Chemical looping systems and methods for producing hydrogen gas are described herein that use a fluidized-bed reactor to reduce carrier particles; and a moving-bed hydrogen reactor to oxidize the reduced carrier particles and form hydrogen gas. Also possibly included as a cooler for cooling the oxidized carrier particles; and a silo for storing the oxidized carrier particles and feeding them to the fluidized-bed reactor and other components. Various configurations of these components are disclosed herein.

An apparatus for carrying out a gas-phase olefin polymerization having a first polymerization zone having a cylindrical segment of diameter D01, a second polymerization zone having a cylindrical upper part of diameter D05 and a cylindrical lower part of diameter D06, a separation zone of diameter D04, a first connecting element of diameter D03, which is a bend of radius R03 or has a bend part of radius R03, a gas recycle line of diameter D08, a transition segment of diameter D02, and a second connecting element of a diameter D09, which is a bend or has a bend part, wherein the ratio D04 to D05 is 1.0 to 1.5, the ratio D05 to D06 is 1.2 to 2, the ratio R03 to D03 is 1 to 6, the ratio D03 to D01 is 0.3 to 0.85, and the ratio D08 to D02 is 1.0 to 2.2.

The invention relates to a system for producing polyolefin. The system comprises a gas phase reactor (1) for polymerizing an olefin to obtain polymerization product. The gas phase reactor (1) comprises a gas distribution plate (11) arranged inside the gas phase reactor (1); a first outlet (12) for continuously withdrawing polymerization product from the gas phase reactor (1) as a first product stream, the first outlet (12) being arranged above the gas distribution plate (11); and a second outlet (13) for continuously withdrawing polymerization product from the gas phase reactor (1) as a second product stream, the second outlet (13) being arranged above the gas distribution plate (11). The system further comprises a first outlet tank (2) in fluid communication with the first outlet (12) via a first passage (22), wherein the first passage (22) comprises a first valve means (221) for controlling the flow of the first product stream in the first passage (22) and wherein the first outlet tank (2) is arranged to receive the first product stream and to concentrate the first product stream; a product receiver tank (3) in fluid communication with the second outlet (13) via a second passage (31), wherein the second passage (31) comprises a second valve means (311) for controlling the flow of the second product stream in the second passage (31), and wherein the product receiver tank (3) is arranged to receive the second product stream; and a control means in communication with the first valve means (221) and the second valve means (311) and arranged to control the operation of the first valve means (221) and the second valve means (311) so that flow in only one of the first passage (22) and the second passage (31) is allowed at a time. The invention relates also to a process for recovering polymerization product from a gas phase reactor (1). The gas phase reactor (1) is suitable for polymerizing an olefin to obtain polymerization product and comprises a gas distribution plate (11) arranged inside the gas phase reactor (1); a first outlet (12) for continuously withdrawing polymerization product from the gas phase reactor (1), the first outlet (12) being arranged above the gas distribution plate (11); and a second outlet (13) for continuously withdrawing polymerization product from the gas phase reactor (1), the second outlet (13) being arranged above the gas distribution p

A slurry reactor system including a slurry reactor configured to convert, under slurry hydroconversion conditions, a slurry reactor content flowing upwards and containing a feedstock including one or more of fats, oils and greases, a slurry hydroconversion catalyst and a hydrogen stream to a slurry hydroconversion effluent containing a slurry phase effluent including catalyst particles and a liquid product and a vapor phase effluent including a hydroconversion product, and a separation unit external to the slurry reactor to separate the slurry phase effluent from the vapor phase effluent to produce a recycled slurry stream. An inlet of the separation unit is in fluid communication with an outlet of the slurry reactor to receive the slurry hydroconversion effluent from the slurry reactor and an outlet of the separation unit is in fluid communication with an inlet of the slurry reactor to receive the recycled slurry stream from the separation unit.

A fluidized bed device for coupling naphtha and methanol to prepare aromatics and co-produce olefins and its application method are provided. By using the device, under the action of a catalyst, naphtha reacts with methanol to generate product gas containing aromatics and light olefins as main components. The method can efficiently and selectively convert linear and branched aliphatic hydrocarbons into aromatics, while also increasing p-xylene production through aromatic methylation reactions, with the p-xylene content in the xylene mixture exceeding 75 wt %. The fluidized bed reactor achieves increased p-xylene production by controlling the progression of cascade reactions (naphtha.fwdarw.benzene/toluene.fwdarw.p-xylene). Additionally, it utilizes the methylation reaction of benzene/toluene with methanol to provide in-situ heat for the coupled naphtha-methanol aromatization process, thereby achieving autothermal balance.

A process for producing high purity hydrogen includes separating a gas stream comprising hydrogen and unreacted light hydrocarbons from a product effluent comprising the gas stream comprising the hydrogen and the unreacted light hydrocarbons, and a spent carbon supported metal catalyst comprising one or more active metal compounds and solid carbon deposits derived from catalytically cracking a light hydrocarbon feedstock in the presence of a carbon supported metal catalyst comprising one or more active metal compounds in a reactor, separating the hydrogen and the unreacted light hydrocarbons from the gas stream comprising the hydrogen and the unreacted light hydrocarbons, and withdrawing high purity hydrogen.

A process for continuous production of partly crystalline polycondensate pellet material which comprises the step of crystallizing the pellet material in a second treatment space (6a) under fixed bed conditions by supply of energy from the exterior by means of a process gas, wherein the process gas has a temperature (T.sub.Gas), which is higher than the sum of the pellet temperature (T.sub.GR) and the temperature increase (T.sub.KR) which occurs due to heat of crystallization released hi the second treatment space (6a), i.e., (T.sub.Gas>(T.sub.GR+T.sub.KR)). The pellets at the exit from the second treatment space (6a) have an average temperature (T.sub.PH), which is 10 to 90 C. higher than the sum of the temperature of the pellets (T.sub.GR) and the temperature increase (T.sub.KR) which occurs due to heat of crystallization released in the second treatment space (6a), i.e., (T.sub.GR+T.sub.KR+90 C.)T.sub.PH(T.sub.GR+T.sub.KR+10).

A hybrid catalyst for simultaneous dehalogenation and cracking of plastic derived oil includes a plurality of composite particles, wherein each of the composite particles includes red mud particles and beta zeolite particles. A process for upgrading plastic derived oil includes contacting the plastic derived oil with the hybrid catalyst. A system for upgrading plastic derived oil includes an FCC reactor containing the hybrid catalyst.

A hybrid catalyst for simultaneous dehalogenation and cracking of plastic derived oil includes a plurality of composite particles, where each of the composite particles includes red mud particles and USY zeolite particles. A process for upgrading plastic derived oil includes contacting the plastic derived oil with the hybrid catalyst in an FCC reactor to produce an FCC effluent and a used hybrid catalyst. The plastic derived oil comprises halogen-containing compounds, and the contacting at reaction conditions causes halogen-containing compounds to react to form hydrocarbons and hydrogen halides, which are adsorbed onto surfaces of the red mud particles. The contacting at reaction conditions also causes hydrocarbons in the plastic derived oil to undergo cracking reactions to produce the FCC effluent. The FCC effluent may have a reduced concentration of the halogen-containing compounds. A system that includes the hybrid catalyst is also disclosed.

A process for screening polymer from a polymer-lean vapor stream, whereby the process comprises the steps of separating an effluent stream comprising the polymer and a first mixture of hydrocarbons into a polymer-rich stream and the polymer-lean vapor stream; spraying a condensed vapor composition comprising a second mixture of hydrocarbons into the polymer-lean vapor stream via a condensed vapor composition stream; screening a screened condensed vapor composition stream comprising the polymer and the condensed vapor composition from the polymer-lean vapor stream.