Disclosed are systems, servers and methods for improving temperature profile control in a reactor with at least three fixed beds, exothermic reactions and interstage cooling. A model of the temperature differential across the first bed is developed and its error is used to infer unmeasured feed composition disturbances, which are used in the control of the downstream fixed beds for faster response to unmeasured feed composition changes and improved control of the temperature profile throughout the reactor. The first bed model error is then used as an input into an overall model that predicts reactor temperature profiles, which provides advanced notice of reactions in downstream beds, and enables efficient adjustment and compensation to a feed composition change. A Model Predictive Control (MPC) algorithm is applied to adjust the bed intercooling and first bed feed temperature so that the reactor temperature profile can be more precisely controlled.

A method for removing perfluorinated compounds from a fluoropolymer material is provided. The method includes the steps of: (a) providing the fluoropolymer material in a chamber; (b) providing an anaerobic environment in the chamber; and (c) providing a fluorination gas in the chamber, thereby exposing the fluoropolymer material to the fluorination gas. The method results in the removal the perfluorinated compounds from the fluoropolymer material.

Herein are described apparatus and processes for the preparation of cannabinoids, such as cannabidiol (CBD) and derivatives thereof. The apparatus and processes described can be used for the one-step, flow-mediated synthesis of cannabidiol and derivatives with improved overall yield, material throughput, and product purity relative to batch processes.

Disclosed is a catalyst pre-contact method for the continuous polymerization of an olefin, wherein a primary catalyst, a co-catalyst and, optionally, an external electron donor are mixed and then undergo a pre-contact reaction, with the pre-contact reaction temperature being −30° C. to 35° C. and adjustable, and the pre-contact reaction time being 0.5 min to 10 min and adjustable, and the pre-contacted catalyst is brought into a catalyst prepolymerization system and then into a catalyst polymerization system, or is directly brought into the catalyst polymerization system. Further disclosed is a catalyst pre-contact device for the continuous polymerization of an olefin, which can adjust the pre-contact time and pre-contact temperature of the catalyst so that the performance of the catalyst achieves a better level according to the process.

In an aspect, the present disclosure provides a method for the oxidative coupling of methane to generate hydrocarbon compounds containing at least two carbon atoms (C.sub.2+ compounds). The method can include mixing a first gas stream comprising methane with a second gas stream comprising oxygen to form a third gas stream comprising methane and oxygen and performing an oxidative coupling of methane (OCM) reaction using the third gas stream to produce a product stream comprising one or more C.sub.2+ compounds.

Provided herein are methods, systems, and apparatus for measuring and/or controlling mass flow/concentration of a catalytically reactive gas within a mixed gas stream by determining thermal rise due to decomposition.

The invention relates to an integrated process for assessing one or more properties of a catalyst. In the method, a standard chemical reactor or reactors is/are provided, and a bypass means is also provided, to transport a sample of whatever is added to the industrial reactor, to the test reactor. Both gases and liquids are transferred to the test reactor.

A reformer suitable for micro-scale design has horizontal catalyst tube(s) passing through a baffled radiant section for convective and radiant heat transfer to the tube(s). To reduce the footprint and/or to facilitate field assembly a combustion chamber and convection section can be oriented transversely with respect to the radiant section; the tube(s) can be horizontal and/or include structured catalyst; and/or the combustion chamber provides flameless combustion or produces a flame without impinging on the tubes. Also, a skid frame-mountable version of the reformer; and a process for transporting, assembling, and/or operating the steam methane reformer.

A process and system for the conversion of a feedstock comprising C3-C5 light alkanes to a C5+ hydrocarbon product, for example, a BTX-rich hydrocarbon product, by performing the alkane activation (first-stage) and the oligomerization/aromatization (second-stage) in separate stages, which allows each conversion process to occur at optimal reaction conditions thus increasing the overall hydrocarbon product yield. The alkane activation or first-stage is operated at a higher temperature than the second-stage since light alkanes are much less reactive than light olefins. Since aromatization of olefins is more efficient at higher pressure, the second-stage is maintained at a higher pressure than the first-stage. Further, fixed-bed catalysts are used in each of the first-stage and the second-stage.

The present disclosure relates generally processes and systems for converting a C2-C7 light alkanes feed to liquid transportation fuels or value-added chemicals. The feed is contacted with an aromatization catalyst at a temperature and pressure that selectively converts C4 and larger alkanes to an intermediate product comprising monocyclic aromatics and olefins. Following separation of the aromatics and C5+ hydrocarbons from the intermediate product, unconverted C2-C3 alkanes are thermally-cracked to produce olefins that are subsequently oligomerized to produce a liquid transportation fuel blend stock or value-added chemicals.