The present invention relates to an oxygen carrier solid in particulate form, to the preparation thereof and to the use thereof in a chemical looping redox process such as chemical looping combustion (CLC). The oxygen carrier solid comprises, in the oxidized form thereof, an Fe content X of between 5% and 39.3%, an Mg content Y of between 3% and 21.5%, and an Al content Z of between 57% and 92%, the contents X, Y and Z being expressed respectively as % by weight of Fe.sub.2O.sub.3, MgO and Al.sub.2O.sub.3 relative to the total weight of the oxygen carrier solid, with X+Y+Z=100% and with Y28.33-0.645X. The carrier comprises an active redox mass comprising Fe.sub.2O.sub.3, and a ceramic matrix within which said active redox mass is dispersed, said ceramic matrix comprising a sub-stoichiometric spinel of formula Mg.sub.aAl.sub.bO.sub.4.

The present invention relates to an oxygen carrier solid in particulate form, to the preparation thereof and to the use thereof in a chemical looping redox process such as chemical looping combustion (CLC). The oxygen carrier solid comprises, in the oxidized form thereof, an Fe content X of between 5% and 39.3%, an Mg content Y of between 3% and 21.5%, and an Al content Z of between 57% and 92%, the contents X, Y and Z being expressed respectively as % by weight of Fe.sub.2O.sub.3, MgO and Al.sub.2O.sub.3 relative to the total weight of the oxygen carrier solid, with X+Y+Z=100% and with Y28.33-0.645X. The carrier comprises an active redox mass comprising Fe.sub.2O.sub.3, and a ceramic matrix within which said active redox mass is dispersed, said ceramic matrix comprising a sub-stoichiometric spinel of formula Mg.sub.aAl.sub.bO.sub.4.

A process and apparatus for manufacture of oxide products for use as biocide, chemical detoxifying, and catalytic support products, from caustic calcined carbonate powder, preferably from magnesite, dolomite, or hydromagnesite, is described. These oxide particles are characterized by high surface area, high porosity and a high degree of calcination, and the method of manufacture of utilizes an indirectly heated counterflow reactor. The oxides may be used as a powder, granules, or formulated into a slurry and used as a spray, emulsion, foam or fog, or the powder product may be directly applied. Also described is the formation of particles with microstructures defined by at least one nano-crystalline structure positioned on the outer surface of the particles.

A process and apparatus for manufacture of oxide products for use as biocide, chemical detoxifying, and catalytic support products, from caustic calcined carbonate powder, preferably from magnesite, dolomite, or hydromagnesite, is described. These oxide particles are characterized by high surface area, high porosity and a high degree of calcination, and the method of manufacture of utilizes an indirectly heated counterflow reactor. The oxides may be used as a powder, granules, or formulated into a slurry and used as a spray, emulsion, foam or fog, or the powder product may be directly applied. Also described is the formation of particles with microstructures defined by at least one nano-crystalline structure positioned on the outer surface of the particles.

Disclosed is a catalyst for production of multi-walled carbon nanotubes, in which the catalyst includes a transition metal catalyst supported on a support mixture including MgO, and thus can increase the production of multi-walled carbon nanotubes and, at the same time, reduce the number of walls of the multi-walled carbon nanotubes to thereby reduce the surface resistance of the multi-walled carbon nanotubes. Also disclosed is a method of producing multi-walled carbon nanotubes using the catalyst. The catalyst for production of multi-walled carbon nanotubes includes: a support mixture of a first support and a second support mixed with the first support; and a transition metal catalyst supported on the support mixture.

Disclosed is a catalyst for production of multi-walled carbon nanotubes, in which the catalyst includes a transition metal catalyst supported on a support mixture including MgO, and thus can increase the production of multi-walled carbon nanotubes and, at the same time, reduce the number of walls of the multi-walled carbon nanotubes to thereby reduce the surface resistance of the multi-walled carbon nanotubes. Also disclosed is a method of producing multi-walled carbon nanotubes using the catalyst. The catalyst for production of multi-walled carbon nanotubes includes: a support mixture of a first support and a second support mixed with the first support; and a transition metal catalyst supported on the support mixture.

Processes for preparing supported gold nanoparticle catalysts are provided. In an exemplary embodiment, the process includes adding a solution of a phosphorus compound to a solution of chloro (dimethyl sulfide) gold (I) to obtain a solution of chloro (phosphorus compound) gold (I) complex, adding the solution of chloro (phosphorus compound) gold (I) complex to a solution of silver nitrate to obtain a solution of nitro (phosphorus compound) gold (I) complex, applying the solution of nitro (phosphorus compound) gold (I) complex to a metal hydroxide support, drying the metal hydroxide support; and calcining the dried metal hydroxide support to form the supported gold nanoparticle catalyst. Supported gold nanoparticle catalysts prepared by the process and processes for oxidizing ethylene to ethylene oxide in the presence of the supported gold nanoparticle catalysts are also provided.

Processes for preparing supported gold nanoparticle catalysts are provided. In an exemplary embodiment, the process includes adding a solution of a phosphorus compound to a solution of chloro (dimethyl sulfide) gold (I) to obtain a solution of chloro (phosphorus compound) gold (I) complex, adding the solution of chloro (phosphorus compound) gold (I) complex to a solution of silver nitrate to obtain a solution of nitro (phosphorus compound) gold (I) complex, applying the solution of nitro (phosphorus compound) gold (I) complex to a metal hydroxide support, drying the metal hydroxide support; and calcining the dried metal hydroxide support to form the supported gold nanoparticle catalyst. Supported gold nanoparticle catalysts prepared by the process and processes for oxidizing ethylene to ethylene oxide in the presence of the supported gold nanoparticle catalysts are also provided.

A catalyst is provided. The catalyst includes a carrier and a metal Pd. The carrier is represented by a formula: M.sub.xAl.sub.(1x)O.sub.(3x)/2, where M is an alkaline earth metal, and x is between 0.09 and 0.24. The metal Pd is loaded on the carrier. A method for manufacturing the catalyst and a method for manufacturing a hydrogenated bisphenol A or derivatives thereof using the catalyst are also provided.

A water treatment composition for treating organic wastewater is provided. The water treatment composition includes a bulk catalytic material and an oxidant. The bulk catalytic material includes iron atoms or ions, manganese atoms or ions, and magnesium atoms or ions.