An installation for the conversion of uranium hexafluoride (UF.sub.6) to uranium dioxide (UO.sub.2) comprises a hydrolysis reactor (4) for the conversion of UF.sub.6 into uranium oxyfluoride powder (UO.sub.2F.sub.2), a pyrohydrolysis furnace (6) for converting the UO.sub.2F.sub.2 powder supplied by the reactor (4) into UO.sub.2 powder, a supply device (8) comprising reagent injection ducts (10) for the injection of UF.sub.6, water vapor or H.sub.2, and a control system (16) designed to control the supply device (8) so as to supply at least one of the reagent injection ducts (10) with a neutral gas during a shut-down or start-up phase of the conversion installation.

A reactor for performing a gas/liquid biphasic high-pressure reaction with a foaming medium, comprising an interior formed by a cylindrical, vertically oriented elongate shell, a bottom and a cap, wherein the interior is divided by internals into a backmixed zone and a zone of limited backmixing, wherein the backmixed zone and the zone of limited backmixing are consecutively traversable by the reaction mixture, wherein the backmixed zone comprises means for introducing gas and liquid and a gas outlet and also comprises at least one mixing apparatus selected from a stirrer, a jet nozzle and means for injecting the gas, and the zone of limited backmixing comprises a reaction product outlet, a first cylindrical internal element which in the interior extends in the longitudinal direction of the reactor and which delimits the zone of limited backmixing from the backmixed zone, backmixing-preventing second internal elements in the form of random packings, structured packings or liquid-permeable trays arranged in the zone of limited backmixing and a riser tube whose lower end is arranged within the backmixed zone and whose upper end opens into the zone of limited backmixing so that liquid from the backmixed zone can ascend into the zone of limited backmixing via the riser tube, wherein flow into the zone of limited backmixing enters from below. The reactor is configured such that the high-pressure reaction space is optimally utilized and contamination of workup steps or subsequent reactions arranged downstream of the high-pressure reaction with foam is substantially avoided. The invention further relates to a process for performing a continuous gas/liquid biphasic high-pressure reaction in the reactor.

A reactor for performing a gas/liquid biphasic high-pressure reaction with a foaming medium, comprising an interior formed by a cylindrical, vertically oriented elongate shell, a bottom and a cap, wherein the interior is divided by internals into a backmixed zone and a zone of limited backmixing, wherein the backmixed zone and the zone of limited backmixing are consecutively traversable by the reaction mixture, wherein the backmixed zone comprises means for introducing gas and liquid and a gas outlet and also comprises at least one mixing apparatus selected from a stirrer, a jet nozzle and means for injecting the gas, and the zone of limited backmixing comprises a reaction product outlet, a first cylindrical internal element which in the interior extends in the longitudinal direction of the reactor and which delimits the zone of limited backmixing from the backmixed zone, backmixing-preventing second internal elements in the form of random packings, structured packings or liquid-permeable trays arranged in the zone of limited backmixing and a riser tube whose lower end is arranged within the backmixed zone and whose upper end opens into the zone of limited backmixing so that liquid from the backmixed zone can ascend into the zone of limited backmixing via the riser tube, wherein flow into the zone of limited backmixing enters from below. The reactor is configured such that the high-pressure reaction space is optimally utilized and contamination of workup steps or subsequent reactions arranged downstream of the high-pressure reaction with foam is substantially avoided. The invention further relates to a process for performing a continuous gas/liquid biphasic high-pressure reaction in the reactor.

A gas nozzle (100), a gas reaction device (10) and a gas hydrolysis reaction method. A plurality of fuel gas channels (116) are provided on a side wall of a nozzle cavity (110) of the gas nozzle (100); the plurality of fuel gas channels (116) are arranged around the side wall of the nozzle cavity (110); a mixed gas introduced from a nozzle inlet (112) is surrounded by a fuel gas (21) introduced from the plurality of fuel gas channels (116); and the fuel gas channels (116) are inclined towards a nozzle outlet (114), and the fuel gas channels (116) are further inclined in the same clockwise direction. In this way, the fuel gas (21) introduced from the plurality of fuel gas channels (116) forms a downwardly conical spiral flame, and a flame formed by the mixed gas introduced from the nozzle inlet (112) is wrapped therein and sprayed out from the nozzle outlet (114).

A refractory-lined equipment includes a vessel defining an interior at least partially lined with a refractory material, and a nozzle assembly coupled to the vessel and extending into the interior. The nozzle assembly includes an outer sleeve fixed to the sidewall and extending through an aperture defined in the sidewall, the outer sleeve defining a central passageway, and a nozzle cartridge assembly positionable within the central passageway and including an inner sleeve, a refractory lining disposed about the inner sleeve, and a nozzle positioned within the inner sleeve. The nozzle cartridge assembly is removably coupled to the outer sleeve external to the vessel.

A refractory-lined equipment includes a vessel defining an interior at least partially lined with a refractory material, and a nozzle assembly coupled to the vessel and extending into the interior. The nozzle assembly includes an outer sleeve fixed to the sidewall and extending through an aperture defined in the sidewall, the outer sleeve defining a central passageway, and a nozzle cartridge assembly positionable within the central passageway and including an inner sleeve, a refractory lining disposed about the inner sleeve, and a nozzle positioned within the inner sleeve. The nozzle cartridge assembly is removably coupled to the outer sleeve external to the vessel.

An improved reactor comprising a shell and at least one reactor internal component. The reactor internal component includes a tube bundle comprising a plurality of tubes attached by at least one tube support plate comprising at least one radial strut and at least one bracket configured to secure to at least one tube of the tube bundle. The tubes are arranged in concentric bands about a longitudinal axis of the reactor. The reactor can also include a gas inlet plate, a catalyst support plate, and a top plate. The reactor shell can include a domed head portion with a startup nozzle connected to a reducing flange, providing a manhole access opening into the shell. Sliding strips that slide relative to the tube support plates can facilitate easier assembly, and support rings for the tubes adjacent the plates can accommodate variable thermal expansion of the tubes received in the plates.

An improved reactor comprising a shell and at least one reactor internal component. The reactor internal component includes a tube bundle comprising a plurality of tubes attached by at least one tube support plate comprising at least one radial strut and at least one bracket configured to secure to at least one tube of the tube bundle. The tubes are arranged in concentric bands about a longitudinal axis of the reactor. The reactor can also include a gas inlet plate, a catalyst support plate, and a top plate. The reactor shell can include a domed head portion with a startup nozzle connected to a reducing flange, providing a manhole access opening into the shell. Sliding strips that slide relative to the tube support plates can facilitate easier assembly, and support rings for the tubes adjacent the plates can accommodate variable thermal expansion of the tubes received in the plates.

In a general aspect, a system can include a reactor for combusting fuel and producing high-temperature, high-pressure liquid as a byproduct, and at least one vessel defining a cavity to be partially filled with water, with an air pocket within the cavity above the water. The system can further include respective valves to control admission of liquid from the reactor into the air pocket when the air pocket has a pressure lower than an operating pressure of the reactor, and to control emission of the water from the at least one vessel through of the vessel after the water in the at least one vessel has been pressurized by the liquid from the reactor. The system can also include a hydroelectric drive system for receiving water emitted from the cavity, and for converting energy in the received water into electrical energy.

A method for making a solid carbon material comprises: delivering a liquid comprising at least one liquid organic compound into a reaction region of a reactor; delivering a gas comprising at least one gaseous organic compound into the reaction region of the reactor; and inducing a chemical reaction between the at least one liquid organic compound and the at least one gaseous organic compound, wherein: the chemical reaction occurs in the reaction region of the reactor; the solid carbon material is made via the reaction; the solid carbon material is made during the reaction in the form of a dispersion comprising the solid carbon material dispersed in the liquid; and the chemical reaction is a homogeneous reaction comprising homogeneous nucleation of the solid carbon material in the reaction region of the reactor.