Metal organic framework membranes can be used in gas separation applications.

A polymer membrane, methods of gas separation utilizing the polymer membrane, and methods of producing the polymer membrane are disclosed herein. The polymer membrane includes a crosslinked polyethylene glycol network polymer according to formula (I):

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A microporous polymeric composition including a matrix polymer having a fractional free volume of at least 0.1 and dispersed particles having a hypercrosslinked polymer.

An asymmetric polyvinylidene chloride copolymer membrane is made by a method using a dope solution comprised of a polyvinylidene chloride copolymer and a solvent that solubilizes the polyvinylidene chloride copolymer that is shaped to form an initial shaped membrane. The initial shaped membrane is then quenched in a liquid comprised of a solvent that is miscible with the solvent that solubilizes the polyvinylidene chloride copolymer but is immiscible with the polyvinylidene chloride copolymer to form a wet asymmetric polyvinylidene chloride copolymer membrane. The solvents are removed from the wet membrane to form the asymmetric polyvinylidene chloride (PVDC) copolymer membrane. The membrane then may be further heated to form a carbon asymmetric membrane in which the porous support structure and separation layer of the PVDC membrane is maintained. The asymmetric carbon membrane may be useful to separate gases such as olefins from their corresponding paraffins, hydrogen from syngas or cracked gas, natural gas or refinery gas, oxygen/nitrogen, or carbon dioxide and methane.

Halogen-free, microporous polyolefin membranes are disclosed herein. The halogen-free, microporous polyolefin membranes can be manufactured using an environmentally friendly manufacturing process that includes extrusion of polymer-plasticizer mixtures followed by sheet formation and extraction of the plasticizer with a halogen-free solvent. The halogen-free solvent has a flashpoint greater than about 23 C. and an initial boiling point at least about 50 C. lower than the flashpoint of the plasticizer. The process can further be a closed loop process in which the halogen-free solvent can be reused.

There is provided a zeolite membrane which is an MFI-type zeolite membrane formed on an inorganic oxide porous substrate, in which, in a diffraction pattern obtained by X-ray diffraction measurement using a CuK ray as an X-ray source, when an intensity of a diffraction peak appearing at diffraction angles of 7.3 to 8.4 at which a crystal lattice plane belongs to 011 and/or 101 planes is used as a reference, an intensity of a diffraction peak appearing at diffraction angles of 8.4 to 9.0 at which a crystal lattice plane belongs to 200 and/or 020 planes is preferably 0.3 or more.

There is provided a method of producing a separation membrane in which a zeolite membrane is formed on an inorganic oxide porous substrate. The substrate has amorphous SiO.sub.2 as a main component of a zeolite formation portion of the substrate, the method includes: a first step of forming a zeolite seed crystal and an alkaline component including a structure directing agent on a surface of the substrate; and a second step of treating a formed product obtained in the first step under a heated steam atmosphere, and the zeolite membrane is formed on the surface of the substrate.

The present invention belongs to the membrane separation area, which provides an MXene material based composite nanofiltration membrane and corresponding method. The mentioned membrane is flat membrane, which has supporting layer and functional separation layer and supporting layer is under the functional separation layer. The functional separation layer is a kind of dense ultra-thin layer, no more than 50 ?m, prepared with MXene and crosslinking agent. This invention is about a flat composite nanofiltration membrane which has excellent separation performance, thermal resistance and chemical stability because of the novel MXene in the functional separation layer. It can be used in the treatment of the waste water with heavy metal ions, organic solvents or other highly oxidizing solution.

A heat exchanger for a blood circulation circuit includes a hollow fiber membrane layer having a plurality of laminated hollow fiber membranes 31. Each of the hollow fiber membranes 31 has a barrier layer 5 having a hydrogen peroxide barrier property, and the barrier layer 5 has an oxygen permeability coefficient of 6 cc.Math.cm/m.sup.2.Math.24 h/atm or less at 25 C.

The present invention relates to a composite porous hollow-fiber membrane including a first layer and a second layer which each include a fluororesin-based polymer, in which at least a part of molecular chains of the fluororesin-based polymer is oriented in a longitudinal direction of the composite porous hollow-fiber membrane, the molecular chains of the fluororesin-based polymer have a degree of orientation it in the longitudinal direction of the composite porous hollow-fiber membrane of 0.4 or higher but less than 1.0, the degree of orientation it being calculated with the specific formula.