Methods for the photoreduction of molecules are provided, the methods comprising illuminating an amino-terminated diamond surface comprising amino groups covalently bound to the surface of diamond with light comprising a wavelength sufficient to excite an electronic transition defined by the energy band structure of the amino-terminated diamond, thereby inducing the emission of electrons from the amino-terminated diamond surface into a sample comprising molecules to be reduced, wherein the emitted electrons induce the reduction of the molecules to form a reduction product; and collecting the reduction product.

Disclosed is a process for the catalytic thermal decomposition of ammonia into hydrogen and nitrogen by contacting ammonia at a temperature of at least 500 C. with a porous ceramic layer which comprises nickel. Also disclosed is a reactor for carrying out the process.

A modular device for generating hydrogen gas from a hydrogen liquid carrier may include a housing; an inlet for receiving the hydrogen liquid carrier; and at least one cartridge arranged within the housing. The cartridge may include at least one catalyst configured to cause a release of hydrogen gas when exposed to the hydrogen liquid carrier. The modular device may include a gas outlet for expelling the hydrogen gas released in the modular device and a liquid outlet for expelling spent hydrogen liquid carrier.

A reactor includes a plurality of reaction side flow passages through which a reaction fluid flows, a catalyst (catalyst structure) disposed inside the reaction side flow passages to accelerate the reaction of the reaction fluid, a plurality of heat medium side flow passages which are alternately stacked with the reaction side flow passages, and through which a heat medium flows, and a suppression flow passage which is disposed adjacent to a surface of the reaction side flow passage, the heat medium side flow passages being not stacked on the surface, and through which flows a suppression fluid suppressing the heat dissipation to the outside from the reaction fluid flowing through the reaction side flow passage, or the heat transfer from the outside to the reaction fluid.

Embodiments of methods and apparatuses for isomerization of paraffins are provided. In one example, a method comprises the steps of separating an isomerization effluent into a product stream that comprises branched paraffins and a stabilizer overhead vapor stream that comprises HCl, H.sub.2, and C.sub.6-hydrocarbons. C.sub.6-hydrocarbons are removed from at least a portion of the stabilizer overhead vapor stream to form a HCl and H.sub.2-rich stream. An isomerization catalyst is activated using at least a portion of the HCl and H.sub.2-rich stream to form a chloride-promoted isomerization catalyst. A paraffin feed stream is contacted with the chloride-promoted isomerization catalyst in the presence of hydrogen for isomerization of the paraffins.

Methods for the photoreduction of molecules are provided, the methods comprising illuminating an amino-terminated diamond surface comprising amino groups covalently bound to the surface of diamond with light comprising a wavelength sufficient to excite an electronic transition defined by the energy band structure of the amino-terminated diamond, thereby inducing the emission of electrons from the amino-terminated diamond surface into a sample comprising molecules to be reduced, wherein the emitted electrons induce the reduction of the molecules to form a reduction product; and collecting the reduction product.

A system for extracting hydrogen gas from a liquid hydrogen carrier may include a hydrogen gas reactor, a catalyst for facilitating extraction of the hydrogen gas from the liquid hydrogen carrier, and a reservoir for containing the liquid hydrogen carrier and a spend liquid hydrogen carrier. The system may be configured to regulate a flow of liquid hydrogen carrier in and out of the hydrogen gas reactor, to move a catalyst relative to a volume of the liquid hydrogen carrier, and to provide a continuous flow of the hydrogen gas, in response to a demand for the hydrogen gas.

Provided herein are systems and methods for chemical reactions involving heterogeneous catalysis.

A radial flow processing device includes a body with an inner chamber, a pair of inner and outer concentric tubes extending into the body, and a processing disk containing a central opening through which the inner tube extends, the disk being connected with the inner tube. The body has a top wall, a bottom wall, and at least one side wall which define the inner chamber. The bottom wall, top wall, or both, contain at least one opening through which at least one tube extends. A diameter of the inner tube is less than a diameter of the outer tube such that there is a space between both tubes, and a diameter of the disk is less than a width of the body.