Two-part condensation curable silyl-modified polymer (SMP) based sealant compositions, in particular two-part condensation curable SMP based translucent sealant compositions containing a catalyst comprising (i) a titanate and/or zirconate and (ii) a metal carboxylate salt.

A cerium-zirconium based mixed oxide composition have: (a) a Ce:Zr molar ratio of 1 or less, and (b) a cerium oxide content of 10-50% by weight. The composition has (i) a surface area of at least 18 m.sup.2/g, and a total pore volume as measured by N.sub.2 physisorption of at least 0.11 cm.sup.3/g, after ageing at 1100° C. in an air atmosphere for 6 hours, (ii) a surface area of at least 42 m.sup.2/g, and a total pore volume as measured by N.sub.2 physisorption of at least 0.31 cm.sup.3/g, after ageing at 1000° C. in an air atmosphere for 4 hours, and (iii) Dynamic Oxygen Storage Capacity (D-OSC) value as measured by H.sub.2-TIR of greater than 500 μmol/g at 600° C. after aging at 800° C. in an air atmosphere for 2 hours. A process contacts the exhaust gas with the composition Another process is for preparing the composition.

The invention provides a polycondensation catalyst for producing polyester by an esterification reaction or a transesterification reaction of a dicarboxylic acid or an ester-forming derivative thereof and a glycol, wherein the polycondensation catalyst comprises particles of a water-insoluble or hardly water-soluble phosphate having on the surfaces a coating layer of titanic acid in an amount, of 0.1 to 100 parts by weight in terms of TiO.sub.2 per 100 parts by weight of the phosphate.

A high surface area to mass catalyst is formed by a method that includes a Kirigami mapped cutting of a flat three metal laminate composite formed on a deposition support. Kirigami derived catalyst has a shape that provides a high surface to mass ratio and promotes the flow of a fluid containing a reagent for a reaction catalyzed by the exterior metal catalyst films of the three metal laminate composite. Structural integrity of the Kirigami derived catalyst results from a support metal film residing between two metal catalyst films. The shaping to the Kirigami derived structure involves cutting the flat three metal laminate composite to that of a Kirigami map, imposing stress on the cut structure to force a non-planar deformation, and delaminating the Kirigami derived catalyst from the deposition support.

Provided are a catalyst structure for ozone decomposition including a support containing a porous inorganic material, and an α-MnO.sub.2 catalyst located on at least a portion of inner pores and a surface of the support, an air-cleaning method using the same, and an air-cleaning device and an air-cleaning system each including the catalyst structure for ozone decomposition.

Monodisperse polystyrene microspheres are self-assembled on a conductive surface of FTO glass by vertical deposition method to prepare three-dimensional ordered photonic crystal opal template; the three-dimensional ordered photonic crystal opal template is immersed in a solution containing rhodium source, titanium source and strontium source, and is then calcined to prepare a rhodium doped strontium titanate inverse opal material; and the rhodium doped strontium titanate inverse opal material is added to water containing pollutants, and is then subjected to illumination and/or ultrasonic treatment to complete the removal of the pollutants in the water. The three-dimensional ordered macroporous rhodium doped strontium titanate inverse opal material may be applied in the field of photocatalysis. Under the action of external force, a built-in electric field formed by the spontaneous polarization of the material may effectively separate the photo-induced carriers, which may thus enhance the photocatalytic performance and improve the photocatalytic efficiency.

This application relates to a photoactive product comprising: a catechol-containing compound, an amine-containing polymer, and photoactive material. The photoactive product can act as a photocatalyst and can be used in photoelectrodes for use in, for example, photoelectrochemical analyte sensing, including biosensing. The photoelectrodes modified with hybrid organic/inorganic materials can provide increased light absorption and charge separation, binding sites for attaching biorecognition probes, and built-in film-forming properties for well-adhered and uniform photoactive frameworks on the collector electrodes.

Disclosed are methods of dehydrogenating a light alkane gas (and/or light alkene gas), which include adding hydrogen (H.sub.2) to the light alkane gas (and/or light alkene gas) in the presence of a catalyst composition containing zirconium oxide. Also disclosed are catalyst compositions containing zirconium oxide and methods of preparation thereof, where the catalyst compositions are useful in methods of dehydrogenating light alkane gas.

Provided is halloysite powder including a granule in which halloysite including halloysite nanotubes and titanium oxide are aggregated. The granule includes a first pore derived from a tube hole of the halloysite nanotubes, and a second pore different from the first pore.

A process for ring hydrogenation of dialkyl terephthalates having C.sub.3- to C.sub.16-alkyl groups can be performed in a hydrogenation unit composed of two reaction units in series. In the process, a suitable process parameter in relation to the first reaction unit is adjusted so that a certain reaction conversion is achieved.