B01J19/18

POLYMERIZATION INSTALLATION WITH INTEGRATED COMBINED ABSORPTION-DIFFUSION AND ABSORPTION-CONDENSATION UNIT AND ITS APPLICATION FOR POLYMER AND COPOLYMER PREPARATION
20220401902 · 2022-12-22 · ·

A polymerization installation with integrated combined absorption-diffusion and absorption-condensation unit, as well as to its use for the preparation of various polymers and copolymers by addition, emulsion, suspension or radical polymerization, which will find application in chemical industry. There are four structural units in the installation, as follows: supply unit (A), reaction unit (B), combined absorption-diffusion and absorption-condensation unit (C) and finished product discharge unit (D).

Polymerization Reactor for Production of Super Absorbent Polymer
20220403058 · 2022-12-22 · ·

A polymerization reactor for production of a super absorbent polymer according to the present disclosure includes: a composition supply part for supplying a monomer composition solution; a central pipe connected to the composition supply part; a composition distribution part including a water storage tank located at a discharge port of the central pipe; a distribution pipe connected to the water storage tank; and an ultrasonic device installed inside the water storage tank, a conveyor belt located under the composition distribution part and on which the composition solution is dropped, and an energy supply part for supplying polymerization energy to the composition solution on the conveyor belt, wherein the ultrasonic device supplies bubbles to the composition solution flowing into the water storage tank.

Oligomeriser with an improved feed system

In an embodiment, a reactor for carrying out a melt transesterification reaction at a reactor temperature of 160 to 300° C. and a reactor pressure of 5 to 200 mbar, comprises a cylindrical tank comprising a top, a side, and a bottom, wherein the bottom is convex, extending away from the top; a stirring shaft disposed within the cylindrical tank along an axis thereof so that it is rotatable from outside of the cylindrical tank; a stirring blade extending from the stirring shaft in the cylindrical tank; a reactant solution inlet located on the bottom; and a reaction solution outlet located on the bottom. The reactor can be used for the polymerization of a polycarbonate oligomer.

Oligomeriser with an improved feed system

In an embodiment, a reactor for carrying out a melt transesterification reaction at a reactor temperature of 160 to 300° C. and a reactor pressure of 5 to 200 mbar, comprises a cylindrical tank comprising a top, a side, and a bottom, wherein the bottom is convex, extending away from the top; a stirring shaft disposed within the cylindrical tank along an axis thereof so that it is rotatable from outside of the cylindrical tank; a stirring blade extending from the stirring shaft in the cylindrical tank; a reactant solution inlet located on the bottom; and a reaction solution outlet located on the bottom. The reactor can be used for the polymerization of a polycarbonate oligomer.

POLYMERIZATION PROCESS AND REACTOR FOR CONTROLLING MOLECULAR WEIGHT DISTRIBUTION AND COMONOMER COMPOSITION DISTRIBUTION
20220395801 · 2022-12-15 ·

A reactor for the polymerization of olefins comprising a first inlet for introducing a first stream comprising monomer(s), catalyst(s) and optionally hydrogen, solvent or comonomer(s) and/or mixtures thereof, at least one outlet for withdrawing a product stream, characterized in that the reactor further comprises at least one second inlet for introducing a second stream comprising monomer(s), catalyst(s) and optionally hydrogen, solvent or comonomer(s) and/or mixtures thereof; and a process for polymerizing olefins in a reactor according to the present invention, comprising the steps of introducing monomer(s), catalyst(s), and optionally hydrogen, solvent or comonomer(s) and/or mixtures thereof as the first stream via the first inlet into the reactor forming a reaction mixture; polymerizing a polymer from the reaction mixture; withdrawing the product stream via the at least one outlet from the reactor; characterized in that the process comprises a further step of introducing a second stream comprising monomer(s), catalyst(s), and optionally hydrogen, solvent or comonomer(s) and/or mixtures thereof into the reactor via the at least one second inlet into the reactor.

PREPARATION OF EXPANDED GRAPHITE BY PHYSICAL SHEARING
20220396487 · 2022-12-15 ·

Provided herein are high throughput continuous or semi-continuous reactors and processes for manufacturing expanded graphite materials. Such processes are suitable for manufacturing expanded graphite materials with little batch-to-batch variation.

Flow Reactor and Desulpurization Process
20220395802 · 2022-12-15 ·

A flow reactor comprising: a cylindrical body defining a conduit extending from a first end to a second end; a conduit inlet for providing a flow of a liquid reagent into the conduit, the conduit inlet at or near the first end; a conduit outlet for providing a flow of a liquid content from the conduit, the conduit outlet at or near the second end; a rotating screw arranged within the conduit and extending in the conduit, the rotating screw arranged to rotate about an axis extending from the first end to the second end, to direct the liquid content from the conduit inlet to the conduit outlet; and one or more ultrasonic emitters arranged to emit ultrasound waves in the conduit. The flow reactor may be used for desulphurization of fuel oil.

A CONTINUOUS FLOW PROCESS FOR THE SYNTHESIS OF METAL NANOWIRES USING BUBBLE COLUMN REACTOR
20220388062 · 2022-12-08 ·

A continuous flow process for the synthesis of metal nanowires using a bubble column reactor. Also disclosed are different types of multiphase bubble column reactors for synthesizing metal nanowires in high yields and purity through a continuous process. The continuous process provides tunability for the aspect ratio of the nanowires.

Reactor and process for producing alkyl (meth)acrylates

A novel process can be used for a heterogeneously catalysed oxidation reaction, in the presence of a pulverulent noble metal-containing catalyst, where (meth)acrolein, an alkyl alcohol, in particular methanol, and an oxygen-containing gas are converted to an alkyl (meth)acrylate, in particular methyl (meth)acrylate. A corresponding reactor suitable for performing the reaction is also useful. The process allows for an effective retention of the particulate catalyst and the continuous discharge of fines fractions of the catalyst powder which are present, particularly in a fresh catalyst batch as a consequence of its preparation. Such fines fractions may also be produced by abrasion during the reaction. The process allows for effective recycling, recovery, and utilization of these discharged catalyst fractions.

Reactor and process for producing alkyl methacrylates
20220380293 · 2022-12-01 · ·

A process produces methyl methacrylate by direct oxidative esterification of methacrolein. Methyl methacrylate is used in large amounts for producing polymers and copolymers with other polymerizable compounds. An optimized workup of the reactor discharge from the oxidative esterification of methacrolein allows for co-discharged fine catalyst particles to be very efficiently separated and optionally removed or recycled. In addition, this process can reduce the formation of byproducts in extended continuous operation compared to known variant. A reactor system contains stirrer configurations which allow virtually abrasion-free operation and thus a catalyst on-stream time of several years.