A gas generation plant for generating hydrogen-containing synthesis gas includes a gas generation reactor which is oriented in the vertical direction being greater in length vertically than width. A gas inlet is designed for the passage of superheated water vapor into the gas generation reactor. Through an upper outlet, a gas/water vapor mixture can exit the gas generation reactor and be reused in the second heating element after having been superheated. Synthesis gas can exit through a lower gas outlet. In the vertical direction, the gas inlet is arranged at a smaller distance from the lower end than the lower gas outlet. The upper gas outlet is arranged at a smaller vertical distance from the upper end than the lower gas outlet. The vertical distance between the upper gas outlet and the lower gas outlet is greater than the vertical distance between the lower gas outlet and the gas inlet.

Apparatuses for gasifying glycerol using solar energy, system including the apparatuses, and methods of using the apparatuses are provided. The apparatuses may include a concentrated solar dish comprising an opening and a gasifying reactor comprising a chamber. An entrance of the chamber may be aligned to the opening. The apparatuses may also include a thermal insulator disposed on outer surfaces of the concentrated solar dish and the gasifying reactor and a pipe in the thermal insulator. The pipe may be configured to deliver glycerol into the chamber of the gasifying reactor in the form of atomized mist. The glycerol may be delivered to a portion of the chamber adjacent the opening.

A process for producing biocoke is provided, comprising: providing a heated biogas stream comprising carbon-containing vapors; providing a kinetic interface media, in solid form; introducing the kinetic interface media and the heated biogas stream to a kinetic interface reactor, operated to convert at least some of the carbon-containing vapors to biocoke; removing the solid biocoke-containing kinetic interface media from the kinetic interface reactor; and recovering the solid biocoke-containing kinetic interface media. Other variations provide a process for producing biocoke, comprising: providing a bioliquid stream comprising carbon-containing liquids; providing a kinetic interface media, in solid form; introducing the kinetic interface media and the bioliquid stream to a kinetic interface reactor, operated to convert at least some of the carbon-containing liquids to biocoke; removing the solid biocoke-containing kinetic interface media from the kinetic interface reactor; and recovering the solid biocoke-containing kinetic interface media. Many embodiments are described.

A device (1) and method are claimed for converting thermal energy into dissociation energy of molecules of a gas medium (3). The device incorporates a reaction vacuum chamber (2), designed to enable a gas medium (3) to be supplied therein, at least one thermal radiator (4), of which at least one emission spectral line of a medium (5), in the temperature range 350° C. to 1500° C., at least partially corresponds to the absorption spectral line of molecules of the gas medium (3). At least part of the volume of the vacuum chamber (2) is positioned in the zone of optical visibility of the radiator (4) and is a reaction volume (7) for the gas medium (3), in which reaction volume, as a result of resonance oscillations of molecules of the gas medium (3), excited by the radiator (4), at least partial dissociation of the gas medium (3) takes place. The device also incorporates a system (8) for drawing off at least one product of dissociation of molecules of the gas medium (3).

A distribution chamber suitable for distributing a liquid stream to a plurality of pipe openings distributed over a planar surface. The distribution chamber includes three perforated plates. A method to distribute a liquid stream to a plurality of pipe openings, a method to decompose ammonium carbamate from an aqueous solution comprising ammonium carbamate and a method to produce a concentrated aqueous urea solution from a diluted aqueous urea solution.

The present invention relates to a method for molten metal pyrolysis of a feed comprising hydrocarbons and nitrogen and/or hydrogen sulphide to produce solid carbon and one or more of liquid sulfur, hydrogen gas and ammonia gas. The molten salt layer contains two reaction zones of different temperatures, a high temperature zone for pyrolysing the hydrocarbon and a low temperature zone for pyrolysing the hydrogen sulphide and/or forming the ammonia. Liquid salt is used to separate produced solid carbon and optionally the produced liquid sulphur from the molten metal and to facilitate isolation of produced carbon. The invention further relates to a reactor for performing the method according to the invention.

Provided are a graphene preparation apparatus, including: a chamber having a space for preparation of graphene; a first electrode and a second electrode disposed in the chamber to be separated a predetermined distance from each other, the first electrode and the second electrode supporting a catalytic metal and receiving electric current for preparation of the graphene to heat the catalytic metal using Joule heating; additional heaters disposed at opposite sides of the catalytic metal, respectively, and heating the catalytic metal to compensate for a temperature difference between both end regions and a central region of the catalytic metal heated using Joule heating induced by the first electrode and the second electrode; and a current supply unit supplying electric current to the first electrode and the second electrode.

Direct thermal decomposition of hydrocarbons into solid carbon and hydrogen is performed by a process and a device. The process comprises preheating a hydrocarbon gas stream to a temperature between 500° C. and 700° C. and injecting the pre-heated hydrocarbon gas stream into the reactor pool of a liquid metal reactor containing a liquid media; forming a multi-phase flow with a hydrocarbon gas comprising hydrogen and solid carbon at a temperature between 900° C. and 1200° C.; forming a carbon layer on the free surface of the liquid media made up of solid carbon particles which are then displaced into at least one carbon extraction system and at least one recipient for collecting them; and, at the same time, the gas comprising hydrogen leaves the reactor pool through a porous rigid section, being collected at a gas outlet collector from where the gas comprising hydrogen finally leaves the liquid metal reactor.

The device for pyrolysis of carbonaceous materials comprises a working chamber comprising a non-magnetic wall comprising an inner graphite lining; one or more electrodes adapted to be inserted within a carbon-based bedding; a solenoid coiled around the device exterior, the solenoid adapted to create a magnetic field within the working chamber such that when the solenoid is energized, the carbon-based bedding is caused to move; a lower solids outlet comprising an airlock, the solids outlet adapted to permit solids to exit the device; and a lower gas outlet adapted to permit gaseous substances to exit after having traveled through the carbon-based bedding. The method comprises the steps of loading carbon-containing materials into the working chamber; using the first and second electrodes to heat the carbon-containing materials by passing electric current through the carbon-containing materials without air access; collecting, cleaning and releasing gaseous pyrolysis products produced by the heating.

The disclosure describes a system for generating hydrogen gas from a hydrocarbon through pyrolysis with reduced soot formation and increased carbon loading. The system includes a pyrolysis reactor configured to generate the hydrogen gas from the hydrocarbon through pyrolysis. The pyrolysis reactor includes one or more fibrous substrates configured to provide a deposition surface for carbon generated from the pyrolysis of the hydrocarbon. Each fibrous substrate has an effective void fraction between 40% and 95%, and includes a plurality of fibers configured to maintain chemical and structural stability between about 850° C. and about 1300° C. The one or more fibrous substrates may have a relatively high surface area to fiber volume of the plurality of fibers.