Disclosed are a catalyst used for converting carbon dioxide to methanol by hydrogenation and a method preparing the sane. The caratlys may include: a mesoporous indium oxide; and a catalyst supported on the mesoporous indium oxide. Preferably, a porous structure of the mesoporous indium oxide may have Ia3d symmetry and may include mesopores and micropores interconnecting the mesopores.

Disclosed are a catalyst used for converting carbon dioxide to methanol by hydrogenation and a method preparing the sane. The caratlys may include: a mesoporous indium oxide; and a catalyst supported on the mesoporous indium oxide. Preferably, a porous structure of the mesoporous indium oxide may have Ia3d symmetry and may include mesopores and micropores interconnecting the mesopores.

A catalyst for preparing light olefin using direct conversion of syngas is a composite catalyst and formed by compounding component I and component II in a mechanical mixing mode. The active ingredient of component I is a metal oxide; and the component II is one or more than one of zeolite of CHA and AEI structures or metal modified CHA and/or AEI zeolite. A weight ratio of the active ingredients in the component I to the component II is 0.1-20. The reaction process has high product yield and selectivity, wherein the sum of the selectivity of the propylene and butylene reaches 40-75%; and the sum of the selectivity of light olefin comprising ethylene, propylene and butylene can reach 50-90%. Meanwhile, the selectivity of a methane side product is less than 15%.

A catalyst for preparing light olefin using direct conversion of syngas is a composite catalyst and formed by compounding component I and component II in a mechanical mixing mode. The active ingredient of component I is a metal oxide; and the component II is one or more than one of zeolite of CHA and AEI structures or metal modified CHA and/or AEI zeolite. A weight ratio of the active ingredients in the component I to the component II is 0.1-20. The reaction process has high product yield and selectivity, wherein the sum of the selectivity of the propylene and butylene reaches 40-75%; and the sum of the selectivity of light olefin comprising ethylene, propylene and butylene can reach 50-90%. Meanwhile, the selectivity of a methane side product is less than 15%.

A method for producing plasmonic nanomaterials that are catalytically or photocatalytically active by fabricating plasmonic nanostructures on substrates using electrodeposition into a nano-template structure and forming a plurality of nanorods in an array, wherein the nanorods are made from materials chosen from the group consisting of materials that are plasmonic and/or catalytic, and materials that are catalytically activated by depositing pure elemental metals, alloys, or alternating layers of different metals or alloys, and producing catalytic plasmonic nanomaterials. Catalytic plasmonic nanomaterials made from the above method. An optical reactor device that utilizes catalytic nanomaterials for photocatalytic synthesis of methanol or ammonia. A method of photocatalytic synthesis of methanol and ammonia by using catalytic plasmonic nanomaterial to convert CO.sub.2 and H.sub.2 to methanol and N.sub.2 and H.sub.2 to ammonia using optical power. A hybrid plasma-plasmonic reactor for the utilization of CO.sub.2 and CH.sub.4 to produce methanol, ethylene, and acetic acid.

An organic base modified composite catalyst for producing ethylene by hydrogenation of carbon monoxide is a composite catalyst and formed by compounding component I and component II in a mechanical mixing mode. The active ingredient of the component I is a metal oxide; the component II is an organic base modified zeolite of MOR topology; and a weight ratio of the active ingredients in the component I to the component II is 0.1-20, and preferably 0.3-8. The reaction process has an extremely high product yield and selectivity. The selectivity of C.sub.2-C.sub.3 olefins is as high as 78-87%; the selectivity of hydrocarbon products with more than 4 C atoms is less than 10%; the selectivity of a methane side product is extremely low (<9%); and meanwhile, the selectivity of the ethylene is 75-82%.

A heterojunction composite material consisting of one-dimensional In.sub.2O.sub.3 hollow nanotube and two-dimensional ZnFe.sub.2O.sub.4 nanosheets and its application are disclosed. When using this material for catalytic reactions, the hollow cavity and two-dimensional nanosheets of hollow nanomaterials can not only reduce the migration distance to accelerate the electron-hole separation, but also provide a large surface area and rich active sites to promote pollution adsorption and surface catalysis. At the same time, multiple light scattering or reflection in the hollow cavity of the hollow nanomaterials can increase light absorption and utilization. In addition, the heterojunction photocatalyst constructed by growing two-dimensional semiconductor nanosheets on a tubular substrate can promote the effective separation of photogenerated electrons and photogenerated holes, thereby improving the catalytic efficiency. In terms of catalytic performance, In.sub.2O.sub.3 @ ZnFe.sub.2O.sub.4 shows effective degradation of tetracycline, and due to its ferromagnetism, it shows convenient and good separation effect and has good recycling performance.

The present invention discloses photostable composite of indium gallium nitride and zinc oxide for solar water splitting, comprising Indium content in the range of 1-40 wt %, Ga content in the range of 1 to 15 wt %, nitrogen content in the range of 0.1 to 5 wt %, and the remaining is ZnO. The combustion synthesis comprises the steps of: (a) dissolving 45 to 55 wt % urea, 75 to 80 wt % Zinc nitrate, 3 to 5 wt % Gallium nitrate, and 15 to 20 wt % Indium nitrate in water with stirring until a homogenous solution is formed; and (b) heating the homogenous solution of step (a) at a temperature in the range of 450-550 [deg.]C. for period in the range of 2 to 20 min to obtain the photostable composite.

The present invention discloses photostable composite of indium gallium nitride and zinc oxide for solar water splitting, comprising Indium content in the range of 1-40 wt %, Ga content in the range of 1 to 15 wt %, nitrogen content in the range of 0.1 to 5 wt %, and the remaining is ZnO. The combustion synthesis comprises the steps of: (a) dissolving 45 to 55 wt % urea, 75 to 80 wt % Zinc nitrate, 3 to 5 wt % Gallium nitrate, and 15 to 20 wt % Indium nitrate in water with stirring until a homogenous solution is formed; and (b) heating the homogenous solution of step (a) at a temperature in the range of 450-550 [deg.]C. for period in the range of 2 to 20 min to obtain the photostable composite.

According to one or more embodiments described herein, a method for dehydrogenating hydrocarbons may include passing a hydrocarbon feed comprising one or more alkanes or alkyl aromatics into a fluidized bed reactor, contacting the hydrocarbon feed with a dehydrogenation catalyst in the fluidized bed reactor to produce a dehydrogenated product and hydrogen, and contacting the hydrogen with an oxygen-rich oxygen carrier material in the fluidized bed reactor to combust the hydrogen and form an oxygen-diminished oxygen carrier material. In additional embodiments, a dual-purpose material may be utilized which has dehydrogenation catalyst and oxygen carrying functionality.