Patent classifications
B01J21/10
PREPARATION METHOD FOR CYCLOHEXANE DIMETHANOL HAVING HIGH TRANS CONTENT AND CYCLOHEXANE DIMETHANOL PREPARED THEREBY
Provided is a preparation method for a cyclohexane dimethanol (CHDM), which can have a high trans content through particular conditions, additive addition, or reactant addition, which is controlled in a cyclohexane dicarboxylic acid (CHDA) hydrogenation reaction, and a cyclohexane dimethanol prepared thereby.
METHOD FOR PRODUCING INDENE
The present invention provides a production method for indene, comprising a dehydrogenation step of obtaining a reaction product containing indene by contacting a raw material composition containing indene with a dehydrogenation catalyst, wherein the dehydrogenation catalyst comprises a support containing aluminum, and a group 14 metal element and platinum supported on the support, a content of the platinum in the dehydrogenation catalyst is 0.6 to 2.5% by mass based on a whole amount of the dehydrogenation catalyst, and an atomic ratio of the group 14 metal element to the platinum in the dehydrogenation catalyst is 4.0 to 20.0.
METHOD FOR PRODUCING INDENE
The present invention provides a production method for indene, comprising a dehydrogenation step of obtaining a reaction product containing indene by contacting a raw material composition containing indene with a dehydrogenation catalyst, wherein the dehydrogenation catalyst comprises a support containing aluminum, and a group 14 metal element and platinum supported on the support, a content of the platinum in the dehydrogenation catalyst is 0.6 to 2.5% by mass based on a whole amount of the dehydrogenation catalyst, and an atomic ratio of the group 14 metal element to the platinum in the dehydrogenation catalyst is 4.0 to 20.0.
Calcium salts-supported metal catalyst, method for preparing the same, and method for hydrodeoxygenation reaction of oxygenates using the same
Disclosed herein are a calcium salts-supported metal catalyst, a method for preparing the same, and a method for the hydrodeoxygenation reaction of oxygenates using the same. The catalyst, in which a metal catalyst is supported on a carrier of a calcium salt, for example, calcium carbonate, has the effect of increasing the efficiency of hydrodeoxygenation reaction of oxygenates.
PDO OR BMTZ LIGAND FOR SUPPORTED COORDINATED PT HYDROSILYLATION CATALYSTS
The invention describes single-site metal catalysts such as Pt single-site centers on powdered oxide supports with a 1,10-phenanthroline-5,6-dione (PDO) or bis-pyrimidyltetrazine (BMTZ) ligand on powdered MgO, Al.sub.2O.sub.3, or CeO.sub.2.
Nanostructured Carbons and Methods of Preparing the Same
The inventive concept described herein relates to nanostructured carbons having improved characteristics, and method of preparing the same.
Self-disinfecting photocatalyst sheet with primer
A self-disinfecting photocatalyst sheet includes a substrate material and a photocatalyst layer with a primary photocatalyst and a secondary photocatalyst. The primary photocatalyst is a metal oxide photocatalyst, whereas the secondary photocatalyst is a metallic photocatalyst. The substrate material binds the photocatalyst layer by either connecting a metal ion of the primary photocatalyst and/or the secondary photocatalyst through two oxygen atoms of a carboxyl group (COO), or by forming hydrogen bonds between a carbonyl group and a surface hydroxyl group (OH.sup.) of the primary photocatalyst. The self-disinfecting photocatalyst sheet is activatable by a visible light and can self-disinfect against bacteria and viruses.
CATALYSTS, SYSTEMS, AND PROCESSES FOR REGULATING A CONTACTING STATE IN PRODUCING LIGHT OLEFINS FROM PARAFFINS
The present invention relates to catalysts, catalyst systems, and processes for the production of valuable light olefins, such as ethylene, from paraffinic hydrocarbons, such as propane, through dehydrogenation and metathesis. The contacting state between dehydrogenation and metathesis catalysts can advantageously be manipulated using an inert or relatively inert coating or outer shell that provides a degree of physical separation between catalytically active centers or inner cores. This has been discovered to significantly increase olefin selectivity (i.e., reduce undesired hydrogenation/hydrogenolysis side reactions) without an appreciable paraffin conversion deficit, such that the overall yield of desired olefinic hydrocarbons such as ethylene is thereby significantly increased.
Gold-based catalyst for oxidative esterification of aldehydes to carboxylic acid esters
The present invention relates to novel catalysts for oxidative esterification, by means of which, for example, (meth)acrolein can be converted to methyl (meth)acrylate. The catalysts of the invention are especially notable for high mechanical and chemical stability even over very long periods. This especially relates to an improvement in the catalyst service life, activity and selectivity over prior art catalysts which lose activity and/or selectivity relatively quickly in continuous operation in media having even a small water content.
Gold-based catalyst for oxidative esterification of aldehydes to carboxylic acid esters
The present invention relates to novel catalysts for oxidative esterification, by means of which, for example, (meth)acrolein can be converted to methyl (meth)acrylate. The catalysts of the invention are especially notable for high mechanical and chemical stability even over very long periods. This especially relates to an improvement in the catalyst service life, activity and selectivity over prior art catalysts which lose activity and/or selectivity relatively quickly in continuous operation in media having even a small water content.