Patent classifications
B01J10/002
Micro-interface enhanced oxidation system and oxidation method for preparing hydrogen peroxide
The invention provides a micro-interface enhanced oxidation system and an oxidation method for preparing hydrogen peroxide, wherein the micro-interface enhanced oxidation system includes: an oxidation reactor, wherein a top portion of a side surface is provided with a liquid phase pipeline for delivering hydrogenated anthraquinone, and a bottom portion of the side surface is provided with a gas phase pipeline for delivering air; and a liquid distributor, a packing section, a seal pan and a hybrid micro-interface unit that are arranged in order from top to bottom are arranged in the oxidation reactor, wherein the hybrid micro-interface unit comprises a upper-mounted micro-interface generator and a lower-mounted micro-interface generator that are communicated with each other up and down, and the hydrogenated anthraquinone delivered in goes down in turn until being mixed with the air in the hybrid micro-interfacial unit to be dispersed and crushed after being distributed through the liquid distributor.
METHOD FOR OLIGOMERISATION IN A GAS/LIQUID REACTOR COMPRISING A CENTRAL DUCT
The present invention relates to a gas/liquid reactor for the oligomerization of gaseous ethylene, comprising a central pipe which delimits inside the reactor chamber a central zone allowing a descending flow and an outer zone allowing an ascending flow, thus making it possible to increase the time of travel of the injected gas bubbles in the liquid phase, without increasing the volume of the liquid phase and thus the volume of the reactor.
Bubble Column Reactor
Provided is a bubble column reactor including a reaction zone configured to carry out a reaction of a gaseous reactant in a liquid reaction medium; a disengaging section provided above the reaction zone and configured such that a first gas stream rising from the reaction zone is introduced into the disengaging section; and a condensation zone provided above the disengaging section and configured such that a second gas stream rising from the disengaging section is introduced into the condensation zone, wherein a diameter of the condensation zone is greater than a diameter of the disengaging section.
OXIDATION CONTROL FOR IMPROVED FLUE GAS DESULFURIZATION PERFORMANCE
A system and method of using the system for controlling oxidation of sulfites to reduce total nitrite and nitrate levels in a slurry is disclosed. The system includes a tank having an inlet for receiving a slurry produced in a wet flue gas desulfurization process. The tank also includes an inlet for receiving a gas. The inlet for receiving the gas is operable to disperse at least a portion of the gas received in the tank through at least a portion of the slurry received in the tank. A sensor is configured to measure a sulfite concentration of the slurry received in the tank to obtain a sulfite concentration measurement. In some embodiments, the sensor is a sulfite analyzer. In other embodiments, the sensor is a virtual analyzer. The system also includes a controller. Software executing on the controller generates an electronic signal affecting an adjustment of a flow rate of gas into the slurry in the tank based at least in part on the sulfite concentration/sulfite concentration measurement.
FURAN-2,5-DICARBOXYLIC ACID PURGE PROCESS
Disclosed is an oxidation process to produce a crude carboxylic acid product carboxylic acid product. The process comprises oxidizing a feed stream comprising at least one oxidizable compound to generate a crude carboxylic acid slurry comprising furan-2,5-dicarboxylic acid (FDCA) and compositions thereof. Also disclosed is a process to produce a dry purified carboxylic acid product by utilizing various purification methods on the crude carboxylic acid.
Alkylbenzene hydroperoxide production using dispersed bubbles of oxygen containing gas
An apparatus for oxidation of a C.sub.8-C.sub.12alkylbenzene reactant to a C.sub.8-C.sub.12 alkylbenzene hydroperoxide product, the re-actor can comprise: a flow reactor comprising a reactant inlet, an oxidate product outlet, wherein the reactor is configured to provide a liquid flow from the reactant inlet to the product outlet, a gas inlet configured to introduce an oxygen-containing gas into the reactor, and an inlet sparger configured to flow gas bubbles comprising the oxygen-containing gas within the liquid flow, and wherein: the inlet sparger is configured to flow the gas bubbles having a diameter of 1.0 mm to 5.0 mm over a gas bubble residence time from 1 to 200 seconds, and/or the inlet sparger configured to flow the gas bubbles such that greater than or equal to 80% of the gas bubbles do not coalesce into larger bubbles over a gas bubble residence time of 1 to 200 seconds.
Segmented reactor for homogeneous regeneration of spent ionic liquid
We provide a segmented reactor for regenerating a spent acidic ionic liquid via a hydrogenation reaction and hydrocracking, comprising: no solid hydrogenation catalyst; a gas inlet on one side for feeding a gas feed comprising a hydrogen; a liquid inlet on an opposite side for feeding a spent acidic ionic liquid; partitions along an axis of the reactor that create segments, wherein each segment functions as a bubble column reactor; and an outlet from which a regenerated acidic ionic liquid flows out of the segmented reactor.
Processes for increasing bioalcohol yield from biomass
A process for increasing alcohol yield from biomass (the form or agro- or forest residue, grains, hops, etc.), involving multiple hydrodynamic cavitation treatments of biomass filtrateboth before and after fermentation. Carbohydrates extracted from biomass are subjected to a first cavitation treatment to promote additional conversion into carbohydrates. The carbohydrates are then combined with bacterial species and nutrients, and allowed to ferment. The fermentation product is subjected to a second hydrodynamic cavitation treatment to promote further conversion of carbohydrates into bioalcohol. After distillation, the bioalcohol is subjected to a second hydrodynamic cavitation treatment to increase its purity.
Airlift Reactor Assembly with Helical Sieve Plate
The present invention discloses an airlift reactor assembly with a helical sieve plate, comprising a reaction tank, wherein a draft tube and a gas sparger are assembled in the reaction tank, the gas sparger is arranged just below an riser section of the draft tube, a helical sieve plate is arranged in the riser section of the draft tube, and a body of the helical sieve plate is helical upwards to guide a part of two/three-phase flow in the riser section, and the body of the helical sieve plate is provided with a plurality of sieve meshes to guide the remaining two/three-phase go through the helical sieve plate in the riser section and to break bubbles. The present invention gives consideration to both macroscopic mixing and microscopic mixing processes. In addition to driving liquid to circularly flow by using ejected gas, the helical sieve plate can be used for breaking large bubbles into small bubbles thereby effectively preventing the bubbles from coalescing, increasing gas holdup and increasing a volumetric oxygen transfer coefficient.
Processes for increasing bioalcohol yield from biomass
A process for increasing alcohol yield from biomass (the form or agro- or forest residue, grains, hops, etc.), involving multiple hydrodynamic cavitation treatments of biomass filtrateboth before and after fermentation. Carbohydrates extracted from biomass are subjected to a first cavitation treatment to promote additional conversion into carbohydrates. The carbohydrates are then combined with bacterial species and nutrients, and allowed to ferment. The fermentation product is subjected to a second hydrodynamic cavitation treatment to promote further conversion of carbohydrates into bioalcohol. After distillation, the bioalcohol is subjected to a second hydrodynamic cavitation treatment to increase its purity.