Patent classifications
B01J23/002
Cored round trilobe shaped catalyst for producing maleic anhydride
The present disclosure provides an improved shaped catalyst containing catalytic material comprised of mixed oxides of vanadium and phosphorus and using such shaped catalysts for the production of maleic anhydride.
CHEMICAL HOMOGENEITY AND CATALYTIC PERFORMANCE OF MIXED-METAL OXIDE CATALYSTS
A method for preparing a mixed-metal oxide catalyst comprising molybdenum, vanadium, at least one of niobium or tantalum, and at least one of tellurium or antimony and useful for the oxidative dehydrogenation of ethane to ethylene, the method comprising preparing a catalyst precursor, pressing the precursor into a dense pellet using a pressure of greater than about 5,000 psi, and annealing the pellet to form the mixed-metal oxide catalyst.
Catalyst for ethane ODH
A catalyst for oxidative dehydrogenation (ODH) of ethane with an empirical formula Mo—V—Te—Nb—Pd—O produced using a process comprising impregnation of the Pd component on the surface of the catalyst following a calcination step using a Pd compound free of halogens. The resulting catalyst can be used in both diluted and undiluted ODH processes and shows higher than expected activity without any loss of selectivity.
Supported perovskite-oxide composites for enhanced low temperature thermochemical conversion of CO.SUB.2 .to CO
Disclosed herein is a catalyst composite containing a perovskite-oxide and an oxide support, methods of preparing a catalyst composite containing a perovskite-oxide and an oxide support, and the use thereof for CO.sub.2 conversion by a reverse water gas shift chemical looping (RWGS-CL) process.
Cu.SUB.y./MMgO.SUB.x .interfacial catalyst for selective alkyne hydrogenation and its preparation method
Cu.sub.y/MMgO.sub.x interfacial catalyst for selective alkyne hydrogenation and its preparation method are disclosed. The preparation method of the catalyst includes: the mixture of salt and alkali solution is nucleated momentarily by nucleation/crystallization isolation method, preparing the composite metal hydroxide Cu.sub.yMMg.sub.4-LDHs as precursor, which has typical hexagonal morphology of the double hydroxide; the precursor is topologically transformed by heat treatment to produce unsaturated oxide; the catalyst with Cu.sub.y-MMgO.sub.x interface structure is prepared by separating and electronically modifying Cu particles. By adjusting the ratio of Cu.sup.2+/M.sup.3+ in LDHs, the electronic and geometric structure of Cu.sub.y-MMgO.sub.x interface can be flexibly controlled, thus enhancing the reaction activity, product selectivity and stability. The catalyst can be used in the selective hydrogenation of various alkynes in the fields of petrochemical and fine chemical industry, with the outstanding catalytic activity and C═C double bond selectivity. The catalyst also has good reusability.
Mixed oxide catalyst for oxygen storage applications and a method for making the catalyst
Catalyst material composed of a sodium incorporated cerium-zirconium based mixed oxide catalyst material, such as Ce—Zr/Al.sub.2O.sub.3, for oxygen storage capacity applications. The sodium incorporated cerium-zirconium based mixed oxide catalyst material is synthesized by co-precipitation techniques using sodium carbonate as the precipitating agent and exhibits a high oxygen storage capacity.
SUSPENSION OF NANOPARTICLES OF A MIXED OXIDE
The present invention relates to a suspension of nanoparticles of a mixed oxide based on cerium and zirconium. It also relates to the use of said suspension for the preparation of a catalysed gasoline particulate filter.
DEHYDROGENATION CATALYST FOR PRODUCING OLEFINS FROM ALKANE GAS AND PREPARATION METHOD THEREOF
A dehydrogenation catalyst for producing olefins from alkane gases, in which cobalt and zinc are supported on alumina. A method for preparing the dehydrogenation catalyst for producing olefins from alkane gases, includes: preparing a mixed solution by mixing cobalt and zinc precursors with water; preparing a supported catalyst by impregnating alumina with the mixed solution; drying the supported catalyst; and calcining the dried supported catalyst at 500° C. to 900° C.
METHOD FOR PRODUCING ACRYLIC ACID
A method includes supplying a gas containing acrolein to a fixed bed reactor including a reaction tube to produce acrylic acid by vapor phase catalytic oxidation of acrolein. The reaction tube is packed with catalysts having different activities in such a way that catalyst layers are formed in a tube axis direction. A catalyst X having the highest activity among the catalysts contained in all the catalyst layers is placed in the whole or a part of a section up to 30% of a length of all the catalyst layers from a rearmost portion on a gas outlet side toward a gas inlet side. A catalytically active component x in the catalyst X has Mo, V, and optionally Cu. When Cu is included, its amount is 0.8 mol or less per 12 mol of Mo. A specific surface area of the catalytically active component x is 15-40 m.sup.2/g.
Bifunctional Metal Oxides And Paraffin Isomerization Therewith
Tungstated zirconium catalysts for paraffin isomerization may comprise: a mixed metal oxide that is at least partially crystalline and comprises tungsten, zirconium, and a variable oxidation state metal selected from Fe, Mn, Co, Cu, Ce, Ni, and any combination thereof. The mixed metal oxide comprises about 5 wt. % to about 25 wt. % tungsten, about 40 wt. % to about 70 wt. % zirconium, and about 0.01 wt. % to about 5 wt. % variable oxidation state metal, each based on a total mass of the mixed metal oxide. The mixed metal oxide has a total surface area of about 50 m.sup.2/g or greater as measured according to ISO 9277, and at least one of the following: an ammonia uptake of about 0.05 to about 0.3 mmol/g as measured by temperature programmed adsorption/desorption, or a collidine uptake of about 100 μmol/g or greater as measured gravimetrically.