Patent classifications
B01J23/38
ONE-POT PROCESS USING HETEROGENEOUS CATALYST
The present invention relates to a process for the one-pot hydrogenation and dehydration or isomerization of an organic compound, and to a catalyst composition for this process comprising transition metal particles having particle size below 50 nm supported on a material comprising at least one fluorinated polymer (P), wherein polymer (P) bears —SO.sub.2X functional groups, X being selected from X′ and OM, X′ being selected from the groups consisting of F, Cl, Br and I; and M being selected from the group consisting of H, and alkaline metal and NH.sub.4.
Bimetallic catalyst for high nitrate nitrogen reduction and selectivity and manufacturing methods thereof
In a method of manufacturing a bimetallic catalyst for reductively decomposing nitrate nitrogen, a powder including a trivalent iron oxide, a powder including a trivalent iron oxyhydroxide powder or a combination thereof is mixed in an aqueous solution. A copper precursor and a palladium precursor are mixed in the aqueous solution to form a precursor mixture. The precursor mixture is dried. The dried precursor mixture is fired at a temperature from about 300° C. to about 450° C. to form a fired product. The fired product is reduced by a reducing agent. A hydrochloric acid solution is mixed in the aqueous solution, or mixed with the copper precursor or the palladium precursor.
Bimetallic catalyst for high nitrate nitrogen reduction and selectivity and manufacturing methods thereof
In a method of manufacturing a bimetallic catalyst for reductively decomposing nitrate nitrogen, a powder including a trivalent iron oxide, a powder including a trivalent iron oxyhydroxide powder or a combination thereof is mixed in an aqueous solution. A copper precursor and a palladium precursor are mixed in the aqueous solution to form a precursor mixture. The precursor mixture is dried. The dried precursor mixture is fired at a temperature from about 300° C. to about 450° C. to form a fired product. The fired product is reduced by a reducing agent. A hydrochloric acid solution is mixed in the aqueous solution, or mixed with the copper precursor or the palladium precursor.
Catalysts for the reduction of ammonia emission from rich-burn exhaust
A system for reducing ammonia (NH.sub.3) emissions includes (a) a first component comprising a first substrate containing a three-way catalyst, wherein the first component is disposed upstream of a second component comprising a second substrate containing an ammonia oxidation catalyst, wherein said ammonia oxidation catalyst comprises a small pore molecular sieve supporting at least one transition metal; and (b) an oxygen-containing gas input disposed between the components. For example, a CHA Framework Type small pore molecular sieve may be used. A method for reducing NH.sub.3 emission includes introducing an oxygen-containing gas into a gas stream to produce an oxygenated gas stream; and exposing the oxygenated gas stream to an NH.sub.3 oxidation catalyst to selectively oxidize at least a portion of the NH.sub.3 to N.sub.2. The method may further include the step of exposing a rich burn exhaust gas to a three-way catalyst to produce the gas stream comprising NH.sub.3.
Catalyst having a three-dimensional dent structure in the form of a hexagon
A catalyst includes a gas-permeable textile sheet material made of noble-metal-containing wire having a three-dimensional secondary structure produced thereon. The secondary structure is a three-dimensional dent structure including dents arranged adjacent to each other in rows in two spatial directions. The dents are in the form of a hexagon. The dent structure is formed by self-organization in a denting process.
DIESEL REFORMING APPARATUS HAVING A HEAT EXCHANGER FOR HIGHER EFFICIENCY STEAM REFORMING FOR SOLID OXIDE FUEL CELLS (SOFC)
Embodiments of the present disclosure are directed to a diesel reformer system comprising: a diesel autothermal reforming unit; a post-reforming unit disposed downstream of the autothermal reforming unit; a heat exchanger disposed downstream of the post-reforming unit; and a desulfurization unit disposed downstream of the heat exchanger.
DIESEL REFORMING APPARATUS HAVING A HEAT EXCHANGER FOR HIGHER EFFICIENCY STEAM REFORMING FOR SOLID OXIDE FUEL CELLS (SOFC)
Embodiments of the present disclosure are directed to a diesel reformer system comprising: a diesel autothermal reforming unit; a post-reforming unit disposed downstream of the autothermal reforming unit; a heat exchanger disposed downstream of the post-reforming unit; and a desulfurization unit disposed downstream of the heat exchanger.
DOWNSTREAM PRODUCTION PROCESS FOR HIGH PURITY BUTADIENE
Systems and methods for producing butadiene are disclosed. In a reaction unit, n-butane is dehydrogenated in the presence of a double-dehydrogenation catalyst to produce a mixture that includes butadiene and unreacted n-butane. An extractive distillation unit that uses soybean oil as the solvent is utilized to extract at least some of the unreacted n-butane from the mixture.
Catalyst system for dewaxing
A catalyst system for dewaxing of a hydrocarbon feedstock comprising a mixture of a first dewaxing catalyst composition and a second dewaxing catalyst composition, wherein the first dewaxing catalyst composition is a ZSM-12 zeolite based catalyst composition and the second dewaxing catalyst composition is a EU-2 and/or ZSM-48 zeolite based catalyst composition, and wherein a concentration gradient of the mixture is achieved within a single catalyst bed, such that the concentration of the first dewaxing catalyst is decreasing and the concentration of the second dewaxing catalyst is increasing through the catalyst bed; and a process for dewaxing of a hydrocarbon feedstock comprising contacting the hydrocarbon feedstock with said catalyst system.
Catalyst system for dewaxing
A catalyst system for dewaxing of a hydrocarbon feedstock comprising a mixture of a first dewaxing catalyst composition and a second dewaxing catalyst composition, wherein the first dewaxing catalyst composition is a ZSM-12 zeolite based catalyst composition and the second dewaxing catalyst composition is a EU-2 and/or ZSM-48 zeolite based catalyst composition, and wherein a concentration gradient of the mixture is achieved within a single catalyst bed, such that the concentration of the first dewaxing catalyst is decreasing and the concentration of the second dewaxing catalyst is increasing through the catalyst bed; and a process for dewaxing of a hydrocarbon feedstock comprising contacting the hydrocarbon feedstock with said catalyst system.