holes (21a to 21g) extend in oblique directions with respect to a direction perpendicular to the principal surface of the resin film (2). The through holes (21a to 21g) that extend in different oblique directions are present together.

The present disclosure provides a laminate having low air permeability and excellent moisture permeability, a partition member for total heat exchange element composed of the laminate, a total heat exchange element provided with a plurality of the partition members for total heat exchange element, and a ventilation device provided with the total heat exchange element. The laminate of the present disclosure is provided with a porous substrate and a moisture-permeable membrane disposed on one side of the porous substrate, the moisture-permeable membrane being provided with a porous substrate and a moisture-permeable membrane disposed on at least one side of the porous substrate, and the moisture-permeable membrane being formed of a thermoplastic copolymer having a side chain containing a hydrophilic group which is a functional group.

In this disclosure, a process of recycling acid, base and the salt reagents required in the Li recovery process is introduced. A membrane electrolysis cell which incorporates an oxygen depolarized cathode is implemented to generate the required chemicals onsite. The system can utilize a portion of the salar brine or other lithium-containing brine or solid waste to generate hydrochloric or sulfuric acid, sodium hydroxide and carbonate salts. Simultaneous generation of acid and base allows for taking advantage of both chemicals during the conventional Li recovery from brines and mineral rocks. The desalinated water can also be used for the washing steps on the recovery process or returned into the evaporation ponds. The method also can be used for the direct conversion of lithium salts to the high value LiOH product. The method does not produce any solid effluent which makes it easy-to-adopt for use in existing industrial Li recovery plants.