Patent classifications
B01J3/008
Method to produce light olefins from crude oil
Embodiments of the disclosure provide a system and method for producing light olefins from a crude oil. A crude oil feed is introduced to a crude distillation unit to produce a distillate fraction and a residue fraction. The distillate fraction is introduced to a non-catalytic steam cracker to produce a light olefin fraction and a pyrolysis oil fraction. The residue fraction is introduced to a supercritical water reactor to produce an effluent stream. The effluent stream is introduced to a flash separator to produce a gas phase fraction and a liquid phase fraction. The gas phase fraction is introduced to a catalytic steam cracker to produce a light olefin fraction and a pyrolysis oil fraction. Optionally, the residue fraction is introduced to a vacuum distillation unit to produce a light vacuum gasoil fraction, a heavy vacuum gasoil fraction, and a vacuum residue fraction. The vacuum residue fraction is introduced to a solvent deasphalting unit to produce a deasphalted oil and a pitch fraction. The deasphalted oil fraction, optionally combined with the heavy vacuum gasoil fraction, can be introduced to the supercritical water reactor in lieu of the residue fraction.
SYSTEM FOR CHEMICAL TRANSFORMATION OF 3D STATE MATERIALS
A system for chemical transformation of 3D state materials is disclosed wherein, a reaction group having a main body arranged to shape a reaction chamber in which a component configured to support a sample of 3D state arranged to be chemically transform is expected. The system further includes an oven arranged to heat the reaction chamber and a GAS supply group arranged to release a first gas in the reaction chamber and/or a casing component, inside the main body, which has a chemical agent suitable for releasing a second gas into the reaction chamber. The main body has at least two turbines arranged to converge into the reaction chamber, the first and/or the second gas on the samples. The invention relates also to a method for chemical transformation of 3D state materials.
Supercritical water and ammonia oxidation system and process
The present application provides systems and methods for upgrading an oil stream. The system includes a reactor, a phase separator, an expansion device, a cooling unit, and two separation units. The reactor receives the oil stream, ammonia, and supercritical water. The supercritical water upgrades the oil stream, and the ammonia reacts with sulfur initially present in the oil stream to produce ammonia-sulfur compounds. The phase separator receives a mixture stream comprising the upgraded oil stream, supercritical water, and the ammonia-sulfur compounds, and separates out non-dissolved components. The expansion device reduces the pressure of the mixture stream below a water critical pressure. The cooling unit reduces the temperature of the mixture stream. A first separation unit separates the mixture stream it into a hydrocarbon-rich gaseous phase, a water stream containing ammonia-sulfur compounds, and a treated oil stream. A second separation unit separates the ammonia-sulfur compounds from the water stream.
Horizontal self-balancing supercritical reaction apparatus
A horizontal self-balancing supercritical reaction apparatus, comprising a pressure vessel, a high pressure air compression apparatus, and at least one reactor arranged within the pressure vessel. The reactor is internally provided with front and rear pistons, two ends of the reactor are sealed by the reactor front piston and the reactor rear piston, a pressure medium is filled between the reactor front piston and an inner wall of the pressure vessel, the reactor rear piston is connected to a rear piston driving motor by a rear piston push rod, the reactor is provided with a water inlet and a water/air outlet which are controlled by valves, the reactor is internally provided with a heating apparatus, and the high pressure air compression apparatus is connected to the inside of the reactor. The present invention utilises a pressure self-balancing system, which significantly improves the stress characteristics of the reactor.
Taxane particles and their use
Compositions are provided that include having at least 95% by weight of a taxane, or a pharmaceutically acceptable salt thereof, where the particles have a mean bulk density between about 0.050 g/cm.sup.3 and about 0.15 g/cm.sup.3, and/or a specific surface area (SSA) of at least 18 m.sup.2/g, 20 m.sup.2/g, 25 m.sup.2/g, 30 m.sup.2/g, 32 m.sup.2/g, 34 m.sup.2/g, or 35 m.sup.2/g. Methods for making and using such compositions are also provided.
POLYMER COMPOSITION
A method of impregnating a polymer composition with an active compound or composition using liquid carbon dioxide, in order for the active compound or composition to be later released from the polymer composition gradually over a period of time. The polymer composition may comprise polybutylene succinate and pores and/or cavities into which the active compound or composition can be introduced by the method. The method involves exposing the polymer composition to carbon dioxide and the active compound or composition under increased pressure. The polymer composition may be used to form an article for use in repelling or attracting insects, for example wearable insect repellent articles or lures for insect traps. Polymer compositions suitable for use in the method, and articles comprising said polymer compositions and active compounds or compositions are also described. A method of attracting or repelling insects is also described.
REACTOR FOR THE HYDROTHERMAL OXIDATION TREATMENT OF AN ORGANIC MATERIAL IN A REACTION MEDIUM
A reactor for hydrothermal oxidation treatment of an organic material in a reaction medium, comprising: a confinement member housed in a chamber and defining a confinement zone and a peripheral zone; at least one inlet for an oxidising fluid into the peripheral zone; a first cooling system, with an external circulation cold loop having a fluid inlet and outlet, opening into a first portion of the peripheral zone; a heating system, with an external circulation hot loop having a fluid inlet and outlet opening into a second portion of the peripheral zone; a channel with a mouth, a channel stirring system; a second cooling system for creating a temperature gradient along the channel between a cold temperature and the reaction temperature; each circulation loop being equipped with a circulator and with a heat exchanger.
Method for Removing Volatile Organic Compounds from Sponge by Using Supercritical or Subcritical Fluid
Disclosed is a method of removing volatile organic compounds from sponges by using supercritical/subcritical fluid, The method includes the following steps: placing the sponge block to be treated in the extraction kettle; feeding the critical flow medium into the extraction kettle; performing extraction under the supercritical or subcritical conditions of the critical flow medium; releasing pressure to normal pressure after extraction; and separating to obtain devolatilized sponge. The volatile removal device used in the disclosure is a supercritical extraction equipment, which can adopt static extraction or dynamic extraction or a combination of the two. CO2 releases pressure in the separating kettle after contacting the sponge to be treated in the device for mass transfer for a certain period, when the static extraction devolatilization is carried out.
Device and process under conditions close to the supercritical range or under supercritical conditions
A process including introducing, into a device, an aqueous fluid containing at least one inorganic salt, the water of the aqueous fluid being in supercritical conditions or close to the supercritical range in the device, and measuring the concentration or the amount of inorganic salt in the device, this measurement preferably being carried out before the entry of the inorganic salt into the device, Then bringing the inorganic salt into contact with an aqueous flow containing at least one hydroxide salt to obtain in the device an aqueous fluid mixture containing an inorganic salt and a hydroxide salt and adjusting the concentration or amount of the hydroxide salt as a function of the concentration or amount of the inorganic salt needed to at least partially solubilize the inorganic salt. Preferably the measurement of the concentration or the amount of inorganic salt leaving the device is also performed.
METHOD AND SYSTEM FOR SUPERCRITICAL FLUID EXTRACTION OF METAL
A method for supercritical fluid extraction of metal from a source, the method comprising: providing a reactor chamber; providing a source comprising a target metal; optionally, providing a chelating agent; providing a solvent; adding the source comprising the target metal, the chelating agent and the solvent into the reactor chamber; adjusting the temperature and pressure in the reactor chamber so that the solvent is heated and compressed above its critical temperature and pressure; optionally, providing mechanical agitation to the reactor chamber; recovering a chelate comprising the target metal.