Embodiments are directed to adamantane-intercalated layered double-hydroxide (LDH) particles and the methods of producing adamantane-intercalated LDH particles. The method comprises adding to an aqueous solution a first precursor and a second precursor to form an initial mixture, where the first precursor is Al(OH).sub.3 or Al.sub.2O.sub.3, the second precursor is a hydroxide M(OH).sub.2 or an oxide MO, where M is a metal of oxidation state +2; and the initial mixture has a M/Al molar ratio of from 1 to 5. The method also comprises adding to the initial mixture an amount of adamantane to form a reaction mixture having an Al/adamantane molar ratio of from 0.5 to 2; and heating the reaction mixture to produce adamantane-intercalated LDH particles, where the adamantane-intercalated LDH particles have aspect ratios greater than 100.

The present invention relates to a catalyst for the removal of carbon monoxide and hydrocarbon from the exhaust gas of lean-operated internal combustion engines on a supporting body, which bears platinum and/or palladium on one or more refractory carrier materials and also contains cerium oxide and which, after reductive treatment at 250° C. and after CO adsorption, is characterized by certain peaks in Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS), and also relates to the use thereof for removing carbon monoxide and hydrocarbon from the exhaust gas of lean-operated internal combustion engines.

An exhaust gas purification system of the present disclosure includes a first exhaust gas purification device that purifies exhaust gas discharged from an internal combustion engine and a second exhaust gas purification device that additionally purifies the exhaust gas purified by the first exhaust gas purification device, wherein the exhaust gas is exhaust gas with a gaseous composition in which an amount of reducing agents is in excess compared to a stoichiometric gaseous composition and a gaseous composition in which an amount of oxidants is in excess compared to the stoichiometric gaseous composition are alternately switched between, the first exhaust gas purification device includes a three-way catalyst, and the second exhaust gas purification device includes an exhaust gas purification catalyst containing spinel-type MgAl.sub.xFe.sub.2.00−xO.sub.4.00 supporting particles on which Rh is supported, where 0.00<×≤1.50.

A heterogeneous catalyst comprising a support and a noble metal. The catalyst has an average diameter of at least 200 microns and at least 90 wt % of the noble metal is in the outer 50% of catalyst volume.

The present disclosure relates to ruthenium promoter catalyst compositions. The ruthenium promoter catalyst compositions comprise ruthenium metal species, an oxide support material, and a promoter species independently selected from the group consisting of La, Rb, Y, Yb, K, Cs, and Ba, or hydroxides, nitrates or oxides thereof. The present disclosure also relates to various methods, processes, systems, membranes and/or reactors, which can utilise the ruthenium promoter catalyst compositions, for example in ammonia synthesis.

The present disclosure relates to ruthenium promoter catalyst compositions. The ruthenium promoter catalyst compositions comprise ruthenium metal species, an oxide support material, and a promoter species independently selected from the group consisting of La, Rb, Y, Yb, K, Cs, and Ba, or hydroxides, nitrates or oxides thereof. The present disclosure also relates to various methods, processes, systems, membranes and/or reactors, which can utilise the ruthenium promoter catalyst compositions, for example in ammonia synthesis.

The present invention relates to a catalyst for dehydration of a primary alcohol, a method of preparing the same, and a method of producing an alpha-olefin using the same. The catalyst for dehydration of a primary alcohol according to the present invention has an excellent catalyst stability while having an excellent activity with respect to dehydration, and a high turnover frequency, such that a linear alpha-olefin with high purity may be produced with a high selectivity even in a case where a relatively small amount of a cocatalyst is added as compared with a homogeneous catalyst system.

The present invention relates to a catalyst for dehydration of a primary alcohol, a method of preparing the same, and a method of producing an alpha-olefin using the same. The catalyst for dehydration of a primary alcohol according to the present invention has an excellent catalyst stability while having an excellent activity with respect to dehydration, and a high turnover frequency, such that a linear alpha-olefin with high purity may be produced with a high selectivity even in a case where a relatively small amount of a cocatalyst is added as compared with a homogeneous catalyst system.

A nanohybrid includes: reduced graphene oxide (rGO); zinc ferrite (ZnFe.sub.2O.sub.4) nanoparticles dispersed in the rGO; and manganese dioxide (MnO.sub.2) nanoflakes three-dimensionally attached on the rGO. The nanohybrid reduces recombination of graphene through the synergistic effects of MnO.sub.2 nanoflakes, ZnFe.sub.2O.sub.4 nanoparticles, and graphene, and increases the surface area of the catalyst, thus being capable of exhibiting higher catalytic activity than the conventional δ-MnO.sub.2@ZnFe.sub.2O.sub.4, γ-MnO.sub.2@rGO, and ZnFe.sub.2O.sub.4@rGO composites in the decomposition of harmful organic waste.

A nanohybrid includes: reduced graphene oxide (rGO); zinc ferrite (ZnFe.sub.2O.sub.4) nanoparticles dispersed in the rGO; and manganese dioxide (MnO.sub.2) nanoflakes three-dimensionally attached on the rGO. The nanohybrid reduces recombination of graphene through the synergistic effects of MnO.sub.2 nanoflakes, ZnFe.sub.2O.sub.4 nanoparticles, and graphene, and increases the surface area of the catalyst, thus being capable of exhibiting higher catalytic activity than the conventional δ-MnO.sub.2@ZnFe.sub.2O.sub.4, γ-MnO.sub.2@rGO, and ZnFe.sub.2O.sub.4@rGO composites in the decomposition of harmful organic waste.