A process where external fuel oil is used to wash entrained catalyst from a fluidized-bed propane dehydrogenation reactor effluent, where the fuel oil and catalyst mixture is returned to the reactor to provide the net fuel required for catalyst regeneration. Optionally the fluidized-bed propane dehydrogenation reactor effluent and the fuel oil are contacted in a direct contact inline device before entering a flash zone in the reactor vessel.

Redox catalysts having surface medication, methods of making redox catalysts with surface modification, and uses of the surface modified redox catalysts are provided. In some aspects, the redox catalysts include a core oxygen carrier region and an outer shell having an average thickness of about 1-100 monolayers surrounding the outer surface of the core region.

Redox catalysts having surface medication, methods of making redox catalysts with surface modification, and uses of the surface modified redox catalysts are provided. In some aspects, the redox catalysts include a core oxygen carrier region such as CaMnO.sub.3, BaMnO.sub.3-, SrMnO.sub.3-, Mn.sub.2SiO.sub.4, Mn.sub.2MgO.sub.4-, La.sub.0.8Sr.sub.0.2O.sub.3-, La.sub.0.8Sr.sub.0.2FeO.sub.3-, Ca.sub.9Ti.sub.0.1Mn.sub.0.9O.sub.3-, Pr.sub.6O.sub.11-, manganese ore, or a combination thereof; and an outer shell having an average thickness of about 1-100 monolayers surrounding the outer surface of the core region. The outer shell can include, for example a salt selected such as Li.sub.2WO.sub.4, Na.sub.2WO.sub.4, K.sub.2WO.sub.4, SrWO.sub.4, Li.sub.2MoO.sub.4, Na.sub.2MoO.sub.4, K.sub.2MoO.sub.4, CsMoO.sub.4, Li.sub.2CO.sub.3, Na.sub.2CO.sub.3, K.sub.2CO.sub.3, or a combination thereof.

An oxygen gas stream is distributed to a spent catalyst stream through an oxygen nozzle of an oxygen gas distributor and a fuel gas stream is distributed to the spent catalyst stream through a fuel nozzle of a fuel gas distributor. An oxygen gas jet generated from said oxygen nozzle and a fuel gas jet generated from said fuel gas nozzle have the same elevation in the regenerator. In a regenerator, an oxygen gas distributor and a fuel gas distributor may be located in a mixing chamber. A fuel outlet of a fuel nozzle of the fuel gas distributor may be within a fifth of the height of the mixing chamber from an oxygen outlet of an oxygen nozzle of the oxygen gas distributor. In addition, clear space is provided between a fuel gas nozzle on a fuel gas distributor and a closest oxygen nozzle on an oxygen gas distributor.

An oxygen gas stream is distributed to a spent catalyst stream through an oxygen nozzle of an oxygen gas distributor and a fuel gas stream is distributed to the spent catalyst stream through a fuel nozzle of a fuel gas distributor. An oxygen gas jet generated from said oxygen nozzle and a fuel gas jet generated from said fuel gas nozzle have the same elevation in the regenerator. In a regenerator, an oxygen gas distributor and a fuel gas distributor may be located in a mixing chamber. A fuel outlet of a fuel nozzle of the fuel gas distributor may be within a fifth of the height of the mixing chamber from an oxygen outlet of an oxygen nozzle of the oxygen gas distributor. In addition, clear space is provided between a fuel gas nozzle on a fuel gas distributor and a closest oxygen nozzle on an oxygen gas distributor.

The present invention relates to a hydrocarbon conversion process comprising contacting a hydrocarbon feed stream with a hydrocarbon conversion catalyst, wherein the hydrocarbon conversion catalyst comprises a first composition comprising a dehydrogenation drogenation active metal on a solid support; and a second composition comprising a transition metal and a doping agent on an inorganic support, wherein the doping agent is selected from zinc, gallium, indium, lanthanum, and mixtures thereof.

A catalyst for synthesizing aromatic hydrocarbons, a preparation method thereof and a method for synthesizing aromatic hydrocarbons by using the catalyst. The catalyst comprises acidic molecular sieve particles and zinc-aluminum composite oxide particles. The catalyst has relatively high selectivity to aromatic hydrocarbons, particularly BTX, stable performance, and a long single-pass life.

The invention provides a method for regenerating a deNO.sub.X catalyst comprising contacting the catalyst with steam at a temperature in the range of from 250 to 390 C. The invention further provides a method of reducing the amount of nitrogen oxide components in a process gas stream comprising: a) contacting the process gas with a deNO.sub.X catalyst which results in the conversion of nitrogen oxide components as well as a decline in the NO.sub.X conversion over the deNO.sub.X catalyst; and b) regenerating the deNO.sub.X catalyst to improve the NO.sub.X conversion by contacting the deNO.sub.X catalyst with steam at a temperature in the range of from 250 to 390 C.

A method and a device for separation of at least one catalyst and/or adsorbent from a homogeneous mixture of catalysts and/or adsorbents containing one or more metal, semi-metal or non-metal contaminant(s) deposited thereon, making it possible to separate catalysts or adsorbents according to the presence or absence of contaminant and also according to the contaminant content, starting from a sorting threshold that corresponds to a content and that is defined by the operator.

Provided is a method for producing HCFC and/or HFC by subjecting a halogenated hydrocarbon and anhydrous hydrogen fluoride to a fluorination reaction in the presence of a catalyst, whereby efficient production can be achieved, without the need to stop the production every time catalytic activity is regenerated or recovered, and without making facilities excessive. Provided as a solution therefor is a method comprising (A) subjecting a halogenated hydrocarbon and anhydrous hydrogen fluoride to a fluorination reaction in at least two reactors each in the presence of a catalyst to thereby obtain HCFC and/or HFC; and (B) while halting the reaction in at least one of the reactors, obtaining HCFC and/or HFC by the reaction in at least one other reactor.