Patent classifications
B01J2/20
Weak ion exchange particulate medium prepared from phenol-containing organic matter for anions contained in aqueous solutions
A process for the preparation of a granulated or pelletized weak anion exchange medium from a phenol-containing organic material like peat, followed by low-temperature torrefaction of the granules to produce a high degree of physical stability of the granules at high-pH conditions, followed by chemical pretreatment of the stable granule via a hydrolysis reaction, and optionally surface treatment with acids, followed by the main chemical treatment of the hydrolyzed granule via separate aldehyde and amine reagents, or alternatively via an adduct reagent like hexamethylenetetramine is provided by this invention. The weak anion exchange medium of this invention can be used in a variety of aqueous solution treatment processes, such as wastewater treatment for removing mineral acids like H.sub.2SO.sub.4, HNO.sub.3, HCl, HBr, HF, H.sub.3PO.sub.4, HI, or formic acid from the wastewater. The resulting anion exchanger medium is particularly useful for treating wastewaters in a low-pH environment.
Weak ion exchange particulate medium prepared from phenol-containing organic matter for anions contained in aqueous solutions
A process for the preparation of a granulated or pelletized weak anion exchange medium from a phenol-containing organic material like peat, followed by low-temperature torrefaction of the granules to produce a high degree of physical stability of the granules at high-pH conditions, followed by chemical pretreatment of the stable granule via a hydrolysis reaction, and optionally surface treatment with acids, followed by the main chemical treatment of the hydrolyzed granule via separate aldehyde and amine reagents, or alternatively via an adduct reagent like hexamethylenetetramine is provided by this invention. The weak anion exchange medium of this invention can be used in a variety of aqueous solution treatment processes, such as wastewater treatment for removing mineral acids like H.sub.2SO.sub.4, HNO.sub.3, HCl, HBr, HF, H.sub.3PO.sub.4, HI, or formic acid from the wastewater. The resulting anion exchanger medium is particularly useful for treating wastewaters in a low-pH environment.
PROCESS AND APPARATUS FOR DIRECT CRYSTALLIZATION OF POLYCONDESATES
A process for continuous production of partly crystalline polycondensate pellet material which comprises the step of crystallizing the pellet material in a second treatment space (6a) under fixed bed conditions by supply of energy from the exterior by means of a process gas, wherein the process gas has a temperature (T.sub.Gas), which is higher than the sum of the pellet temperature (T.sub.GR) and the temperature increase (T.sub.KR) which occurs due to heat of crystallization released hi the second treatment space (6a), i.e., (T.sub.Gas>(T.sub.GR+T.sub.KR)). The pellets at the exit from the second treatment space (6a) have an average temperature (T.sub.PH), which is 10 to 90 C. higher than the sum of the temperature of the pellets (T.sub.GR) and the temperature increase (T.sub.KR) which occurs due to heat of crystallization released in the second treatment space (6a), i.e., (T.sub.GR+T.sub.KR+90 C.)T.sub.PH(T.sub.GR+T.sub.KR+10).
PROCESS AND APPARATUS FOR DIRECT CRYSTALLIZATION OF POLYCONDESATES
A process for continuous production of partly crystalline polycondensate pellet material which comprises the step of crystallizing the pellet material in a second treatment space (6a) under fixed bed conditions by supply of energy from the exterior by means of a process gas, wherein the process gas has a temperature (T.sub.Gas), which is higher than the sum of the pellet temperature (T.sub.GR) and the temperature increase (T.sub.KR) which occurs due to heat of crystallization released hi the second treatment space (6a), i.e., (T.sub.Gas>(T.sub.GR+T.sub.KR)). The pellets at the exit from the second treatment space (6a) have an average temperature (T.sub.PH), which is 10 to 90 C. higher than the sum of the temperature of the pellets (T.sub.GR) and the temperature increase (T.sub.KR) which occurs due to heat of crystallization released in the second treatment space (6a), i.e., (T.sub.GR+T.sub.KR+90 C.)T.sub.PH(T.sub.GR+T.sub.KR+10).
Shaped or sized encapsulated reactant and method of making
Technologies are described for a method of making an encapsulated reactant having a desired shape or size. The method comprises providing solid reactant particles and an encapsulating material. The encapsulating material is heated above its solidification temperature to form a molten, semi-solid, or liquid encapsulating material. The solid reactant particles are added to the molten, semi-solid, or liquid encapsulating material and mixed to disperse the solid reactant particles in the encapsulating material and form a mixture. The mixture may be extruded or formed into the desired shape or size of the encapsulated reactant, or the mixture may be solidified and extruded, granulated, shredded, ground, or pressed into the desired shape or size.
PARTICULATE NUCLEATING AGENT AND METHOD FOR MANUFACTURING THE SAME
The present invention provides a particulate nucleating agent and a method for manufacturing the same. The particulate nucleating agent has an average radial crushing strength of 0.2-25.0N/cm. A weight content of the active ingredients in the particulate nucleating agent is no less than 90 wt %. The particulate nucleating agent is a transparent particulate nucleating agent. The particulate nucleating agent of the present invention can be fed smoothly during production without the change of the chemical composition thereof, so as to realize uniform dispersion in the polymer and reduce defects such as white dots in the polymer. The present invention breaks the traditional view of refining particles of nucleating agent to obtain a polymer having desirable properties, and avoids adding large amount of materials except the active ingredients during the granulation process of the nucleating agent.
A PROCESS FOR THE PREPARATION OF TPU ALLOY BY IN-SITU REACTIVE COMPATIBILITY TECHNOLOGY
A process for preparing a TPU alloy material through in-situ compatibilization includes: 1) adding a premixed TPU raw material to a feeding port of a twin-screw extruder; injecting a mixture of an alloy component and a dual-active substance into the twin-screw extruder through a lateral feeding port; adding an auxiliary reagent to the TPU raw material or the mixture of the alloy component and the dual-active substance, wherein the alloy component is a polyolefin or a thermoplastic polymer material having reactivity, wherein the dual-active substance is a substance containing a group reactive with the TPU raw material and a group reactive with the alloy component, and the auxiliary reagent includes an initiator; 2) controlling a temperature of a reaction zone of the twin-screw extruder at 50 C. to 250 C., and granulating an extruded material by underwater cutting; and 3) drying the granulated product to obtain the TPU alloy material.
A PROCESS FOR THE PREPARATION OF TPU ALLOY BY IN-SITU REACTIVE COMPATIBILITY TECHNOLOGY
A process for preparing a TPU alloy material through in-situ compatibilization includes: 1) adding a premixed TPU raw material to a feeding port of a twin-screw extruder; injecting a mixture of an alloy component and a dual-active substance into the twin-screw extruder through a lateral feeding port; adding an auxiliary reagent to the TPU raw material or the mixture of the alloy component and the dual-active substance, wherein the alloy component is a polyolefin or a thermoplastic polymer material having reactivity, wherein the dual-active substance is a substance containing a group reactive with the TPU raw material and a group reactive with the alloy component, and the auxiliary reagent includes an initiator; 2) controlling a temperature of a reaction zone of the twin-screw extruder at 50 C. to 250 C., and granulating an extruded material by underwater cutting; and 3) drying the granulated product to obtain the TPU alloy material.
EXTRUDING NOZZLE, SYSTEM, AND METHOD THEREFOR
An extruding nozzle is provided. The extruding nozzle includes a housing and a radiator. The radiator is at least partially disposed within the housing. The extruding nozzle also includes at least one material flow channel. The at least one material flow channel is at least partially disposed within the housing and extends through the radiator.
EXTRUDING NOZZLE, SYSTEM, AND METHOD THEREFOR
An extruding nozzle is provided. The extruding nozzle includes a housing and a radiator. The radiator is at least partially disposed within the housing. The extruding nozzle also includes at least one material flow channel. The at least one material flow channel is at least partially disposed within the housing and extends through the radiator.